250 research outputs found
Synthesis and characterization of biodegradable lignin nanoparticles with tunable surface properties
Lignin nanoparticles can serve as biodegradable carriers of biocidal actives with minimal environmental footprint. Here we describe the colloidal synthesis and interfacial design of nanoparticles with tunable surface properties using two different lignin precursors, Kraft (Indulin AT) lignin and Organosolv (high-purity lignin). The green synthesis process is based on flash precipitation of dissolved lignin polymer, which enabled the formation of nanoparticles in the size range of 45–250 nm. The size evolution of the two types of lignin particles is fitted on the basis of modified diffusive growth kinetics and mass balance dependencies. The surface properties of the nanoparticles are fine-tuned by coating them with a cationic polyelectrolyte, poly(diallyldimethylammonium chloride). We analyze how the colloidal stability and dispersion properties of these two types of nanoparticles vary as a function of pH and salinities. The data show that the properties of the nanoparticles are governed by the type of lignin used and the presence of polyelectrolyte surface coating. The coating allows the control of the nanoparticles’ surface charge and the extension of their stability into strongly basic regimes, facilitating their potential application at extreme pH conditions
Precision Measurement of the Neutron Spin Asymmetry and Spin-Flavor Decomposition in the Valence Quark Region
We have measured the neutron spin asymmetry with high precision at
three kinematics in the deep inelastic region at , 0.47 and 0.60, and
, 3.5 and 4.8 (GeV/c), respectively. Our results unambiguously
show, for the first time, that crosses zero around and becomes
significantly positive at . Combined with the world proton data,
polarized quark distributions were extracted. Our results, in general, agree
with relativistic constituent quark models and with perturbative quantum
chromodynamics (pQCD) analyses based on the earlier data. However they deviate
from pQCD predictions based on hadron helicity conservation.Comment: 5 pages, 2 figures, this is the final version appeared in Phys. Rev.
Let
Determination of the pion charge form factor for Q^2=0.60-1.60 GeV^2
The data analysis for the reaction H(e,e' pi^+)n, which was used to determine
values for the charged pion form factor Fpi for values of Q^2=0.6-1.6 GeV^2,
has been repeated with careful inspection of all steps and special attention to
systematic uncertainties. Also the method used to extract Fpi from the measured
longitudinal cross section was critically reconsidered. Final values for the
separated longitudinal and transverse cross sections and the extracted values
of Fpi are presented.Comment: 11 pages, 6 figure
Charged pion form factor between Q^2=0.60 and 2.45 GeV^2. II. Determination of, and results for, the pion form factor
The charged pion form factor, Fpi(Q^2), is an important quantity which can be
used to advance our knowledge of hadronic structure. However, the extraction of
Fpi from data requires a model of the 1H(e,e'pi+)n reaction, and thus is
inherently model dependent. Therefore, a detailed description of the extraction
of the charged pion form factor from electroproduction data obtained recently
at Jefferson Lab is presented, with particular focus given to the dominant
uncertainties in this procedure. Results for Fpi are presented for
Q^2=0.60-2.45 GeV^2. Above Q^2=1.5 GeV^2, the Fpi values are systematically
below the monopole parameterization that describes the low Q^2 data used to
determine the pion charge radius. The pion form factor can be calculated in a
wide variety of theoretical approaches, and the experimental results are
compared to a number of calculations. This comparison is helpful in
understanding the role of soft versus hard contributions to hadronic structure
in the intermediate Q^2 regime.Comment: 18 pages, 11 figure
Precision Measurement of the Neutron Spin Asymmetries and Spin-dependent Structure Functions in the Valence Quark Region
We report on measurements of the neutron spin asymmetries and
polarized structure functions at three kinematics in the deep
inelastic region, with , 0.47 and 0.60 and , 3.5 and 4.8
(GeV/c), respectively. These measurements were performed using a 5.7 GeV
longitudinally-polarized electron beam and a polarized He target. The
results for and at are consistent with previous world
data and, at the two higher points, have improved the precision of the
world data by about an order of magnitude. The new data show a zero
crossing around and the value at is significantly positive.
These results agree with a next-to-leading order QCD analysis of previous world
data. The trend of data at high agrees with constituent quark model
predictions but disagrees with that from leading-order perturbative QCD (pQCD)
assuming hadron helicity conservation. Results for and have a
precision comparable to the best world data in this kinematic region. Combined
with previous world data, the moment was evaluated and the new result
has improved the precision of this quantity by about a factor of two. When
combined with the world proton data, polarized quark distribution functions
were extracted from the new values based on the quark parton
model. While results for agree well with predictions from various
models, results for disagree with the leading-order pQCD
prediction when hadron helicity conservation is imposed.Comment: A typing error in A_\parallel(3He) at x=0.47 in Table VII of Phys.
Rev. C has been noticed and correcte
Measurement of the Charged Pion Electromagnetic Form Factor
Separated longitudinal and transverse structure functions for the reaction
1H(e,eprime pi+)n were measured in the momentum transfer region Q2=0.6-1.6
(GeV/c)**2 at a value of the invariant mass W=1.95 GeV. New values for the pion
charge form factor were extracted from the longitudinal cross section by using
a recently developed Regge model. The results indicate that the pion form
factor in this region is larger than previously assumed and is consistent with
a monopole parameterization fitted to very low Q2 elastic data.Comment: 5 pages, 3 figure
Charged pion form factor between =0.60 and 2.45 GeV. I. Measurements of the cross section for the H() reaction
Cross sections for the reaction H() were measured in Hall
C at Thomas Jefferson National Accelerator Facility (JLab) using the CEBAF
high-intensity, continous electron beam in order to determine the charged pion
form factor. Data were taken for central four-momentum transfers ranging from
=0.60 to 2.45 GeV at an invariant mass of the virtual photon-nucleon
system of =1.95 and 2.22 GeV. The measured cross sections were separated
into the four structure functions , , , and
. The various parts of the experimental setup and the analysis
steps are described in detail, including the calibrations and systematic
studies, which were needed to obtain high precision results. The different
types of systematic uncertainties are also discussed. The results for the
separated cross sections as a function of the Mandelstam variable at the
different values of are presented. Some global features of the data are
discussed, and the data are compared with the results of some model
calculations for the reaction H().Comment: 26 pages, 23 figure
Separated Response Function Ratios in Exclusive, Forward pi^{+/-} Electroproduction
The study of exclusive electroproduction on the nucleon,
including separation of the various structure functions, is of interest for a
number of reasons. The ratio is
sensitive to isoscalar contamination to the dominant isovector pion exchange
amplitude, which is the basis for the determination of the charged pion form
factor from electroproduction data. A change in the value of
from unity at small , to 1/4 at
large , would suggest a transition from coupling to a (virtual) pion to
coupling to individual quarks. Furthermore, the mentioned ratios may show an
earlier approach to pQCD than the individual cross sections. We have performed
the first complete separation of the four unpolarized electromagnetic structure
functions above the dominant resonances in forward, exclusive
electroproduction on the deuteron at central values of 0.6, 1.0, 1.6
GeV at =1.95 GeV, and GeV at =2.22 GeV. Here, we
present the and cross sections, with emphasis on and , and
compare them with theoretical calculations. Results for the separated ratio
indicate dominance of the pion-pole diagram at low , while results
for are consistent with a transition between pion knockout and quark
knockout mechanisms.Comment: 6 pages, 3 figure
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