4,722 research outputs found
The (New) New Judicial Federalism: State Constitutions and the Protection of the Individual Right to Bear Arms
European air quality maps 2005 including uncertainty analysis
The objective of this report is (a) the updating and refinement of European air quality maps based on annual statistics of the 2005 observational data reported by EEA Member countries in 2006, and (b) the further improvement of the interpolation methodologies. The paper presents the results achieved and an uncertainty analysis of the interpolated maps and builds upon earlier reports from Horalék et al. (2005; 2007)
Towards a morphology of cobalt nanoparticles: size and strain effects
Cobalt nanoparticles with diameters of 8 nm have recently shown promising performance for biomedical applications. However, it is still unclear how the shape of cobalt clusters changes with size when reaching the nanoparticle range. In the present work, density functional theory calculations have been employed to compare the stabilities of two non-crystalline (icosahedron and decahedron) shapes, and three crystalline motifs (hcp, fcc, and bcc) for magic numbered cobalt clusters with up to 1500 atoms, based on the changes in the cohesive energies, coordination numbers, and nearest-neighbour distances arising from varying geometries. Obtained trends were extrapolated to a 104 size range, and an icosahedral shape was predicted for clusters up to 5500 atoms. Larger sized clusters adopt hcp stacking, in correspondence with the bulk phase. To explain the crystalline/non-crystalline crossovers, the contributions of the elastic strain density and twin boundary from the specimen surfaces to the cohesive energy of different motifs were evaluated. These results are expected to aid the design and synthesis of cobalt nanoparticles for applications ranging from catalysis to biomedical treatments
Managing the last mile of the supply chain for spare parts
En este trabajo se analiza el diseño de la cadena de suministro en la última milla para las
piezas de repuesto que usan los consumidores en las actividades de reparaciĂłn que llevan a
cabo ellos mismos. Se distribuyĂł una encuesta entre consumidores holandeses para identificar
los mĂ©todos de entrega preferidos y las caracterĂsticas de los pedidos. Los resultados indican
que existe un deseo general entre estos consumidores de realizar actividades de reparaciĂłn
ellos mismos y prefieren la entrega directa de las piezas de repuesto. En cuanto a las
caracterĂsticas de los pedidos, depende de caracterĂsticas coyunturales tales como la edad o
lo crĂticas que sean las piezas
Theory-based evaluation of complex settings for health : readiness for change in health promoting schools.
Bound States of the q-Deformed AdS5 x S5 Superstring S-matrix
The investigation of the q deformation of the S-matrix for excitations on the
string world sheet in AdS5 x S5 is continued. We argue that due to the lack of
Lorentz invariance the situation is more subtle than in a relativistic theory
in that the nature of bound states depends on their momentum. At low enough
momentum |p|<E the bound states transform in the anti-symmetric representation
of the super-algebra symmetry and become the solitons of the Pohlmeyer reduced
theory in the relativistic limit. At a critical momentum |p|=E they become
marginally unstable, and at higher momenta the stable bound states are in the
symmetric representation and become the familiar magnons in the string limit as
q->1. This subtlety fixes a problem involving the consistency of crossing
symmetry with the relativistic limit found in earlier work. With mirror
kinematics, obtained after a double Wick rotation, the bound state structure is
simpler and there are no marginally unstable bound states.Comment: 25 page
Binding modes of carboxylic acids on cobalt nanoparticles
Owing to their high saturation magnetisation, cobalt nanoparticles hold significant potential for the hyperthermia treatment of tumours. Covalent binding of carboxylic acids to the nanoparticles can induce biocompatibility, whilst also preventing the formation of surface oxides which reduce the magnetic properties of cobalt. Understanding the origin of the acid–metal interaction is key, yet probably the most experimentally challenging step, for the rational design of such entities. In this density functional theory study, we use static calculations to establish that a 57-atom Co cluster is the smallest model able to reproduce the adsorption behaviour of carboxylic acids, and ab initio metadynamics to obtain the structure and the free energy landscape for its interaction with valeric acid. Our simulations show that a bridging bidentate binding mode has a stronger affinity compared to monodentate binding, with energetically high transition barriers between the two. A chelate interaction mode of two carboxyl oxygen atoms can be formed as an intermediate. These results clarify the organic–inorganic interactions in the cobalt–acid system, providing a basis for the rational design of biocompatible metallic nanoparticles
Molecular dynamics studies of polar/nonpolar fluid mixtures: I. Mixtures of Lennard-Jones and Stockmayer fluids.
Diffusion in sparse networks: linear to semi-linear crossover
We consider random networks whose dynamics is described by a rate equation,
with transition rates that form a symmetric matrix. The long time
evolution of the system is characterized by a diffusion coefficient . In one
dimension it is well known that can display an abrupt percolation-like
transition from diffusion () to sub-diffusion (D=0). A question arises
whether such a transition happens in higher dimensions. Numerically can be
evaluated using a resistor network calculation, or optionally it can be deduced
from the spectral properties of the system. Contrary to a recent expectation
that is based on a renormalization-group analysis, we deduce that is
finite; suggest an "effective-range-hopping" procedure to evaluate it; and
contrast the results with the linear estimate. The same approach is useful for
the analysis of networks that are described by quasi-one-dimensional sparse
banded matrices.Comment: 13 pages, 4 figures, proofed as publishe
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