Monomineral universal clinopyroxene and garnet barometers for peridotitic, eclogitic and basaltic systems

New versions of the universal Jd-Di exchange clinopyroxene barometer for peridotites, pyroxenites and eclogites, and also garnet barometer for eclogites and peridotites were developed. They were checked using large experimental data sets for eclogitic (∼530) and peridotitic systems (>650). The precision of the universal Cpx barometer for peridotites based on Jd-Di exchange is close to Cr-Tschermakite method produced by Nimis and Taylor (2000). Cpx barometer was transformed by the substitution of major multiplier for KD by the equations dependent from Al-Na-Fe. Obtained equation in combination with the thermometer of Nimis and Taylor (2000) allow to reconstruct position of the magma feeder systems of the alkali basaltic magma within the mantle diapirs in modern platforms like in Vitim plateau and other Southern Siberia localities and several localities worldwide showing good agreement of pressure ranges for black and green suites. These equations allow construct PTX diagrams for the kimberlite localities in Siberia and worldwide calculating simultaneously the PT parameters for different groups of mantle rocks. They give very good results for the concentrates from kimberlite lamproites and placers with mantle minerals. They are useful for PT estimates for diamond inclusions. The positions of eclogite groups in mantle sections are similar to those determined with new Gar–Cpx barometer produced by C. Beyer et al. (2015). The Fe rich eclogites commonly trace the boundary between the lower upper parts of subcontinental lithospheric mantle (SCLM) at 3–4 GPa marking pyroxenite eclogites layer. Ca-rich eclogites and especially grospydites in SCLM beneath Precambrian kimberlites occurs near pyroxenite layer but in younger mantle sections they became common in the lower parts. The diamondiferous Mg Cr-less group eclogites referring to the ancient island arc complexes are also common in the middle part of mantle sections and near 5–6 GPa. Commonly eclogites in lower apart of mantle sections are remelted and trace the high temperature convective branch. The Mg- and Fe-rich pyroxenites also show the extending in pressure trends which suggest the anatexic melting under the influence of volatiles or under the interaction with plums

Deep seated magmas and their mantle roots: introduction

In the last decade there has been a considerable effort to better understand the joint evolution of mafic and ultramafic magmatic systems and their deep mantle roots, through integrated petrological and thermo-barometric studies. Magma generation is regarded as the result of complex processes including melting, creation of channels for melt transfer, and interaction with the wall-rocks. Complexities in magmatic systems involve metasomatism and the creation of metasomatic fronts, branching and splitting of magma volumes during their evolution, and variable compositional development during transfer to upper crystallizing horizons. Intrusions and formation of intermediate magmatic chambers in the upper mantle Moho or in the lower crust are often accompanied by melt differentiation according to Assimilation-Fractional-Crystallization processes (AFC). Splitting of polybaric magmatic systems brings the appearance of a wide spectrum of melt compositions. Each magmatic plume leaves its own tracers in the mantle, and can erase signs of preceding mantle magmatic events. Commonly, petrologists may focus on individual magmatic processes through the study of mantle rocks and mantle xenoliths, but there have been recent efforts to produce complex models that take into account the various aspects of such evolving magmatic system, particularly that take account of spatial and temporal changes. Such studies have also made links to modern and ancient geodynamics, and to questions of continental growth, structure of the mantle and modification of the sub-continental lithospheric mantle (SCLM)

Comparison of mantle lithosphere beneath early Triassic kimberlite fields in Siberian craton reconstructed from deep-seated xenocrysts

Mantle xenocrysts from Early Triassic kimberlite pipes from Kharamai, Ary Mastakh and Kuranakh fields in the Anabar shield of Siberia revealing similar compositional trends were studied to estimate the superplume influence on the SCLM. PT reconstructions using monomineral thermobarometry for 5 phases show division of the SCLM beneath the Kharamai field into 6 units: pyroxenitic Fe-rich (1-2 GPa) and Mg-rich (2-3 GPa) layers; middle with two levels of Gar -Sp pyroxenites at ∼3 and 4 -5 GPa; Ga- dunite –harzburgites ∼ 4.5-6.5 GPa subjected to Ilm-Px vein metasomatism, and a Mg-rich dunite lower part. In the Anabar shield (Ary Mastakh, Dyuken and Kuranakh fields) mantle lithosphere is composed of three large units divided into two parts: upper part with amphiboles and phlogopite; two levels of pyroxenites and eclogites at 3 and 4 GPa, and a lower part composed of refertilized dunites. Diagrams showing P- Fe#Gar clusters for garnets and omphacites illustrate the differences between SCLM of these localities. Differences of Triassic SCLM from Devonian SCLM are in simple layering; abundance of Na-Cr-amphiboles and metasomatism in the upper SCLM part, thick pyroxenite - eclogite layer and lower part depletion, heated from SCLM base to 5.0 GPa. Kharamai mantle clinopyroxenes represent three geochemical types: 1) harzburgitic with inclined linear REE, HFSE troughs and elevated Th, U; 2) lherzolitic or pyroxenitic with round TRE patterns and decreasing incompatible elements; 3) eclogitic with Eu troughs, Pb peak and high LILE content. Calculated parental melts for garnets with humped REE patterns suggest dissolution of former Cpx and depression means Cpx and garnets extraction. Clinopyroxenes from Ary Mastakh fields show less inclined REE patterns with HMREE troughs and an increase of incompatible elements. Clinopyroxenes from Kuranakh field show flatter spoon-like REE patterns and peaks in Ba, U, Pb and Sr, similar to those in ophiolitic harzburgites. The PT diagrams for the mantle sections show high temperature gradients in the uppermost SCLM accompanied by an increase of P-Fe#Ol upward and slightly reduced thickness of the mantle keel of the Siberian craton, resulting from the influence of the Permian -Triassic superplume, but with no signs of delamination

Interaction between protokimberlite melts and mantle lithosphere: evidence from mantle xenoliths from the Dalnyaya kimberlite pipe, Yakutia (Russia)

The Dalnyaya kimberlite pipe (Yakutia, Russia) contains mantle peridotite xenoliths (mostly lherzolites and harzburgites) that show both sheared porphyroclastic (deformed) and coarse granular textures, together with ilmenite and clinopyroxene megacrysts. Deformed peridotites contain high-temperature Fe-rich clinopyroxenes, sometimes associated with picroilmenites, which are products of interaction of the lithospheric mantle with protokimberlite related melts. The orthopyroxene-derived geotherm for the lithospheric mantle beneath Dalnyaya is stepped similar to that beneath the Udachnaya pipe. Coarse granular xenoliths fall on a geotherm of 35 mWm-2 whereas deformed varieties yield a 45 mWm-2 geotherm in the 2–7.5 GPa pressure interval. The chemistry of the constituent minerals including garnet, olivine and clinopyroxene shows trends of increasing Fe# (= Fe/(Fe+Mg) with decreasing pressure. This may suggest that the interaction with fractionating protokimberlite melts occurred at different levels. Two major mantle lithologies are distinguished by the trace element patterns of their constituent minerals, determined by LA-ICP-MS. Orthopyroxenes, some clinopyroxenes and rare garnets are depleted in Ba, Sr, HFSE and MREE and represent relic lithospheric mantle. Re-fertilized garnet and clinopyroxene are more enriched. The distribution of trace elements between garnet and clinopyroxene shows that the garnets dissolved primary orthopyroxene and clinopyroxene. Later high temperature clinopyroxenes related to the protokimberlite melts partially dissolved these garnets. Olivines show decreases in Ni and increases in Al, Ca and Ti from Mg-rich varieties to the more Fe-rich, deformed and refertilized ones. Minerals showing higher Fe# (0.11–0.15) are found within intergrowths of low-Cr ilmenite-clinopyroxene-garnet related to the crystallization of protokimberlite melts in feeder channels. In P-f(O2) diagrams, garnets and Cr-rich clinopyroxenes indicate reduced conditions at the base of the lithosphere at -5 log units below a FMQ buffer. However, Cr-poor clinopyroxenes, together with ilmenite and some Fe-Ca-rich garnets, demonstrate a more oxidized trend in the lower part of lithosphere at -2 to 0 log units relative to FMQ. Clinopyroxenes from xenoliths in most cases show conditions transitional between those determined for garnets and megacrystalline Cr-poor suite. The relatively low diamond grade of Dalnyaya kimberlites is explained by a high degree of interaction with the oxidized protokimberlite melts, which is greater at the base of the lithosphere

Deep-seated xenoliths and xenocrysts from Sytykanskaya pipe: evidence for the evolution of the mantle beneath Alakit, Yakutia, Russia

Heavy mineral concentrate and xenoliths from late autolithic breccia and porphyritic kimberlite of the Sytykanskaya pipe (Alakit field, Yakutia, Russia) were studied by EPMA and LA-ICPMS methods to obtain PTXfO2 diagrams. Trends in P- Fe# - CaO - fO2 for minerals from the porphyritic kimberlite show greater discontinuities than xenocrysts from the breccia. Xenoliths show the widest variation at all pressures. Protokimberlite systems are marked by ilmenite PT points that range from the lithosphere base (7.5 GPa) to a pyroxenite lens situated at intermediate depths (5 - 3.5 GPa) with increasing Cr because of AFC that formed two metasomatic groups with differing Fe#Ol (∼ 10-12 and 13-15). The first Opx-Gar-based mantle geotherm for the Alakit field based on 10 mineral associations is close to the 35 mW/m2 geotherm at 6.5 GPa and 600°C, i.e. near to the Moho. The oxidation state for the megacrystalline ilmenites in the lithosphere base is higher than for other kimberlites in Yakutia. Calculated parental melts for clinopyroxene and garnet by xenocrysts from the breccia show highly inclined linear REE patterns with deep HFSE troughs similar to differentiated protokimberlite magmas. Melts calculated for metasomatic xenoliths have less inclined slopes without troughs in spider diagrams. Garnets reveal S-shaped REE patterns. Calculated melts for garnets from graphite-bearing Cr-websterites located mainly in middle part of the mantle column show slightly inclined convex REE patterns and Ba-Sr troughs with variable enrichment in Nb-Ta-U. The calculated parental melts for clinopyroxenes have inclined REE spectra with a depression in HFSE. Metasomatic clinopyroxenes have enriched patterns with Ba, Zr peaks. 40Ar-39Ar analyses of dispersed phlogopites from the Alakit mantle xenoliths yield a Proterozoic (1154 Ma) age, corresponding to continental arc metasomatism. Alkaline and Ti-rich veins with alkali amphiboles close to richterite formed at ∼1015 Ma and mark a plume event in Rodinia mantle. The∼600-550 Ma stage relates to Rodinia break-up. The last metasomatic event near 385 Ma is related to the protokimberlite

MINERAL COMPOSITION AND PT PARAMETERS OF CRYSTALLIZATION OF MANTLE ROCKS UNDER KIMBERLITE FIELDS OF THE ANABAR REGION

The composition of barophilic minerals from mantle xenoliths and Cpx from concentrates of the Kuranakh, Luchakan, Dyuken, and Ary-Mastakh fields of the Anabar region has been studied. Under these fields, the lithospheric mantle compositions vary significantly. The PT parameters of crystallization were calculated using the composition of clinopyroxenes from xenoliths and heavy fraction of kimberlites. The lithospheric mantle rocks under the northern fields have higher values of Mg# of minerals and calculated mantle geotherm (35–48 mW/m2) compared to the parameters for the southern diamond fields. The pipes from the southwestern part of the Ary-Mastakh field are promising for the diamond potential, presenting Grt-bearing lherzolites and harzburgites with a high content of Cr2O3 (to 8.5 wt. %)

High Water Contents in the Siberian Cratonic Mantle: An FTIR Study of Udachnaya Peridotite Xenoliths

Water is believed to be a key factor controlling the long-term stability of cratonic lithosphere, but mechanisms responsible for the water content distribution in the mantle remain poorly constrained. Water contents were obtained by FTIR in olivine, pyroxene and garnet for 20 well-characterized peridotite xenoliths from the Udachnaya kimberlite (central Siberian craton) and equilibrated at 2-7 GPa. Water contents in minerals do not appear to be related to interaction with the host kimberlite. Diffusion modeling indicates that the core of olivines preserved their original water contents. The Udachnaya peridotites show a broad range of water contents in olivine (6.5 +/- 1.1 to 323 +- 65 ppm H2O (2 sigma)), and garnet (0 - 23 +/- 6 ppm H2O). The water contents of olivine and garnet are positively correlated with modal clinopyroxene, garnet and FeO in olivine. Water-rich garnets are also rich in middle rare earth elements. This is interpreted as the result of interaction between residual peridotites and water rich-melts, consistent with modal and cryptic metasomatism evidenced in the Siberian cratonic mantle. The most water-rich Udachnaya minerals contain 2 to 3 times more water than those from the Kaapvaal craton, the only craton with an intact mantle root for which water data is available. The highest water contents in olivine and orthopyroxene in this study (>= 300 ppm) are found at the bottom of the lithosphere (> 6.5 GPa). This is in contrast with the Kaapvaal craton where the olivines of peridotites equilibrated at > 6.4 GPa have 6 GPa is lower or similar (8.4 10(exp 16) to 8.0 10(exp 18) Pa./s) to that of the asthenosphere (<= 3.7x10(exp 18) Pa./s ). Such lithologies would not be able to resist delamination by the convecting asthenosphere. However, seismology studies as well as the high equilibration pressures of our samples indicate that the Udachnaya cratonic lithosphere is 220-250 km thick. Consequently, the water-rich peridotites are likely not representative of the overall Siberian cratonic lithosphere. Their composition is linked to spatially limited melt metasomatism in mantle regions above asthenospheric upwellings responsible for the kimberlite magmatism prior to their ascent and eruption

СОСТАВ МИНЕРАЛОВ И P-T-ПАРАМЕТРЫ КРИСТАЛЛИЗАЦИИ МАНТИЙНЫХ ПОРОД ПОД КИМБЕРЛИТОВЫМИ ПОЛЯМИ ПРИАНАБАРЬЯ

The composition of barophilic minerals from mantle xenoliths and Cpx from concentrates of the Kuranakh, Luchakan, Dyuken, and Ary-Mastakh fields of the Anabar region has been studied. Under these fields, the lithospheric mantle compositions vary significantly. The PT parameters of crystallization were calculated using the composition of clinopyroxenes from xenoliths and heavy fraction of kimberlites. The lithospheric mantle rocks under the northern fields have higher values of Mg# of minerals and calculated mantle geotherm (35–48 mW/m2) compared to the parameters for the southern diamond fields. The pipes from the southwestern part of the Ary-Mastakh field are promising for the diamond potential, presenting Grt-bearing lherzolites and harzburgites with a high content of Cr2O3 (to 8.5 wt. %).Изучен состав барофильных минералов из мантийных ксенолитов и клинопироксенов из концентратов Куранахского, Лучаканского, Дюкенского и Ары-Мастахского полей Прианабарья. Установлены существенные различия разрезов литосферной мантии под этими полями. По сравнению с южными алмазоносными полями породы литосферной мантии под северными полями отличаются более высокими значениями магнезиальности минералов и более высокими значениями рассчитанной мантийной геотермы (35–48 мВт/м2). Проведена оценка Р-Т-параметров их кристаллизации по составу клинопироксенов из ксенолитов и тяжелой фракции кимберлитов. Согласно изученным составам ксенолитов, наибольшие перспективы на алмазоносность представляет юго-западный участок Ары-Мастахского поля, в котором обнаружены гранатсодержащие лерцолиты и гарцбургиты с высоким содержанием Cr2O3 (до 8.5 мас. %)

SEQUENCE OF AILLIKITE AND CALCITE CARBONATITE FORMATION WITHIN THE BELAYA ZIMA MASSIF, EAST SIBERIA, RUSSIA

The mineralogical and geochemical features, as well as the sequence of formation of aillikite and calcite carbonatite (CC) with pyrochlore are described for the massif of alkaline ultramafic carbonatite complexes Belaya Zima located in East Siberia. Until now, mutually exclusive information presents the temporal relationships of carbonatites and lamprophyres of the Belaya Zima massif.The sample marking the contact of aillikite and CC was comprehensive studied using analytical methods, e.g. XRF (ARL-9900XP spectrometer, ThermoFisher Scientific), ICP-MS (Element Finnigan MAT), SEM (MIRA 3 LMU (Tescan Ltd)), transmission and ore microscopy (AxioScope. A1, Zeiss), 40Ar/39Ar age determination of micas (Argus mass spectrometer, Micromass). The data obtained indicate a later formation of CC relative to aillikites and probable separation of the carbonatite melt from a single picrite-carbonatite source

ПОСЛЕДОВАТЕЛЬНОСТЬ ФОРМИРОВАНИЯ АЙЛИКИТОВ И КАЛЬЦИТОВЫХ КАРБОНАТИТОВ МАССИВА БЕЛАЯ ЗИМА (ВОСТОЧНАЯ СИБИРЬ, РОССИЯ)

The mineralogical and geochemical features, as well as the sequence of formation of aillikite and calcite carbonatite (CC) with pyrochlore are described for the massif of alkaline ultramafic carbonatite complexes Belaya Zima located in East Siberia. Until now, mutually exclusive information presents the temporal relationships of carbonatites and lamprophyres of the Belaya Zima massif.The sample marking the contact of aillikite and CC was comprehensive studied using analytical methods, e.g. XRF (ARL-9900XP spectrometer, ThermoFisher Scientific), ICP-MS (Element Finnigan MAT), SEM (MIRA 3 LMU (Tescan Ltd)), transmission and ore microscopy (AxioScope. A1, Zeiss), 40Ar/39Ar age determination of micas (Argus mass spectrometer, Micromass). The data obtained indicate a later formation of CC relative to aillikites and probable separation of the carbonatite melt from a single picrite-carbonatite source.Для массива ультраосновных щелочных пород и карбонатитов Белая Зима (Восточная Сибирь) описаны минералого-геохимические особенности и последовательность формирования айликитов и кальцитовых карбонатитов (КК) с пирохлором. До настоящего времени о временных взаимоотношениях карбонатитов и лампрофиров массива Белая Зима существуют взаимоисключающие сведения.Проведено комплексное исследование образца, фиксирующего контакт айликита и КК, с применением методов: РФА (спектрометр ARL-9900XP, ThermoFisher Scientific), ИСП-МС (Element Finnigan MAT), СЭМ (MIRA 3 LMU (Tescan Ltd)), просвечивающей и рудной микроскопии (AxioScope. A1, Zeiss), 40Ar/39Ar определения возраста слюд (масс-спектрометр Argus фирмы Micromass). Полученные данные свидетельствуют о более позднем формировании КК относительно айликитов и о вероятном отделении карбонатитового расплава от единого пикрит-карбонатитового источника