5,316 research outputs found
A comparative study of experimental configurations in synchrotron pair distribution function
The identification and quantification of amorphous components and nanocrystalline phases
with very small crystal sizes, smaller than ~3 nm, within samples containing crystalline phases is
very challenging. However, this is important as there are several types of systems that contain these
matrices: building materials, glass-ceramics, some alloys, etc. The total scattering synchrotron pair
distribution function (PDF) can be used to characterize the local atomic order of the nanocrystalline
components and to carry out quantitative analyses in complex mixtures. Although the resolution in
momentum transfer space has been widely discussed, the resolution in the interatomic distance space
has not been discussed to the best of our knowledge. Here, we report synchrotron PDF data collected at
three beamlines in different experimental configurations and X-ray detectors. We not only discuss the
effect of the resolution in Q-space, Qmax ins of the recorded data and Qmax of the processed data, but we
also discuss the resolution in the interatomic distance (real) space. A thorough study of single-phase
crystalline nickel used as standard was carried out. Then, selected cement-related samples including
anhydrous tricalcium and dicalcium silicates, and pastes derived from the hydration of tricalcium
silicate and ye’elimite with bassanite were analyzed.This work is part of the PhD of Mr. Jesus D. Zea-Garcia. This work was supported by Spanish MINECO and FEDER [BIA2017-82391-R research project and I3 [IEDI-2016-0079] program]
Co-evolution of RDF Datasets
Linking Data initiatives have fostered the publication of large number of RDF
datasets in the Linked Open Data (LOD) cloud, as well as the development of
query processing infrastructures to access these data in a federated fashion.
However, different experimental studies have shown that availability of LOD
datasets cannot be always ensured, being RDF data replication required for
envisioning reliable federated query frameworks. Albeit enhancing data
availability, RDF data replication requires synchronization and conflict
resolution when replicas and source datasets are allowed to change data over
time, i.e., co-evolution management needs to be provided to ensure consistency.
In this paper, we tackle the problem of RDF data co-evolution and devise an
approach for conflict resolution during co-evolution of RDF datasets. Our
proposed approach is property-oriented and allows for exploiting semantics
about RDF properties during co-evolution management. The quality of our
approach is empirically evaluated in different scenarios on the DBpedia-live
dataset. Experimental results suggest that proposed proposed techniques have a
positive impact on the quality of data in source datasets and replicas.Comment: 18 pages, 4 figures, Accepted in ICWE, 201
Supersymmetric Flavor Models and the B --> phi K_S Anomaly
We consider the flavor structure of supersymmetric theories that can account
for the deviation of the observed time-dependent CP asymmetry in B --> phi K_S
from the standard model prediction. Assuming simple flavor symmetries and
effective field theory, we investigate possible correlations between sizable
supersymmetric contributions to b --> s transitions and to flavor changing
processes that are more tightly constrained. With relatively few assumptions,
we determine the properties of minimal Yukawa and soft mass textures that are
compatible with the desired supersymmetric flavor-changing effect and
constraints. We then present explicit models that are designed (at least
approximately) to realize these textures. In particular, we present an Abelian
model based on a single U(1) factor and a non-trivial extra-dimensional
topography that can explain the CP asymmetry in B --> phi K_S, while
suppressing other supersymmetric flavor changing effects through a high degree
of squark-quark alignment.Comment: 18 pages LaTeX, 3 eps figure
Response Surface Method to Calculate Energy Savings Associated with Thermal Comfort Improvement in Buildings
In developed countries, a large part of the building stock in 2050 will consist of currently existing buildings. Consequently, in order to achieve the objectives in terms of energy efficiency in the building sector we must consider not only new infrastructures but also the old ones. A reduction in energy consumption for climate control of between 50 and 90% can be achieved by rehabilitation and the implementation of different energy efficiency measures. Currently, these measures to reduce energy consumption and associated CO2 emissions can be modelled using computer tools. However, high precision and detail of thermal behaviour models through simulations can mean a great computational cost for companies, which results in a blockage of servers and workers. In this paper, the Response Surface Methodology (RSM) is presented as an innovative methodology for the simplification of models for calculation of the energy savings associated with thermal comfort improvement in buildings. A single-family house model, located in three different climates, is presented as a case study in order to validate the proposed methodology. Different scenarios were simulated, addressing heating and cooling temperature set points and external wall insulation represented by the transmittance (U-value). Results obtained from energy simulation using Design Builder were contrasted against those estimated from the simplified model extracted from the RSM analysis. The results revealed a deviation lower than 3% when comparing both methods. Therefore, the simplified mathematical prediction models are demonstrated to be suitable for the study of the energy performance of buildings, saving computational time, costs and associated human resources. © 2022 by the authors. Licensee MDPI, Basel, Switzerland
Weak Mixing Angle and Higgs Mass in Gauge-Higgs Unification Models with Brane Kinetic Terms
We show that the idea of Gauge-Higgs unification(GHU) can be rescued from the
constraint of weak mixing angle by introducing localized brane kinetic terms in
higher dimensional GHU models with bulk and simple gauge groups. We find that
those terms lead to a ratio between Higgs and W boson masses, which is a little
bit deviated from the one derived in the standard model. From numerical
analysis, we find that the current lower bound on the Higgs mass tends to
prefer to exceptional groups E(6), E(7), E(8) rather than other groups like
SU(3l), SO(2n+1), G(2), and F(4) in 6-dimensional(D) GHU models irrespective of
the compactification scales. For the compactification scale below 1 TeV, the
Higgs masses in 6D GHU models with SU(3l), SO(2n+1), G(2), and F(4) groups are
predicted to be less than the current lower bound unless a model parameter
responsible for re-scaling SU(2) gauge coupling is taken to be unnaturally
large enough. To see how the situation is changed in more higher dimensional
GHU model, we take 7D S^{3}/ Z_{2} and 8D T^{4}/ Z_{2} models. It turns out
from our numerical analysis that these higher dimensional GHU models with gauge
groups except for E(6) can lead to the Higgs boson whose masses are predicted
to be above the current lower bound only for the compatification scale above 1
TeV without taking unnaturally large value of the model parameter, whereas the
Higgs masses in the GHU models with E(6) are compatible with the current lower
bound even for the compatification scale below 1 TeV.Comment: 22 pages, 4 figure
Z_4 flavor model in Randall-Sundrum model 1
Randall Sundrum models provide a possible explanation of (gauge-gravity)
hierarchy, whereas discrete symmetry flavor groups yield a possible description
of the texture of Standard Model fermion masses. We use both these ingredients
to propose a five-dimensional extension of the Standard Model where the mass
hierarchy of the four-dimensional effective field theory is obtained only using
localizations parameters of order 1. We consider a bulk custodial gauge
symmetry group together with an Abelian group: the model turns out to
yield a rather minimal extension of the SM as it only requires two brane Higgs
fields to provide the desired Yukawa interactions and the required spontaneous
symmetry breaking pattern. In fact, the presence of an extra-dimension allows
the use of the Scherk-Schwarz mechanism to contribute to the breaking of the
bulk custodial group down to the SM gauge symmetry. Moreover, no right-handed
neutrinos are present and neutrino masses are generated radiatively with the
help of a bulk charged scalar field that provides the Lepton-number violation.
Using experimental inputs from the Global Neutrino Analysis and recent Daya Bay
results, a numerical analysis is performed and allowed parameter regions are
displayed.Comment: 23 pages, 3 figures. A brief discussion on contribution from higher
order operators has been added, a few typos corrected and references added.
Version to appear in Phys. Rev.
Elongation and fluctuations of semi-flexible polymers in a nematic solvent
We directly visualize single polymers with persistence lengths ranging from
to 16 m, dissolved in the nematic phase of rod-like {\it fd}
virus. Polymers with sufficiently large persistence length undergo a coil-rod
transition at the isotropic-nematic transition of the background solvent. We
quantitatively analyze the transverse fluctuations of semi-flexible polymers
and show that at long wavelengths they are driven by the fluctuating nematic
background. We extract both the Odijk deflection length and the elastic
constant of the background nematic phase from the data.Comment: 4 pages, 4 figures, submitted to PR
Orthogonal U(1)'s, Proton Stability and Extra Dimensions
In models with a low quantum gravity scale, one might expect that all
operators consistent with gauge symmetries are present in the low-energy
effective theory. If this is the case, some mechanism must be present to
adequately suppress operators that violate baryon number. Here we explore the
possibility that the desired suppression is a consequence of an additional,
spontaneously-broken, non-anomalous U(1) symmetry that is orthogonal to
hypercharge. We show that successful models can be constructed in which the
additional particle content necessary to cancel anomalies is minimal, and
compatible with the constraints from precision electroweak measurements and
gauge unification. If unification is sacrificed, and only the new U(1) and its
associated Higgs fields live in the bulk, it is possible that the gauge field
zero mode and first few Kaluza-Klein excitations lie within the kinematic reach
of the Tevatron. For gauge couplings not much smaller than that of hypercharge,
we show that these highly leptophobic states could evade detection at Run I,
but be discovered at Run II. Our scenario presents an alternative to the
`cartographic' solution to baryon number violation in which leptons and quarks
are separated in an extra dimension.Comment: 16 pages LaTeX, 4 figure
2D Corrugated Magnesium Carboxyphosphonate Materials: Topotactic Transformations and Interlayer “Decoration” with Ammonia
In this paper we report the synthesis and structural characterization of the 2D layered coordination polymer Mg(BPMGLY)(H2O)2 (BPMGLY = bis-phosphonomethylglycine, (HO3PCH2)2N(H)COO2−). The Mg ion is found in a slightly distorted octahedral environment formed by four phosphonate oxygens and two water molecules. The carboxylate group is deprotonated but noncoordinated. This compound is a useful starting material for a number of topotactic transformations. Upon heating at 140 °C one (of the two) Mg-coordinated water molecule is lost, with the archetype 2D structure maintaining itself. However, the octahedral Mg in Mg(BPMGLY)(H2O)2 is now converted to trigonal bipyramidal in Mg(BPMGLY)(H2O). Upon exposure of the monohydrate Mg(BPMGLY)(H2O) compound to ammonia, one molecule of ammonia is inserted into the interlayer space and stabilized by hydrogen bonding. The 2D layered structure of the product Mg(BPMGLY)(H2O)(NH3) is still maintained, with Mg now acquiring a pseudo-octahedral environment. All of these topotactic transformations are also accompanied by changes in hydrogen bonding between the layers.Proyecto nacional MAT2010-1517
Unusual T_c variation with hole concentration in Bi_2Sr_{2-x}La_xCuO_{6+\delta}
We have investigated the variation with the hole concentration in
the La-doped Bi 2201 system, BiSrLaCuO. It is
found that the Bi 2201 system does not follow the systematics in and
observed in other high- cuprate superconductors (HTSC's). The vs
characteristics are quite similar to what observed in Zn-doped HTSC's. An
exceptionally large residual resistivity component in the inplane resistivity
indicates that strong potential scatterers of charge carriers reside in CuO
planes and are responsible for the unusual variation with , as in the
Zn-doped systems. However, contrary to the Zn-doped HTSC's, the strong scatter
in the Bi 2201 system is possibly a vacancy in the Cu site.Comment: RevTeX, 3 figures, to be published in the Physical Review
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