Numerical investigation of crack self-sealing in cement-based composites with superabsorbent polymers

Recently the concept of crack self-sealing has been investigated as a method to prevent degradation and/or loss of functionality of cracked concrete elements. To obtain self-sealing effect in the crack, water swelling admixtures such as superabsorbent polymers (SAP) are added into the cementitious mix. In order to design such self-sealing systems in an efficient way, a three-dimensional mesoscale numerical model is proposed to simulate capillary absorption of water in sound and cracked cement-based materials containing SAP. The numerical results yield the moisture content distribution in cracked and sound domain, as well as the absorption and swelling of SAP embedded in the matrix and in the crack. The performance of the model was validated by using experimental data from the literature, as well as experimentally-informed input parameters. The validated model was then used to investigate the role of SAP properties and dosage in cementitious mixtures, on the water penetration into the material from cracks. Furthermore different crack widths were considered in the simulations. The model shows good agreement with experimental results. From the numerical investigation guidelines are suggested for the design of the studied composites

Influence of Micro-Pore Connectivity and Micro-Fractures on Calcium Leaching of Cement Pastes — A Coupled Simulation Approach

A coupled numerical approach is used to evaluate the influence of pore connectivity and microcracks on leaching kinetics in fully saturated cement paste. The unique advantage of the numerical model is the ability to construct and evaluate a material with controlled properties, which is very difficult under experimental conditions. Our analysis is based on two virtual microstructures, which are different in terms of pore connectivity but the same in terms of porosity and the amount of solid phases. Numerical fracturing was performed on these microstructures. The non-fractured and fractured microstructures were both subjected to chemical leaching. Results show that despite very different material physical properties, for example, pore connectivity and effective diffusivity, the leaching kinetics remain the same as long as the amount of soluble phases, i.e., buffering capacity, is the same. The leaching kinetics also remains the same in the presence of microcracks

Influence of SiO2, TiO2 and Fe2O3 nanoparticles on the properties of fly ash blended cement mortars

This study explores the effects of different types of nanoparticles, namely nano-SiO2 (NS), nano-TiO2 (NT), and nano-Fe2O3 (NF) on the fresh properties, mechanical properties, and microstructure of cement mortar containing fly ash as a supplementary cementitious material. These nanoparticles existed in powder form and were incorporated into the mortar at the dosages of 1%, 3%, and 5% wt.% of cement. Also, fly ash has been added into in mortars with a constant dosage of 30% wt.% of cement. Compressive and flexural strength tests were performed to evaluate the mechanical properties of the mortar specimens with different nanoparticles at three curing ages, 7, 14, and 28 days. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) tests were conducted to study the microstructure and the hydration products of the mortars. To elucidate the effects of nanoparticles on the binder phase, additional experiments were performed on accompanying cement pastes: nanoindentation and open porosity measurements. The study shows that, if added in appropriate amounts, all nanoparticles investigated can result in significantly improved mechanical properties compared to the reference materials. However, exceeding of the optimal concentration results in clustering of the nanoparticles and reduces the mechanical properties of the composites, which is accompanied with increasing the porosity. This study provides guidelines for further improvement of concretes with blended cements through use of nanoparticles

Evaluation of the Self-healing Capability of Ultra-High-Performance Fiber-Reinforced Concrete with Nano-Particles and Crystalline Admixtures by Means of Permeability

[EN] Self-healing is the capability of a material to repair its damage autonomously. Ultra-High-Performance Fiber Reinforced Concrete (UHPFRC) has potentially higher self-healing properties than conventional concrete because of its lower water/binder content and controlled microcracking due to the high fiber content. This work uses a novel methodology based on the permeability to evaluate autogenous self-healing of UHPFRC and enhanced self-healing, incorporating several additions. To this purpose, one UHPFRC was selected and modified to include alumina nanofibers in 0.25% by the cement weight, nanocellulose (nanocrystals and nanofibers), in a dosage of 0.15% by the cement weight, and 0.8-1.6% of a crystalline admixture. The results obtained show that the methodology proposed allows the evaluation of the self-healing capability of different families of concrete mixes that suffered a similar level of damage using permeability tests adapted to the specific properties of UHPFRC.The authors would like to acknowledge the European Union¿s Horizon 2020 ReSHEALience project (Grant Agreement No. 760824).Doostkami, H.; Roig-Flores, M.; Negrini, A.; Mezquida-Alcaraz, EJ.; Serna Ros, P. (2020). Evaluation of the Self-healing Capability of Ultra-High-Performance Fiber-Reinforced Concrete with Nano-Particles and Crystalline Admixtures by Means of Permeability. Springer. 489-499. https://doi.org/10.1007/978-3-030-58482-5_45489499Homma, D., Mihashi, H., Nishiwaki, T.: Self-healing capability of fibre reinforced cementitious composites. J. Adv. Concr. Technol. 7(2), 217–228 (2009)Maes, M., Snoeck, D., De Belie, N.: Chloride penetration in cracked mortar and the influence of autogenous crack healing. Constr. Build. 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Compos. 30(10), 938–946 (2008)Denarié, E., Brühwiler, E.: Strain-hardening ultra-high performance fibre reinforced concrete: deformability versus strength optimization. Restor. Build. Monum. 17(6), 397–410 (2014)Granger, S., Pijaudier-Cabot, G., Loukili, A.: Mechanical behavior of self-healed ultra high performance concrete: from experimental evidence to modeling. In: Proceedings of the 6th International Conference on Fracture Mechanics of Concrete and Concrete Structures, vol. 3, pp. 1827–1834 (2007)Escoffres, P., Desmettre, C., Charron, J.P.: Effect of a crystalline admixture on the self-healing capability of high-performance fiber reinforced concretes in service conditions. Constr. Build. Mater. 173, 763–774 (2018)Sisomphon, K., Copuroglu, O., Koenders, E.A.B.: Self-healing of surface cracks in mortars with expansive additive and crystalline additive. Cem. Concr. 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Use of 3D printing to create multifunctional cementitious composites: Review, challenges and opportunities

Additive manufacturing has been a topic of interest in the construction industry for the past decade. 3D printing of concrete structures promises great improvements in construction efficiency, waste reduction, and shape optimization. Another field where additive manufacturing offers opportunities is on the material level of cementitious composites. Techniques developed in other fields can be used to create multifunctional cementitious composites beyond what is possible with conventional technologies. This letter reviews recent developments in the field. Different applications are discussed: creating reinforcement for cementitious composites, creating capsules and vascular networks, and cementitious composites with superior mechanical behavior. Challenges for further research and practical applications of such materials are also discussed.Materials and Environmen

Smart Crack Control in Concrete through Use of Phase Change Materials (PCMs): A Review

Cracks in concrete structures present a threat to their durability. Therefore, numerous research studies have been devoted to reducing concrete cracking. In recent years, a new approach has been proposed for controlling temperature related cracking—utilization of phase change materials (PCMs) in concrete. Through their ability to capture heat, PCMs can offset temperature changes and reduce gradients in concrete structures. Nevertheless, they can also influence concrete properties. This paper presents a comprehensive overview of the literature devoted to using PCMs to control temperature related cracking in concrete. First, types of PCMs and ways of incorporation in concrete are discussed. Then, possible uses of PCMs in concrete technology are discussed. Further, the influences of PCMs on concrete properties (fresh, hardened, durability) are discussed in detail. This is followed by a discussion of modelling techniques for PCM-concrete composites and their performance. Finally, a summary and the possible research directions for future work are given. This overview aims to assure the researchers and asset owners of the potential of this maturing technology and bring it one step closer to practical application.Materials and Environmen

3D printing and self-healing concrete: a good match?

Self-healing concrete has shown excellent potential in improving the durability of (reinforced) concrete structures and reducing the need for their repair and maintenance. This has been further substantiated by several successful full-scale demonstrator projects. Nevertheless, industrial uptake of the technology is lagging behind, mainly due to the higher initial cost compared to traditional concrete. In addition, it is well known that some self-healing mechanisms can have detrimental effects on properties of concrete, such as e.g., the compressive strength, making some engineers sceptical about practical applicability. With these two issues in mind, one might wonder: shouldn’t we simply apply self-healing concrete only where it is needed? This has been done in the past in so-called hybrid structures, in which self-healing concrete was used in the cover zone as a stay-in-place mold, while traditional concrete was used as infill. Additive manufacturing (3D printing) techniques offer additional possibilities in selective placement and optimization of self-healing concrete composites. Additive manufacturing provides unprecedented freedom in design and optimization of structures at virtually no additional cost. This could allow customizing the placement of self-healing agents based on structural design and loading considerations of a given structure. In this talk, recent developments and potential applications of different additive manufacturing techniques for design and fabrication of self-healing concrete will be discussed.Materials and Environmen

Architected Cementitious Cellular Materials: Peculiarities and opportunities

Conventionally, the properties of cementitious materials are tailored by a simple but efficient method: mixture proportion design. For a given cementitious mixture, the chemical and physical properties of cementitious materials have already been determined. Consequently, the mechanical performance of the hardened cementitious material is determined. This is attributed to the nanoscale, microscale and mesoscale structures formed during the hydration process which are also dictated by the mixture proportion. Apart from this traditional methodology, a novel approach to tailor materials mechanical performance by combining architected cellular structure with certain constituent materials is introduced in this work. Inspired by cellular polymer materials and cellular ceramic materials which show enhanced properties comparing to conventional polymers and ceramics, creating cementitious cellular materials is also assumed to be a promising research direction. Specifically, geometrical features of promising cellular structures and their corresponding mechanical performance is reviewed. Potential processing methods for obtaining such cellular structures using cementitious materials are discussed. In addition, probable requirements on cementitious mixture for the cellular structure are analyzed

Gaussian models for bond strength evaluation of ribbed steel bars in concrete

A precise prediction of the ultimate bond strength between rebar and surrounding concrete plays a major role in structural design, as it effects the load-carrying capacity and serviceability of a member significantly. In the present study, Gaussian models are employed for modelling bond strength of ribbed steel bars embedded in concrete. Gaussian models offer a non-parametric method based on Bayesian framework which is powerful, versatile, robust and accurate. Five different Gaussian models are explored in this paper-Gaussian Process (GP), Variational Heteroscedastic Gaussian Process (VHGP), Warped Gaussian Process (WGP), Sparse Spectrum Gaussian Process (SSGP), and Twin Gaussian Process (TGP). The effectiveness of the models is also evaluated in comparison to the numerous design formulae provided by the codes. The predictions from the Gaussian models are found to be closer to the experiments than those predicted using the design equations provided in various codes. The sensitivity of the models to various parameters, input feature space and sampling is also presented. It is found that GP, VHGP and SSGP are effective in prediction of the bond strength. For large data set, GP, VHGP, WGP and TGP can be computationally expensive. In such cases, SSGP can be utilized.</p