12,160 research outputs found
Long-lived oscillatory incoherent electron dynamics in molecules: trans-polyacetylene oligomers
We identify an intriguing feature of the electron-vibrational dynamics of
molecular systems via a computational examination of \emph{trans}-polyacetylene
oligomers. Here, via the vibronic interactions, the decay of an electron in the
conduction band resonantly excites an electron in the valence band, and vice
versa, leading to oscillatory exchange of electronic population between two
distinct electronic states that lives for up to tens of picoseconds. The
oscillatory structure is reminiscent of beating patterns between quantum states
and is strongly suggestive of the presence of long-lived molecular electronic
coherence. Significantly, however, a detailed analysis of the electronic
coherence properties shows that the oscillatory structure arises from a purely
incoherent process. These results were obtained by propagating the coupled
dynamics of electronic and vibrational degrees of freedom in a mixed
quantum-classical study of the Su-Schrieffer-Heeger Hamiltonian for
polyacetylene. The incoherent process is shown to occur between degenerate
electronic states with distinct electronic configurations that are indirectly
coupled via a third auxiliary state by the vibronic interactions. A discussion
of how to construct electronic superposition states in molecules that are truly
robust to decoherence is also presented
Glass formation, properties, and structure of soda-yttria-silicate glasses
The glass formation region of the soda yttria silicate system was determined. The glasses within this region were measured to have a density of 2.4 to 3.1 g/cu cm, a refractive index of 1.50 to 1.60, a coefficient of thermal expansion of 7 x 10(exp -6)/C, softening temperatures between 500 and 780 C, and Vickers hardness values of 3.7 to 5.8 GPa. Aqueous chemical durability measurements were made on select glass compositions while infrared transmission spectra were used to study the glass structure and its effect on glass properties. A compositional region was identified which exhibited high thermal expansion, high softening temperatures, and good chemical durability
The impact of active workstations on workplace productivity and performance: a systematic review
Active workstations have been recommended for reducing sedentary behavior in the workplace. It is important to understand if the use of these workstations has an impact on worker productivity. The aim of this systematic review was to examine the effect of active workstations on workplace productivity and performance. A total of 3303 articles were initially identified by a systematic search and seven articles met eligibility criteria for inclusion. A quality appraisal was conducted to assess risk of bias, confounding, internal and external validity, and reporting. Most of the studies reported cognitive performance as opposed to productivity. Five studies assessed cognitive performance during use of an active workstation, usually in a single session. Sit-stand desks had no detrimental effect on performance, however, some studies with treadmill and cycling workstations identified potential decreases in performance. Many of the studies lacked the power required to achieve statistical significance. Three studies assessed workplace productivity after prolonged use of an active workstation for between 12 and 52 weeks. These studies reported no significant effect on productivity. Active workstations do not appear to decrease workplace performance
Joint Constraint Modelling Using Evolved Topology Generalized Multi-Layer Perceptron(GMLP)
The accurate simulation of anatomical joint models is important for both medical diagnosis and realistic animation applications. Quaternion algebra has been increasingly applied to model rotations providing a compact representation while avoiding singularities. This paper describes the application of artificial neural networks topologically evolved using genetic algorithms to model joint constraints directly in quaternion space. These networks are trained (using resilient back propagation) to model discontinuous vector fields that act as corrective functions ensuring invalid joint configurations are accurately corrected. The results show that complex quaternion-based joint constraints can be learned without resorting to reduced coordinate models or iterative techniques used in other quaternion based joint constraint approaches
Impacts of fuel consumption taxes on mobility patterns and CO2 emissions using a system dynamic approach
Current transport behaviour leads to increasing congestion of the infrastructure, growing dependence on fossil fuels, increasing energy demand, and growing CO2 emissions. Policies based principally on increasing system speed and in particular car speeds will lead to greater urban sprawl with increases in average trip lengths. Time saved by speed increases are traded for more distance. This trend is not sustainable in the longer term. Transport policies based just on time savings for citizens may not be the basis for our city planning strategy. The same happens with transport cost. With underpriced transport, the market undervalues land use location, which again may lead city to sprawl and could induce greater trip lengths. In this study, the efficiency of a fuel consumption or CO2 tax policy is analysed as a policy to internalise externalities of transport in a fair travel cost. Based on system dynamics theory, an integrated land use and transport model is proposed in order to assess the effects and impacts of such policy in the short, medium and long term. Different scenarios related to clean vehicles are incorporated. This model is applied to three cities Madrid, Vienna and Leeds and compares their results
Testable two-loop radiative neutrino mass model based on an effective operator
A new two-loop radiative Majorana neutrino mass model is constructed from the
gauge-invariant effective operator that violates lepton number conservation by two units. The
ultraviolet completion features two scalar leptoquark flavors and a color-octet
Majorana fermion. We show that there exists a region of parameter space where
the neutrino oscillation data can be fitted while simultaneously meeting
flavor-violation and collider bounds. The model is testable through lepton
flavor-violating processes such as , , and
conversion, as well as collider searches for the scalar
leptoquarks and color-octet fermion. We computed and compiled a list of
necessary Passarino-Veltman integrals up to boxes in the approximation of
vanishing external momenta and made them available as a Mathematica package,
denoted as ANT.Comment: 42 pages, 11 figures, typo in Eq. (4.9) as well as wrong chirality
structures in Secs. 4.5 and 5.2 corrected, final results unchange
How a Christian Worldview Enhances and Interacts with Academic Service Learning
Abstract
This study assesses how a Christian worldview enhances and interacts with academic service learning. It explains the importance of a Christian worldview and development at the undergraduate level. Faith integration is a distinctive to Christian higher education as part of attaining course objectives and fulfilling the mission of the institution. It considers academic service learning as a tool for teaching and learning in pre-service teacher education with faith integration. Findings explain the interaction of Christian worldview and academic service learning informing university student’s perceptions of teaching and understanding of students with special needs. Quantitative research methods demonstrate that academic service learning can inform pre-service teachers through interaction with Christian worldview. Qualitative research methods produce findings indicating that pre-service teachers understand Christian worldview and an enhanced view of students. Conclusions suggest utilizing academic service learning as a tool for faith integration positively influences undergraduate student’s development of a Christian worldview.
Keywords: Christian Worldview, Service learning, Faith Integratio
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