Perfect category-graded algebras

In a perfect category every object has a minimal projective resolution. We give a criterion for the category of modules over a categorygraded algebra to be perfect.Comment: A sufficient condition is replaced by a criterion. Several references added. 17 page

A comparison between gravimetric and in-situ spectroscopic methods to measure the sorption of CO₂in a biocompatible polymer

In situ ATR-IR spectroscopy was used to simultaneously measure the sorption and swelling of carbon dioxide at high pressures in a biocompatible acrylate copolymer poly(methylmethacrylate-co-ethylhexylacrylate-co-ethyleneglycoldimethacrylate), P(MMA–EHA–EGDMA). The ν3 band of CO2 dissolved in the polymer (at 2335 cm−1) was used to calculate the sorption data and the polymer swelling was determined by analyzing the changes in the absorbance of the ν(C O) band (at 1730 cm−1) of the polymer. Transmission spectroscopy in the near-IR region was also used to study the sorption of CO2 in the polymer using combinational and overtone bands. The experiments were carried out in a pressure range of 2.0–12.0MPa and in a temperature range of 27–40 ◦C. The data for CO2 sorption in this polymer obtained by in situ spectroscopic methods have been compared to the data obtained by the gravimetric technique

A Spatially Robust ICA Algorithm for Multiple fMRI Data Sets

In this paper we derive an independent-component analysis (ICA) method for analyzing two or more data sets simultaneously. Our model extracts independent components common to all data sets and independent data-set-specific components. We use time-delayed autocorrelations to obtain independent signal components and base our algorithm on prediction analysis. We applied this method to functional brain mapping using functional magnetic resonance imaging (fMRI). The results of our 3-subject analysis demonstrate the robustness of the algorithm to the spatial misalignment intrinsic in multiple-subject fMRI data sets. 1

Enhanced photovoltaic performance of inverted hybrid bulk-heterojunction solar cells using TiO2/reduced graphene oxide films as electron transport layers

In this study, we investigated inverted hybrid bulk-heterojunction solar cells with the following configuration: fluorine-doped tin oxide (FTO) |TiO2/RGO|P3HT:PC61BM|V2O5 or PEDOT:PSS|Ag. The TiO2/GO dispersions were prepared by sol-gel method, employing titanium isopropoxide and graphene oxide (GO) as starting materials. The GO concentration was varied from 0.1 to 4.0 wt%. The corresponding dispersions were spin-coated onto FTO substrates and a thermal treatment was performed to remove organic materials and to reduce GO to reduced graphene oxide (RGO). The TiO2/RGO films were characterized by x-ray diffraction, Raman spectroscopy, and microscopy techniques. Atomic force microscopy (AFM) images showed that the addition of RGO significantly changes the morphology of the TiO2 films, with loss of uniformity and increase in surface roughness. Independent of the use of V2O5 or PEDOT: PSS films as the hole transport layer, the incorporation of 2.0 wt% of RGO into TiO2 films was the optimal concentration for the best organic photovoltaic performance. The solar cells based on TiO2/RGO (2.0 wt%) electrode exhibited a ∼22.3% and ∼28.9% short circuit current density (Jsc) and a power conversion efficiency enhancement, respectively, if compared with the devices based on pure TiO2 films. Kelvin probe force microscopy images suggest that the incorporation of RGO into TiO2 films can promote the appearance of regions with different charge dissipation capacities.The authors thank LNNano/LNLS for the AFM and KPFM images, and INEO, CNPq (fellowship 246430/2012-5), and FAPESP (fellowship 2010/18656-1) for the financial supports. MINECO for the economic support through the ENE2013-48816-C5-4-R project. The COST Action StableNextSol project MP1307. The Agència de Gestió d’Ajuts Universitaris i de Recerca for the project 2014 SGR 1212. FASL would like to thank to the Secretary of Education of the State of Ceará (SEDUC-CE) for the financial support.Peer reviewe

Adsorbed 3d transition metal atoms and clusters on Au(111):Signatures derived from one electron calculations

The spectroscopic characteristics of systems with adsorbed d impurities on noble metal surfaces should depend on the number and geometric arrangement of the adsorbed atoms and also on their d band filling. Recent experiments using scanning tunneling microscopy have probed the electronic structure of all 3d transition metal impurities and also of Co dimers adsorbed on Au(111), providing a rich variety of results. In this contribution we correlate those experimental results with ab-initio calculations and try to establish necessary conditions for observing a Kondo resonance when using the single impurity Anderson model. We find that the relevant orbitals at the STM tip position, when it is on top of an impurity, are the dThe spectroscopic characteristics of systems with adsorbed d impurities on noble metal surfaces should depend on the number and geometric arrangement of the adsorbed atoms and also on their d band filling. Recent experiments using scanning tunneling microscopy have probed the electronic structure of all 3d transition metal impurities and also of Co dimers adsorbed on Au(111), providing a rich variety of results. In this contribution we correlate those experimental results with ab-initio calculations and try to establish necessary conditions for observing a Kondo resonance when using the single impurity Anderson model. We find that the relevant orbitals at the STM tip position, when it is on top of an impurity, are the d orbitals with m=0 and that the energy of these levels with respect to the Fermi energy determines the possibility of observing a spectroscopic feature due to the impurity. orbitals with m=0 and that the energy of these levels with respect to the Fermi energy determines the possibility of observing a spectroscopic feature due to the impurity

Estimating Evapotranspiration of Mediterranean Oak Savanna at Multiple Temporal and Spatial Resolutions. Implications for Water Resources Management

Mediterranean oak savanna is composed of a mixture of scattered oak trees, crops, pasture, and shrubs. It is the most widespread agroforestry landscape in Europe, and its conservation faces multiple threats including water scarcity, which has been exacerbated by global warming and greater climate variability. Evapotranspiration (ET) can be used as a proxy of the vegetation water status and response to water shortage conditions, providing relevant information about the ecosystem stability and its hydrological dynamics. This study evaluates a framework to estimate ET at multiple spatial and temporal scales and applies it to the monitoring of the oak savanna vegetation water consumption for the years 2013-2015. We used a remote sensing-based energy balance model (ALEXI/DisALEXI approach), and the STARFM data fusion technique to provide daily ET estimates at 30 m resolution. The results showed that modeled energy balance components compared well to ground measurements collected by an eddy covariance system, with root mean square error (RMSE) values ranging between 0.60 and 2.18 MJ m(-2) d(-1), depending on the sensor dataset (MODIS or Landsat) and the flux. The daily 30 m ET series generated by STARFM presented an RMSE value of 0.67 mm d(-1), which yielded a slight improvement compared to using MODIS resolution or more simple interpolation approaches with Landsat. However, the major advantage of the high spatio-temporal resolution was found in the analysis of ET dynamics over different vegetation patches that shape the landscape structure and create different microclimates. Fine-scale ET maps (30 m, daily) provide key information difficult to detect at a coarser spatial resolution over heterogeneous landscapes and may assist management decisions at the field and farm scale

TIM3+FOXP3+ regulatory T cells are tissue-specific promoters of T-cell dysfunction in cancer

T-cell immunoglobulin mucin 3 (TIM3) is an inhibitory molecule that has emerged as a key regulator of dysfunctional or exhausted CD8+ T cells arising in chronic diseases such as cancer. In addition to exhausted CD8+ T cells, highly suppressive regulatory T cells (Tregs) represent a significant barrier against the induction of antitumor immunity. We have found that the majority of intratumoral FOXP3+ Tregs express TIM3. TIM3+ Tregs co-express PD-1, are highly suppressive and comprise a specialized subset of tissue Tregs that are rarely observed in the peripheral tissues or blood of tumor-bearing mice. The co-blockade of the TIM3 and PD-1 signaling pathways in vivo results in the downregulation of molecules associated with TIM3+ Treg suppressor functions. This suggests that the potent clinical efficacy of co-blocking TIM3 and PD-1 signal transduction cascades likely stems from the reversal of T-cell exhaustion combined with the inhibition of regulatory T-cell function in tumor tissues. Interestingly, we find that TIM3+ Tregs accumulate in the tumor tissue prior to the appearance of exhausted CD8+ T cells, and that the depletion of Tregs at this stage interferes with the development of the exhausted phenotype by CD8+ T cells. Collectively, our data indicate that TIM3 marks highly suppressive tissue-resident Tregs that play an important role in shaping the antitumor immune response in situ, increasing the value of TIM3-targeting therapeutic strategies against cancer

Chern_simons Theory of the Anisotropic Quantum Heisenberg Antiferromagnet on a Square Lattice

We consider the anisotropic quantum Heisenberg antiferromagnet (with anisotropy $\lambda$) on a square lattice using a Chern-Simons (or Wigner-Jordan) approach. We show that the Average Field Approximation (AFA) yields a phase diagram with two phases: a Ne{\`e}l state for $\lambda>\lambda_c$ and a flux phase for $\lambda<\lambda_c$ separated by a second order transition at $\lambda_c<1$. We show that this phase diagram does not describe the $XY$ regime of the antiferromagnet. Fluctuations around the AFA induce relevant operators which yield the correct phase diagram. We find an equivalence between the antiferromagnet and a relativistic field theory of two self-interacting Dirac fermions coupled to a Chern-Simons gauge field. The field theory has a phase diagram with the correct number of Goldstone modes in each regime and a phase transition at a critical coupling $\lambda^* > \lambda_c$. We identify this transition with the isotropic Heisenberg point. It has a non-vanishing Ne{\` e}l order parameter, which drops to zero discontinuously for $\lambda<\lambda^*$.Comment: 53 pages, one figure available upon request, Revte