Evaluating the Roles of Rainout and Post-Condensation Processes in a Landfalling Atmospheric River with Stable Isotopes in Precipitation and Water Vapor

Atmospheric rivers (ARs), and frontal systems more broadly, tend to exhibit prominent “V” shapes in time series of stable isotopes in precipitation. Despite the magnitude and widespread nature of these “V” shapes, debate persists as to whether these shifts are driven by changes in the degree of rainout, which we determine using the Rayleigh distillation of stable isotopes, or by post-condensation processes such as below-cloud evaporation and equilibrium isotope exchange between hydrometeors and surrounding vapor. Here, we present paired precipitation and water vapor isotope time series records from the 5–7 March 2016, AR in Bodega Bay, CA. The stable isotope composition of surface vapor along with independent meteorological constraints such as temperature and relative humidity reveal that rainout and post-condensation processes dominate during different portions of the event. We find that Rayleigh distillation controls during peak AR conditions (with peak rainout of 55%) while post-condensation processes have their greatest effect during periods of decreased precipitation on the margins of the event. These results and analyses inform critical questions regarding the temporal evolution of AR events and the physical processes that control them at local scales

Cold dark matter models with high baryon content

Recent results have suggested that the density of baryons in the Universe, OmegaB, is much more uncertain than previously thought, and may be significantly higher. We demonstrate that a higher OmegaB increases the viability of critical-density cold dark matter (CDM) models. High baryon fraction offers the twin benefits of boosting the first peak in the microwave anisotropy power spectrum and of suppressing short-scale power in the matter power spectrum. These enable viable CDM models to have a larger Hubble constant than otherwise possible. We carry out a general exploration of high OmegaB CDM models, varying the Hubble constant h and the spectral index n. We confront a variety of observational constraints and discuss specific predictions. Although some observational evidence may favour baryon fractions as high as 20 per cent, we find that values around 10 to 15 per cent provide a reasonable fit to a wide range of data. We suggest that models with OmegaB in this range, with h about 0.5 and n about 0.8, are currently the best critical-density CDM models.Comment: 14 pages, LaTeX, with 9 included figures, to appear in MNRAS. Revised version includes updated references, some changes to section 4. Conclusions unchange

The ATPase cycle of PcrA helicase and its coupling to translocation on DNA.

The superfamily 1 bacterial helicase PcrA has a role in the replication of certain plasmids, acting with the initiator protein (RepD) that binds to and nicks the double-stranded origin of replication. PcrA also translocates single-stranded DNA with discrete steps of one base per ATP hydrolyzed. Individual rate constants have been determined for the DNA helicase PcrA ATPase cycle when bound to either single-stranded DNA or a double-stranded DNA junction that also has RepD bound. The fluorescent ATP analogue 2'(3')-O-(N-methylanthraniloyl)ATP was used throughout all experiments to provide a complete ATPase cycle for a single nucleotide species. Fluorescence intensity and anisotropy stopped-flow measurements were used to determine rate constants for binding and release. Quenched-flow measurements provided the kinetics of the hydrolytic cleavage step. The fluorescent phosphate sensor MDCC-PBP was used to measure phosphate release kinetics. The chemical cleavage step is the rate-limiting step in the cycle and is essentially irreversible and would result in the bound ATP complex being a major component at steady state. This cleavage step is greatly accelerated by bound DNA, producing the high activation of this protein compared to the protein alone. The data suggest the possibility that ADP is released in two steps, which would result in bound ADP also being a major intermediate, with bound ADP.P(i) being a very small component. It therefore seems likely that the major transition in structure occurs during the cleavage step, rather than P(i) release. ATP rebinding could then cause reversal of this structural transition. The kinetic mechanism of the PcrA ATPase cycle is very little changed by potential binding to RepD, supporting the idea that RepD increases the processivity of PcrA by increasing affinity to DNA rather than affecting the enzymatic properties per se

Atomic spectrometry update. Clinical and biological materials, foods and beverages

This review discusses developments in elemental mass spectrometry, atomic absorption, emission and fluorescence, XRF and LIBS, as applied to the analysis of specimens of clinical interest, foods and beverages. Sample preparation procedures and quality assurance are also included.</p

Understanding Slow Growth in the Adoption of E-Textbooks: Distinguishing Paper and Electronic Delivery of Course Content

E-textbooks have experienced a lower than anticipated rate of adoption among college students. Studies consistently show a student preference for paper versus e-textbooks. When seeking an explanation for the continued reluctance of students to adopt e-textbooks, it is necessary to consider e-textbooks as a technological innovation. This is an exploratory study of the first year of a pilot program during which 991 students in 9 core courses in the Virginia State University (VSU) Reginald F. Lewis College of Business (RFLCB) replaced traditional textbooks with openly licensed e-textbooks. A questionnaire was administered to students who had participated in the e-textbook pilot study in the second semester of the implementation. The adoption process was examined using Venkatesh’s Unified Theory of Acceptance and Use of Technology (UTAUT) as a framework. The questions in the survey were categorized to represent performance expectancy and effort expectancy; two of the four primary constructs in the UTAUT. In accordance with the UTAUT framework, the moderating variables, age, experience, gender and voluntariness, were cross-tabulated with these constructs to see how the moderating factors might influence adoption of digital textbooks. Results show that student gender and voluntariness, as expressed as reported time spent with e-textbook, need to be taken into account when implementing technological innovations such as an e-textbook initiative

Robust interferometer for the routing of light beams carrying orbital angular momentum

We have developed an interferometer requiring only minimal angular alignment for the routing of beams carrying orbital angular momentum. The Mach–Zehnder interferometer contains a Dove prism in each arm where each has a mirror plane around which the transverse phase profile is inverted. One consequence of the inversions is that the interferometer needs no alignment. Instead the interferometer defines a unique axis about which the input beam must be coupled. Experimental results are presented for the fringe contrast, reaching a maximum value of 93±1%