Valley relaxation in graphene due to charged impurities

Monolayer graphene is an example of materials with multi-valley electronic structure. In such materials, the valley index is being considered as an information carrier. Consequently, relaxation mechanisms leading to loss of valley information are of interest. Here, we calculate the rate of valley relaxation induced by charged impurities in graphene. A special model of graphene is applied, where the $p_z$ orbitals are two-dimensional Gaussian functions, with a spatial extension characterised by an effective Bohr radius $a_\textrm{eB}$. We obtain the valley relaxation rate by solving the Boltzmann equation, for the case of noninteracting electrons, as well as for the case when the impurity potential is screened due to electron-electron interaction. For the latter case, we take into account local-field effects and evaluate the dielectric matrix in the random phase approximation. Our main findings: (i) The valley relaxation rate is proportional to the electronic density of states at the Fermi energy. (ii) Charged impurities located in the close vicinity of the graphene plane, at distance $d \lesssim 0.3\,\textrm{\AA}$, are much more efficient in inducing valley relaxation than those farther away, the effect of the latter being suppressed exponentially with increasing graphene-impurity distance $d$. (iii) Both in the absence and in the presence of electron-electron interaction, the valley relaxation rate shows pronounced dependence on the effective Bohr radius $a_\textrm{eB}$. The trends are different in the two cases: in the absence (presence) of screening, the valley relaxation rate decreases (increases) for increasing effective Bohr radius. This last result highlights that a quantitative calculation of the valley relaxation rate should incorporate electron-electron interactions as well as an accurate knowledge of the electronic wave functions on the atomic length scale.Comment: 15 pages, 8 figure

Orbital hyperfine interaction and qubit dephasing in carbon nanotube quantum dots

Hyperfine interaction (HF) is of key importance for the functionality of solid-state quantum information processing, as it affects qubit coherence and enables nuclear-spin quantum memories. In this work, we complete the theory of the basic hyperfine interaction mechanisms (Fermi contact, dipolar, orbital) in carbon nanotube quantum dots by providing a theoretical description of the orbital HF. We find that orbital HF induces an interaction between the nuclear spins of the nanotube lattice and the valley degree of freedom of the electrons confined in the quantum dot. We show that the resulting nuclear-spin--electron-valley interaction (i) is approximately of Ising type, (ii) is essentially local, in the sense that a radius- and dot-length-independent atomic interaction strength can be defined, and (iii) has an atomic interaction strength that is comparable to the combined strength of Fermi contact and dipolar interactions. We argue that orbital HF provides a new decoherence mechanism for single-electron valley qubits and spin-valley qubits in a range of multi-valley materials. We explicitly evaluate the corresponding inhomogeneous dephasing time $T_2^*$ for a nanotube-based valley qubit.Comment: 7 pages, 3 figure

Maximal Rabi frequency of an electrically driven spin in a disordered magnetic field

We present a theoretical study of the spin dynamics of a single electron confined in a quantum dot. Spin dynamics is induced by the interplay of electrical driving and the presence of a spatially disordered magnetic field, the latter being transverse to a homogeneous magnetic field. We focus on the case of strong driving, i.e., when the oscillation amplitude $A$ of the electron's wave packet is comparable to the quantum dot length $L$. We show that electrically driven spin resonance can be induced in this system by subharmonic driving, i.e., if the excitation frequency is an integer fraction (1/2, 1/3, etc) of the Larmor frequency. At strong driving we find that (i) the Rabi frequencies at the subharmonic resonances are comparable to the Rabi frequency at the fundamental resonance, and (ii) at each subharmonic resonance, the Rabi frequency can be maximized by setting the drive strength to an optimal, finite value. Our simple model is applied to describe electrical control of a spin-valley qubit in a weakly disordered carbon nanotube.Comment: 5 pages, 2 figure

Hyperfine-induced valley mixing and the spin-valley blockade in carbon-based quantum dots

Hyperfine interaction (HFI) in carbon nanotube and graphene quantum dots is due to the presence of 13C atoms. We theoretically show that in these structures the short-range nature of the HFI gives rise to a coupling between the valley degree of freedom of the electron and the nuclear spin, in addition to the usual electron spin-nuclear spin coupling. We predict that this property of the HFI affects the Pauli blockade transport in carbon-based double quantum dots. In particular, we show that transport is blocked only if both the spin and the valley degeneracies of the quantum dot levels are lifted, e.g., by an appropriately oriented magnetic field. The blockade is caused by four "supertriplet" states in the (1,1) charge configuration.Comment: 5 pages, 3 figures; v2: published versio

Rashba billiards

We study the energy levels of non-interacting electrons confined to move in two-dimensional billiard regions and having a spin-dependent dynamics due to a finite Rashba spin splitting. The Green's function for such Rashba billiards is constructed analytically and used to find the area and perimeter contributions to the density of states, as well as the smooth counting function. We show that, in contrast to systems with spin-rotational invariance, Rashba billiards always possess a negative energy spectrum. A semi-classical analysis is presented to interpret the singular behavior of the density of states at certain negative energies. Our detailed analysis of the spin structure of Rashba billiards reveals a finite out-of-plane spin projection for electron eigenstates.Comment: 12 pages, 6 figures, minor changes in the text, submitted to PR

Electron-electron attraction in an engineered electromechanical system

Two electrons in a quantum dot repel each other: their interaction can be characterized by a positive interaction energy. From the theory of superconductivity, we also know that mechanical vibrations of the crystal lattice can make the electron-electron interaction attractive. Analogously, if a quantum dot interacts with a mechanical degree of freedom, the effective interaction energy can be negative; that is, the electron-electron interaction might be attractive. In this work, we propose and theoretically study an engineered electromechanical system that exhibits electron-electron attraction: a quantum dot suspended on a nonlinear mechanical resonator, tuned by a bottom and a top gate electrode. We focus on the example of a dot embedded in a suspended graphene ribbon, for which we identify conditions for electron-electron attraction. Our results suggest the possibility of electronic transport via tunneling of packets of multiple electrons in such devices, similar to that in superconducting nanostructures, but without the use of any superconducting elements.Comment: 9 pages, 4 figure

Subharmonic transitions and Bloch-Siegert shift in electrically driven spin resonance

We theoretically study coherent subharmonic (multi-photon) transitions of a harmonically driven spin. We consider two cases: magnetic resonance (MR) with a misaligned, i.e., non-transversal driving field, and electrically driven spin resonance (EDSR) of an electron confined in a one-dimensional, parabolic quantum dot, subject to Rashba spin-orbit interaction. In the EDSR case, we focus on the limit where the orbital level spacing of the quantum dot is the greatest energy scale. Then, we apply time-dependent Schrieffer-Wolff erturbation theory to derive a time-dependent effective two-level Hamiltonian, allowing to describe both MR and EDSR using the Floquet theory of periodically driven two-level systems. In particular, we characterise the fundamental (single-photon) and the half-harmonic (two-photon) spin transitions. We demonstrate the appearance of two-photon Rabi oscillations, and analytically calculate the fundamental and half-harmonic resonance frequencies and the corresponding Rabi frequencies. For EDSR, we find that both the fundamental and the half-harmonic resonance frequency changes upon increasing the strength of the driving electric field, which is an effect analogous to the Bloch-Siegert shift known from MR. Remarkably, the drive-strength dependent correction to the fundamental EDSR resonance frequency has an anomalous, negative sign, in contrast to the corresponding Bloch-Siegert shift in MR which is always positive. Our analytical results are supported by numerical simulations, as well as by qualitative interpretations for simple limiting cases.Comment: 16 pages, 7 figure

Probing individual split Cooper-pairs using the spin qubit toolkit

A superconductor is a natural source of spin-entangled spatially separated electron pairs. Although the first Cooper-pair splitter devices have been realized recently, an experimental confirmation of the spin state and the entanglement of the emitted electron pairs is lacking up to now. In this paper a method is proposed to confirm the spin-singlet character of individual split Cooper pairs. Two quantum dots (QDs), each of them holding one spin-prepared electron, serve as the detector of the spin state of a single Cooper pair that is forced to split when it tunnels out from the superconductor to the QDs. The number of charges on the QDs, measured at the end of the procedure, carries information on the spin state of the extracted Cooper pair. The method relies on the experimentally established toolkit of QD-based spin qubits: resonant spin manipulation, Pauli blockade, and charge measurement.Comment: 15 pages, 7 figure