3,456 research outputs found
Lithium hydroxide dihydrate: A new type of icy material at elevated pressure
We show that, in addition to the known monohydrate, LiOH forms a dihydrate at elevated pressure. The dihydrate involves a large number of H-bonds establishing chains along the direction. In addition, the energy surface exhibits a saddle point for proton locations along certain O interatomic distances, a feature characteristic for superprotonic conductors. However, MD simulations indicate that LiOH·2H_2O is not a superprotonic conductor and suggest the relevant interpolyhedral O–O distances being too large to allow for proton transfer between neighboring Li-coordinated polyhedra at least on the time scale of the MD-simulations
Considering the impact of situation-specific motivations and constraints in the design of naturally ventilated and hybrid buildings
A simple logical model of the interaction between a building and its occupants is presented based on the principle that if free to do so, people will adjust their posture, clothing or available building controls (windows, blinds, doors, fans, and thermostats) with the aim of achieving or restoring comfort and reducing discomfort. These adjustments are related to building design in two ways: first the freedom to adjust depends on the availability and ease-of-use of control options; second the use of controls affects building comfort and energy performance. Hence it is essential that these interactions are considered in the design process. The model captures occupant use of controls in response to thermal stimuli (too warm, too cold etc.) and non-thermal stimuli (e.g. desire for fresh air). The situation-specific motivations and constraints on control use are represented through trigger temperatures at which control actions occur, motivations are included as negative constraints and incorporated into a single constraint value describing the specifics of each situation. The values of constraints are quantified for a range of existing buildings in Europe and Pakistan. The integration of the model within a design flow is proposed and the impact of different levels of constraints demonstrated. It is proposed that to minimise energy use and maximise comfort in naturally ventilated and hybrid buildings the designer should take the following steps: 1. Provide unconstrained low energy adaptive control options where possible, 2. Avoid problems with indoor air quality which provide motivations for excessive ventilation rates, 3. Incorporate situation-specific adaptive behaviour of occupants in design simulations, 4. Analyse the robustness of designs against variations in patterns of use and climate, and 5. Incorporate appropriate comfort standards into the operational building controls (e.g. BEMS)
Development of an adaptive window-opening algorithm to predict the thermal comfort, energy use and overheating in buildings
This investigation of the window opening data from extensive field surveys in UK office buildings demonstrates: 1) how people control the indoor environment by opening windows; 2) the cooling potential of opening windows; and 3) the use of an ‘adaptive algorithm’ for predicting window opening behaviour for thermal simulation in ESP-r. It was found that when the window was open the mean indoor and outdoor temperatures were higher than when closed, but show that nonetheless there was a useful cooling effect from opening a window. The adaptive algorithm for window opening behaviour was then used in thermal simulation studies for some typical office designs. The thermal simulation results were in general agreement with the findings of the field surveys. The adaptive algorithm is shown to provide insights not available using non adaptive simulation methods and can assist in achieving more comfortable, lower energy buildings while avoiding overheating
A three-dimensional finite element model of maximal grip loading in the human wrist
The aim of this work was to create an anatomically accurate three-dimensional finite element model of the wrist, applying subject-specific loading and quantifying the internal load transfer through the joint during maximal grip. For three subjects, representing the anatomical variation at the wrist, loading on each digit was measured during a maximal grip strength test with simultaneous motion capture. The internal metacarpophalangeal joint load was calculated using a biomechanical model. High-resolution magnetic resonance scans were acquired to quantify bone geometry. Finite element analysis was performed, with ligaments and tendons added, to calculate the internal load distribution. It was found that for the maximal grip the thumb carried the highest load, an average of 72.2 ¡ 20.1 N in the neutral position. Results from the finite element model suggested that the highest regions of stress were located at the radial aspect of the carpus. Most of the load was transmitted through the radius, 87.5 per cent, as opposed to 12.5 per cent through the ulna with the wrist in a neutral position. A fully three-dimensional finite element analysis of the wrist using subject-specific anatomy and loading conditions was performed. The study emphasizes the importance of modelling a large ensemble of subjects in order to capture the spectrum of the load transfer through the wrist due to anatomical variation
Comfort driven adaptive window opening behaviour and the influence of building design
It is important to understand and model the behaviour of occupants in buildings and how this behaviour impacts energy use and comfort. It is similarly important to understand how a buildings design affects occupant comfort, occupant behaviour and ultimately the energy used in the operation of the building. In this work a behavioural algorithm for window opening developed from field survey data has been implemented in a dynamic simulation tool. The algorithm is in alignment with the proposed CEN standard for adaptive thermal comfort. The algorithm is first compared to the field study data then used to illustrate the impact of adaptive behaviour on summer indoor temperatures and heating energy. The simulation model is also used to illustrate the sensitivity of the occupant adaptive behaviour to building design parameters such as solar shading and thermal mass and the resulting impact on energy use and comfort. The results are compared to those from other approaches to model window opening behaviour. The adaptive algorithm is shown to provide insights not available using non adaptive simulation methods and can assist in achieving more comfortable and lower energy buildings
Diversity of Diet Composition Decreases with Conjoint Grazing of Cattle with Sheep and Goats
Conjoint or mixed grazing can affect the diet selected by each species (Nicol & Collins, 1990). Diet similarity coefficients are often used to compare pairs of diets (Krebs, 1999). However this approach is awkward when a number of contrasts are required in a multifactorial comparison. Species diversity is a descriptor of a particular environment. Many models provide an estimate of species diversity, the most common of these being a log-normal distribution (Tokeshi, 1996). We tested whether this model could be applied to dietary components selected from a pasture, and thus provide a coefficient of dietary diversity for the individual diets of cattle, sheep and goats when grazed alone or in mixtures, which could then be statistically compared
Diversity of Diet Composition Decreases with Conjoint Grazing of Cattle with Sheep and Goats
Conjoint or mixed grazing can affect the diet selected by each species (Nicol & Collins, 1990). Diet similarity coefficients are often used to compare pairs of diets (Krebs, 1999). However this approach is awkward when a number of contrasts are required in a multifactorial comparison. Species diversity is a descriptor of a particular environment. Many models provide an estimate of species diversity, the most common of these being a log-normal distribution (Tokeshi, 1996). We tested whether this model could be applied to dietary components selected from a pasture, and thus provide a coefficient of dietary diversity for the individual diets of cattle, sheep and goats when grazed alone or in mixtures, which could then be statistically compared
The unusual thickness dependence of superconductivity in -MoGe thin films
Thin films of -MoGe show progressively reduced 's as the
thickness is decreased below 30 nm and the sheet resistance exceeds 100
. We have performed far-infrared transmission and reflection
measurements for a set of -MoGe films to characterize this weakened
superconducting state. Our results show the presence of an energy gap with
ratio in all films studied, slightly higher
than the BCS value, even though the transition temperatures decrease
significantly as film thickness is reduced. The material properties follow
BCS-Eliashberg theory with a large residual scattering rate except that the
coherence peak seen in the optical scattering rate is found to be strongly
smeared out in the thinner superconducting samples. A peak in the optical mass
renormalization at is predicted and observed for the first time
Spectroscopy of HS: evidence of a new energy scale for superconductivity
The discovery of a superconducting phase in sulfur hydride under high
pressure with a critical temperature above 200 K has provided a new impetus to
the search for even higher . Theory predicted and experiment confirmed
that the phase involved is HS with Im-3m crystal structure. The observation
of a sharp drop in resistance to zero at , its downward shift with
magnetic field and a Meissner effect confirm superconductivity but the
mechanism involved remains to be determined. Here, we provide a first optical
spectroscopy study of this new superconductor. Experimental results for the
optical reflectivity of HS, under high pressure of 150 GPa, for several
temperatures and over the range 60 to 600 meV of photon energies, are compared
with theoretical calculations based on Eliashberg theory using DFT results for
the electron-phonon spectral density F(). Two significant
features stand out: some remarkably strong infrared active phonons at
160 meV and a band with a depressed reflectance in the superconducting state in
the region from 450 meV to 600 meV. In this energy range, as predicted by
theory, HS is found to become a better reflector with increasing
temperature. This temperature evolution is traced to superconductivity
originating from the electron-phonon interaction. The shape, magnitude, and
energy dependence of this band at 150 K agrees with our calculations. This
provides strong evidence of a conventional mechanism. However, the unusually
strong optical phonon suggests a contribution of electronic degrees of freedom.Comment: 10 pages, 8 figures. Main manuscript and supplementary informatio
Self-similar signature of the active solar corona within the inertial range of solar-wind turbulence
We quantify the scaling of magnetic energy density in the inertial range of solar-wind turbulence seen
in situ at 1 AU with respect to solar activity. At solar maximum, when the coronal magnetic field is
dynamic and topologically complex, we find self-similar scaling in the solar wind, whereas at solar
minimum, when the coronal fields are more ordered, we find multifractality. This quantifies the solar-wind
signature that is of direct coronal origin and distinguishes it from that of local MHD turbulence, with
quantitative implications for coronal heating of the solar wind
- …