A review of history and geographical distribution of grapevine moths in Italian vineyards in light of climate change: looking backward to face the future

Tortricid and pyralid moths include important pests of vineyards. This review offers a retrospective analysis of the geographic distribution expansion of the European grapevine moth, Lobesia botrana (Denis & Schiffermüller) (Lepidoptera: Tortricidae) and the replacement or marginalization of the importance of the previously largely vine-infesting species, i.e., Sparganothis pilleriana (Denis & Schiffermüller) and Eupoecilia ambiguella (Hübner), because of the combination and interaction between climate change, invasive alien species, and new cultivation techniques. Herein, we have focused on the case study of Italy, which is currently representing the fourth largest country in the world in terms of cultivated wine-growing area, and the biggest producer of wine grapes, as a model to analyze the possible influence of climate change on the occurrence and harmfulness of grapevine moths and what will be the next challenges for their sustainable management. Starting from the retrospective analysis and learned lessons, a research agenda outlining future challenges for IPM of grapevine moth pests in Medi terranean countries is developed

Sustainable management of the vine mealybug in organic vineyards

The vine mealybug (VMB), Planococcus ficus, is a major grapevine pest worldwide, whose chemical control is often unsatisfactory due to its cryptic behavior, insecticide resistance and high fecundity rate. Recently, increasing restrictions have been applied to insecticides used for managing VMB. This review discusses sustainable VMB management strategies in organic viticulture. Pheromone-mediated mating disruption has been proved to be effective in both organic wine and table-grape vineyards. Biocontrol projects carried out through the release of parasitoids and/or predators have often provided inconclusive results, ranging from effective reduction of mealybug infestation to a marginal impact of parasitoids on VMB density. The latter outcome is likely due to constraints affecting the parasitoid activity, such as the disrupting activity of mealybug-tending ants and broad-spectrum insecticides, or untimely release of parasitoids. Ant suppression should be associated with the release of beneficial organisms, as mealybug-tending ants can severely affect the parasitoid activity. Cultural and physical control and the employment of entomopathogens and natural products mitigate the buildup of VMB populations, but they are not widely applied. VMB control in organic viticulture requires the integration of different strategies, as application of single control tools as a stand-alone treatment may not be effective, especially for high pest infestation. Future research to determine the density action threshold below which sustainable methods are effective and calibrate efforts in relation with pest infestation is needed. A multi-disciplinary approach is required to define the most appropriate sustainable control protocols in different environmental conditions and promote a further spread of organic viticulture

Morphology, thermal, mechanical properties and ageing of nylon 6,6/graphene nanofibers as Nano2 materials

Nylon 6,6 nanofibers loaded with different Graphene (G) amounts were successfully produced with stable process and good fiber quality, using an optimized solvent system suitable both for electrospinning and for G-suspension. G addition is found to significantly affect diameter but not thermal behaviour. A new phenomenological model is proposed for the interpretation of mechanical behaviour of nanofibrous mat, trying to take into account the nanofibrous morphology. The model highlights a G contribution to mechanical properties that mainly affects the initial steps of deformation where fibers stretch, slide, twist and re-orient. Finally, the nanofibers were analysed after 20 months ageing, showing no significant alteration with respect to the pristine ones, thus the lack of detrimental ageing-effects due to G addition

Water-Resistant Photo-Crosslinked PEO/PEGDA Electrospun Nanofibers for Application in Catalysis

Catalysts are used for producing the vast majority of chemical products. Usually, catalytic membranes are inorganic. However, when dealing with reactions conducted at low temperatures, such as in the production of fine chemicals, polymeric catalytic membranes are preferred due to a more competitive cost and easier tunability compared to inorganic ones. In the present work, nanofibrous mats made of poly(ethylene oxide), PEO, and poly(ethylene glycol) diacrylate, PEGDA, blends with the Au/Pd catalyst are proposed as catalytic membranes for water phase and low-temperature reactions. While PEO is a water-soluble polymer, its blending with PEGDA can be exploited to make the overall PEO/PEGDA blend nanofibers water-resistant upon photo-crosslinking. Thus, after the optimization of the blend solution (PEO molecular weight, PEO/PEGDA ratio, photoinitiator amount), electrospinning process, and UV irradiation time, the resulting nanofibrous mat is able to maintain the nanostructure in water. The addition of the Au-6/Pd-1 catalyst (supported on TiO2) in the PEO/PEGDA blend allows the production of a catalytic nanofibrous membrane. The reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP), taken as a water phase model reaction, demonstrates the potential usage of PEO-based membranes in catalysis

Rubbery nanofibrous interleaves enhance fracture toughness and damping of CFRP laminates

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How Nanofibers Carry the Load: Toward a Universal and Reliable Approach for Tensile Testing of Polymeric Nanofibrous Membranes

Nanofibrous nonwovens show high versatility and outstanding properties, with reduced weight. Porous morphology, high material flexibility and deformability challenge their mechanical testing, severely affecting results reliability. Still today, a specific technical standard method to carry out tensile testing of nonwoven nanofibrous mats is lacking, as well as studies concerning tensile test data reliability. In this work, an accurate, systematic, and critical study is presented concerning tensile testing of nonwovens, using electrospun Nylon 66 random nanofibrous mats as a case study. Nanofibers diameter and specimen geometry are investigated to thoroughly describe the nanomat tensile behavior, also considering the polymer thermal properties, and the nanofibers crossings number as a function of the nanofibers diameter. Below a threshold value, which lies between 150 and 250 nm, the overall mat mechanical behavior changes from ductile to brittle, showing enhanced elastic modulus for a high number of nanofibers crossings. While specimen geometry does not affect tensile results. Stress\u2013strain data are analyzed using a phenomenological data fitting model to better interpret the tensile behavior. The experimental results demonstrate the high reliability of the proposed mass-based load normalization, providing a simple, effective, and universally suitable method for obtaining high reproducible tensile stress\u2013strain curves

How Nanofibers Carry the Load: Toward a Universal and Reliable Approach for Tensile Testing of Polymeric Nanofibrous Membranes

Nanofibrous nonwovens show high versatility and outstanding properties, with reduced weight. Porous morphology, high material flexibility and deformability challenge their mechanical testing, severely affecting results reliability. Still today, a specific technical standard method to carry out tensile testing of nonwoven nanofibrous mats is lacking, as well as studies concerning tensile test data reliability. In this work, an accurate, systematic, and critical study is presented concerning tensile testing of nonwovens, using electrospun Nylon 66 random nanofibrous mats as a case study. Nanofibers diameter and specimen geometry are investigated to thoroughly describe the nanomat tensile behavior, also considering the polymer thermal properties, and the nanofibers crossings number as a function of the nanofibers diameter. Below a threshold value, which lies between 150 and 250 nm, the overall mat mechanical behavior changes from ductile to brittle, showing enhanced elastic modulus for a high number of nanofibers crossings. While specimen geometry does not affect tensile results. Stress–strain data are analyzed using a phenomenological data fitting model to better interpret the tensile behavior. The experimental results demonstrate the high reliability of the proposed mass-based load normalization, providing a simple, effective, and universally suitable method for obtaining high reproducible tensile stress–strain curves

Risk factors for discontinuing oral immunotherapy in children with persistent cow milk allergy

Background: There are no universally accepted criteria for discontinuing milk oral immunotherapy (MOIT) in patients with persistent cow milk allergy (CMA) and little data are available on predictive risk factors for dropping out from oral immunotherapy (OIT), due to allergic reactions or other reasons. Methods: We retrospectively reviewed clinical records of patients with persistent severe CMA undergoing MOIT in a tertiary care center hospital to investigate risk factors associated with discontinuation of OIT. Persistent and severe allergy was defined as the history of systemic reactions and any milk protein-specific IgE level >85 kU/ml. All patients were first admitted for an in-hospital rush phase eventually followed by an at-home dose increase. We evaluated the effect of various factors on two primary outcomes: the highest dose of milk ingested during the in-hospital rush phase and during the home OIT phase. Results: We identified 391 patients, of whom 131 met the inclusion criteria for the retrospective study, 54 females and 77 males. Data of the home OIT phase were available for 104 patients (27%). Regarding the home OIT outcome, an association for having a cow milk avoiding diet was found with reaching a dose below 10 ml during the in-hospital rush phase (relative risks [RR]: 2.33, confidence interval [CI]: 0.85; 6.42), an age above than 10 years from the time of admission (RR: 3.29, CI: 0.85; 12.73), and a higher total number of reactions occurred during the hospitalization (RR: 1.54, CI: 1.02; 2.32), whereas the presence of respiratory reactions with wheezing (RR: 1.93, CI: 0.49; 7.61) and an IM adrenaline use was related to a higher risk of having an OIT still in progress (RR: 5.47, CI: 0.33; 7.73). Conclusions: In this cohort of children with persistent CMA undergoing OIT who presented with respiratory reactions with wheezing, the development of anaphylaxis with the need for IM adrenaline, and age above 10 years were predictors of poor long-term outcome