Influence of carrier lifetime on quantum criticality and superconducting Tc of (TMTSF)_2ClO_4

This work presents and analyzes electrical resistivity data on the organic superconductor (TMTSF)$_2$ClO$_4$ and their anion substituted alloys (TMTSF)$_2$(ClO$_4$)$_{1-x}$(ReO$_4$)$_x$ along the least conducting $c^\star$ axis. Nonmagnetic disorder introduced by finite size domains of anion ordering on non Fermi liquid character of resistivity is investigated near the conditions of quantum criticality. The evolution of the $T$-linear resistivity term with anion disorder shows a limited decrease in contrast with the complete suppression of the critical temperature $T_c$ as expected for unconventional superconductivity beyond a threshold value of $x$. The resulting breakdown of scaling between both quantities is compared to the theoretical predictions of a linearized Boltzmann equation combined to the scaling theory of umklapp scattering in the presence of disorder induced pair-breaking for the carriers.Comment: 13 pages, 8 figure

Two insulating phases in compressed Pr1-xCaxMnO3 thin films

The temperature dependent resistivity of two Pr1-xCaxMnO3 (x=0.5 and 0.4) thin films grown on LaAlO3 has been studied as a function of hydrostatic pressure (up to 2.5 GPa) and magnetic field (up to 9T). Both samples show a monotonic decrease in the resistivity with an increase in pressure, corresponding to a change of -35% at 2.5 GPa. No pressure induced metal-to-insulator transition was observed in the temperature-dependent resistivity. The non-trivial interaction between high pressure and magnetic field reveals that the effect of pressure cannot be simply rescaled to that of a specific field, as has been reported for the corresponding bulk material. We propose an interpretation of the data based on phase separation, where two different insulating phases coexist: the charge ordered phase, which is sensitive to both magnetic field and pressure, and a second insulating phase that can be tuned by magnetic field. Such a result demonstrates that phase separation can be manipulated in thin films by independent application of magnetic field and/or external pressure.Comment: 9 pages, 3 figuresn submitted to Applied Physics Letter

(Sr/Ca)_{14}Cu_{24}O_{41} spin ladders studied by NMR under pressure

(63)Cu-NMR measurements have been performed on two-leg hole-doped spin ladders Sr_{14-x}Ca_{x}Cu_{24}O_{41} single crystals (0-x-12) at several pressures up to the pressure domain where the stabilization of a superconducting ground state can be achieved. The data reveal marked decrease of the spin gap derived from Knight shift measurements upon Ca substitution and also under pressure and confirm the onset of low lying spin excitations around P_{c} as previously reported. The spin gap in Sr_{2}Ca_{12}Cu_{24}O_{41} is strongly reduced above 20 kbar. However, the data of an experiment performed at P=36 kbar where superconductivity has been detected at 6.7K by an inductive technique have shown that a significant amount of spin excitations remains gapped at 80K when superconductivity sets in. The standard relaxation model with two and three-magnon modes explains fairly well the activated relaxation data in the intermediate temperature regime corresponding to gapped spin excitations using the spin gap data derived from Knight shift experiments.The data of Gaussian relaxation rates of heavily doped samples support the limitation of the coherence lenght at low temperature by the average distance between doped holes. We discuss the interplay between superconductivity and the spin gap and suggest that these new results support the exciting prospect of superconductivity induced by the interladder tunnelling of preformed pairs as long as the pressure remains lower than the pressure corresponding to the maximum of the superconducting critical temperature.Comment: 15 pages Latex, 13 figures. to be published in Eur.Phys.Jour.B,200

Phase diagram of quarter-filled band organic salts, [EDT-TTF-CONMe2]2X, X = AsF6 and Br

An investigation of the P/T phase diagram of the quarter-filled organic conductors, [EDT-TTF-CONMe2]2X, is reported on the basis of transport and NMR studies of two members, X=AsF6 and Br of the family. The strongly insulating character of these materials in the low pressure regime has been attributed to a remarkably stable charge ordered state confirmed by 13C NMR and the only existence of 1/4 Umklapp e-e scattering favoring a charge ordering instead of the 1D Mott localization seen in (TM)2X which are quarter-filled compounds with dimerization. A non magnetic insulating phase instead of the spin density wave state is stabilized in the deconfined regime of the phase diagram. This sequence of phases observed under pressure may be considered as a generic behavior for 1/4-filled conductors with correlations

Influence of Quantum Hall Effect on Linear and Nonlinear Conductivity in the FISDW States of the Organic Conductor (TMTSF)_2PF_6

We report a detailed characterization of quantum Hall effect (QHE) influence on the linear and non-linear resistivity tensor in FISDW phases of the organic conductor (TMTSF)2PF6. We show that the behavior at low electric fields, observed for nominally pure single crystals with different values of the resistivity ratio, is fully consistent with a theoretical model, which takes QHE nature of FISDW and residual quasi-particle density associated with different crystal imperfection levels into account. The non-linearity in longitudinal and diagonal resistivity tensor components observed at large electric fields reconciles preceding contradictory results. Our theoretical model offers a qualitatively good explanation of the observed features if a sliding of the density wave with the concomitant destruction of QHE, switched on above a finite electric field, is taken into account.Comment: 8 pages, 6 figures, submitted to EPJ

Coexistence of Superconductivity and Spin Density Wave orderings in the organic superconductor (TMTSF)_2PF_6

The phase diagram of the organic superconductor (TMTSF)_2PF_6 has been revisited using transport measurements with an improved control of the applied pressure. We have found a 0.8 kbar wide pressure domain below the critical point (9.43 kbar, 1.2 K) for the stabilisation of the superconducting ground state featuring a coexistence regime between spin density wave (SDW) and superconductivity (SC). The inhomogeneous character of the said pressure domain is supported by the analysis of the resistivity between T_SDW and T_SC and the superconducting critical current. The onset temperature T_SC is practically constant (1.20+-0.01 K) in this region where only the SC/SDW domain proportion below T_SC is increasing under pressure. An homogeneous superconducting state is recovered above the critical pressure with T_SC falling at increasing pressure. We propose a model comparing the free energy of a phase exhibiting a segregation between SDW and SC domains and the free energy of homogeneous phases which explains fairly well our experimental findings.Comment: 13 pages, 10 figures, revised v: fig.9 added, section 4.2 rewritten, accepted v: sections 4&5 improve

Photochromism, Electrical Properties, and Structural Investigations of a Series of Hydrated Methylviologen Halobismuthate Hybrids: Influence of the Anionic Oligomer Size and Iodide Doping on the Photoinduced Properties and on the Dehydration Process

Syntheses, X-ray structural analyses, thermal behaviors, photochromism, and electrical properties of a series of methylviologen (MV2+) halobismuthate hybrids, namely, (MV)3[Bi4Cl18](H2O)y (1a, y~1.7), (MV)4[Bi6Cl26](H2O)y (2a, y~1.7), (MV)4[Bi6Cl25.6I0.4](H2O)y (3a, y~1.5), and (MV)4[Bi6Cl24.6I1.4](H2O)y (4a, y~1.3), are reported. Because of the thermal effect of a UV lamp or as a result of being heated up to 100 °C, all of the above compounds undergo a complete (1a, 2a, and 3a) or a partial (4a) dehydration together, in 2a and 3a, with an impressive structural reorganization involving a 90° rotation of methylviologen dimers and, in 3a, a new Cl/I distribution, finally leading to (MV)3[Bi4Cl18] (1b), (MV)4[Bi6Cl26] (2b), (MV)4[Bi6Cl25.6I0.4] (3b), and (MV)4[Bi6Cl24.6I1.4](H2O)x (4a, x ~ 0.65), respectively. In its turn, 4a (x ~ 0.65) undergoes an abrupt structural change at 160 °C when water molecules are completely removed, leading to (MV)4[Bi6Cl24.6I1.4] (4b). Obviously, the two first dehydrated phases can be considered as the n = 2 (1b) and n = 3 (2b) members of the (MV)(2n+2)/2[Bi2nCl8n+2] family, and the ultimate member (n = ∞) with an infinite 1D double-chain inorganic framework, namely, (MV)[Bi2Cl8], has already been reported. According to the results of structural refinements, some positions of the Cl atoms in the [Bi6Cl26]8− anionic cluster of 3a and 4a have been occupied by I atoms, finally leading to iodide-doped materials of the 2a type (percentage of doping: 3a, 1.5%; 4a, 5.4%). Upon UV irradiation, yellow crystals of 2a and 3a (which become 2b and 3b because of the thermal effect of the UV lamp) or yellow crystals of 2b, 3b, and 4a undergo a color change to black crystals (in the case of 2b), as observed in (MV)[Bi2Cl8], or light-brown crystals (in the cases of 3b and 4a). These photochromic properties are probably due to the photoinduced electron transfer from the anionic part to the methylviologen dications. In contrast, no color change is observed when yellow crystals of 1a or 1b and the iodide-doped (MV)[Bi2Cl8−εIε] material are irradiated. Because the relative positions of methylviologen to the host anionic frameworks are comparable in all structures (the N···Cl distances are about 3.4 Å), these results indicate that such kinds of photochemical reactions depend on the dimension of the anionic networks, as well as the iodide doping. The single-crystal electrical conductivity measurements of 2b before and after irradiation were carried out between 150 and 393 K. The results prove that both of them are semiconductors with weak room temperature conductivity and that the band gap of the irradiated crystal (2b, 0.35 eV) is much smaller than that of the original hybrid 2a (1.0 eV)