Conflitos e gestão neoliberal da educação / Conflicts and neoliberal educational management

Os conflitos representados, basicamente, pela conversão do direito universal à educação em um serviço privado estão associados aos demais conflitos que se estabelecem a partir de um processo de reforma empresarial da educação, da instituição escolar e do papel do antigo educador. O neoliberalismo possibilita a expansão do capital internacional, que transformará as velhas instituições de ensino em organizações, ditando-lhes um ritmo empresarial de produção e de avaliação. O Banco Mundial e outros organismos atuam fortemente na determinação desses padrões, por conta dos quais se estabelecem novas e conflituosas relações entre um direito público e interesses privados, além de diversos outros conflitos que desenham um novo formato para a questão, com destaque para a precarização do educador, tornado tarefeiro, tudo isto sob uma espécie de gestão neoliberal, que vê na escola uma empresa. Avulta um quadro de riscos, cujos efeitos já se fazem sentir, enquanto muitos outros ainda estarão por vir. 

Dye-sensitized solar cells using fluorone-based ionic liquids with improved cell efficiency

POCI-01-0145-FEDER-016387. POCI-01-0145-FEDER-007265. UID/QUI/50006/2019. LISBOA-01-0145-FEDER-402-022125. SFRH/BD/135087/2017.Six trihexyltetradecylphosphonium chloride (P6,6,6,14Cl) based ionic liquids (IL) with dianionic fluorone derivatives were synthesized with total exchange of chloride from the dianionic dye: Fluorescein (a), Rose Bengal (b), Phloxine B (c), Eosin B (d), Eosin Y (e) and Erythrosin B (f). Spectroscopic characterization of these viscous salts indicated the presence of the expected 1 or 2 strong absorption bands. A total of 12 compounds, as sodium (from a to f) or as trihexyltetradecylphosphonium dianion salts (from a′ to f′), were used for sensitization of nanocrystalline TiO2. Here, we report the sensitization activity of these metal free dyes in terms of current-potential curve, open-circuit potential, fill factor, and overall solar energy conversion efficiency which have been evaluated under 100 mW cm-2 light intensity. We developed a strategy to improve the light harvesting of these conventional dyes by simple cationic exchange which was accompanied by a minimum of 30% increase in the cell photovoltaic conversion efficiency. Also, for Eosin B the binding to TiO2 apparently allows reduction of the-NO2 electron-withdrawing group to-NO22-. This provides a new interaction between the reduced nitro group and the TiO2 surface, reflecting an improvement in the overall DSSC performance reaching its maximum of 0.65% efficiency after light DSSC soaking. Factors that improve DSSC performance like aggregate inhibition, increment of the electrode's quasi-Fermi level and slight red shift in the absorption spectra of the tested anionic dyes were achieved by simple cationic exchange.authorsversionpublishe

Smart systems for monitoring buildings - an IoT application

Life in society has initiated a search for comfort and security in social centers. This search generated revolutions within the knowledge about the technologies involved, making the environments automated and integrated. Along with this increase, ecological concerns have also arisen, which have been involved since the design of intelligent buildings, remaining through the years of their use. Based on these two pillars, the present study aims to monitor three central systems inside the apartments of the Apolo Building (Bragan¸cacity, Portugal). The electrical energy consumption, water flow, and waste disposal systems are integrated through a single database. The data is sent remotely via WiFi through the microcontroller. For better visualization and analytics of the data, a web application is also developed, which allows for real-time monitoring. The obtained results demonstrate to the consumer his behavior regarding household expenses. The idea of showing the consumer their expenditure is to create an ecological awareness. Through the data collected and the environmental alternatives found, it is possible to observe whether there was a behavior change when receiving this data, either in the short or long term.The authors are grateful to the Foundation for Science and Technology (FCT, Portugal) for financial support through national funds FCT/MCTES (PIDDAC) to CeDRI (UIDB/05757/2020 and UIDP/05757/2020) and SusTEC (LA/P/0007/2021). Thadeu Brito was supported by FCT PhD grant SFRH/BD/08598 /2020 and João Braun received the support of a fellowship from ”la Caixa” Foundation (ID 100010434) with code LCF/BQ/DI20/11780028.info:eu-repo/semantics/acceptedVersio

ERP correlates of error processing during performance on the HalsteadCategory Test

The Halstead Category Test (HCT) is a neuropsychological test that measures a person's ability to formulate and apply abstract principles. Performance must be adjusted based on feedback after each trial and errors are common until the underlying rules are discovered. Event-related potential (ERP) studies associated with the HCT are lacking. This paper demonstrates the use of amethodology inspired on Singular SpectrumAnalysis (SSA) applied to EEG signals, to remove high amplitude ocular andmovement artifacts during performance on the test. This filtering technique introduces no phase or latency distortions, with minimum loss of relevant EEG information. Importantly, the test was applied in its original clinical format, without introducing adaptations to ERP recordings. After signal treatment, the feedback-related negativity (FRN) wave, which is related to error-processing, was identified. This component peaked around 250ms, after feedback, in fronto-central electrodes. As expected, errors elicited more negative amplitudes than correct responses. Results are discussed in terms of the increased clinical potential that coupling ERP informationwith behavioral performance data can bring to the specificity of theHCT in diagnosing different types of impairment in frontal brain function.info:eu-repo/semantics/publishedVersio

A Systematic Review and Meta-analysis

Funding Information: This research was funded through the Portuguese Foundation for Science and Technology (FCT), I.P., under Project UIDB04045/2020. Publisher Copyright: © 2022, The Author(s).Background: Physical activity is essential in acquiring healthy lifestyle behaviors in the early years of maturational development and preventing various diseases. Resistance training (RT) is fundamental for improving body composition and is increasingly recommended for obese adolescents. A systematic review and meta-analysis were performed to synthesize and analyze data on the effects of RT programs in this population, seeking to develop useful recommendations for health and sports professionals. Methods: A search was performed using four databases (Web of Science, Scopus, PubMed, and ScienceDirect). According to specific inclusion criteria, twenty-one studies were selected to evaluate the impact of RT on body mass index (BMI), body fat, waist circumference, muscle strength, insulin sensitivity, lean mass and cardiorespiratory fitness. Results: After the RT programs, the adolescents improved their muscle strength (SMD, 1.44; 95% CI: 0.76–2.12), cardiorespiratory fitness (SMD, 1.09; 95% CI: 0.15–2.04), BMI (SMD, 0.21; 95% CI: 0.07–0.35), waist circumference (SMD, 0.27; 95% CI: 0.06–0.47) and body fat (SMD, 0.20; 95% CI: 0.05–0.34). However, insulin sensitivity (SMD, 0.32; 95% CI: − 0.47 to 1.10) and lean mass (SMD, 0.12; 95% CI: − 0.06 to 0.31) did not reveal any changes. Different RT programs were used but it seems that 2–3 times/week ∼60 min/session of RT for 12 weeks should be recommended for positive changes. Conclusions: RT seems to be effective when the objective is to improve muscle strength, cardiorespiratory fitness and can be an efficient strategy to reduce obesity in adolescents by reducing body fat, waist circumference and body mass index. PROSPERO Registration number: CRD42022333411.publishersversionpublishe

Reply to: comment on: The benefits of resistance training in obese adolescents: a systematic review and meta-analysis

We thank Dr. Zhang [1] for his interest in our literature review about the effects of resistance training (RT) programs in obese adolescents [2]. In the review, we analyzed 21 studies to evaluate the impact of RT on body mass index, body fat, waist circumference, lean mass, insulin sensitivity, muscle strength, and cardiorespiratory fitness. Our main findings showed that RT programs seem to be positive for obese adolescents, improving muscle strength and cardiorespiratory fitness and reducing body fat, waist circumference, and body mass index. Yet, we were clear to advise the reader that the results should be carefully analyzed, and some limitations were addressed, for example, (i) the small number of participants in each study; (ii) the use/comparison of different training programs (i.e., varying durations, intensities, and exercises); (iii) methodological issues (i.e., with an unclear or high risk of bias); (iv) unclear dietary control of participants; and (v) maturational-related issues. We understand that these limitations should not refrain professionals from critically appreciating our results and then designing RT programs for obese adolescents.info:eu-repo/semantics/publishedVersio

Early intervention in Portugal: study of professionals’ perceptions

Early intervention (EI) has been characterized by considerable advances in its domain, which has had great repercussions in the implementation of the family-centered approach. These changes have had implications in the practices and in the adoption and learning of new values that should be implemented in EI. This study evaluates the professional perspectives regarding familycentered practices in EI programs in Portugal. The results highlight the importance of effective collaboration and coordination between health, education, and social services and the importance of providing child and family support in a natural context. These results reinforce the need to invest in professional training to improve the quality of services offered to families in EI.Fundação para a Ciência e a Tecnologia (FCT) no âmbito do projecto PEst-OE/CED/UI1661/2014 do CIEd

Impact of organizational factors on accident prediction in the retail sector

Although different actions to prevent accidents at work have been implemented in companies, the number of accidents at work continues to be a problem for companies and society. In this way, companies have explored alternative solutions that have improved other business factors, such as predictive analysis, an approach that is relatively new when applied to occupational safety. Nevertheless, most reviewed studies focus on the accident dataset, i.e., the casualty’s characteristics, the accidents’ details, and the resulting consequences. This study aims to predict the occurrence of accidents in the following month through different classification algorithms of Machine Learning, namely, Decision Tree, Random Forest, Gradient Boost Model, K-nearest Neighbor, and Naive Bayes, using only organizational information, such as demographic data, absenteeism rates, action plans, and preventive safety actions. Several forecasting models were developed to achieve the best performance and accuracy of the models, based on algorithms with and without the original datasets, balanced for the minority class and balanced considering the majority class. It was concluded that only with some organizational information about the company can it predict the occurrence of accidents in the month ahead.USDA - U.S. Department of Agriculture(PCIF/GRF/0141/2019)The authors are grateful to the Foundation for Science and Technology (FCT, Portugal) for financial support through national funds FCT/MCTES (PIDDAC) to CeDRI (UIDB/05757/2020 and UIDP/05757/2020), ALGORITMI UIDB/00319/2020 and SusTEC (LA/P/0007/2021). This work has been supported by NORTE-01-0247-FEDER-072598 iSafety: Intelligent system for occupational safety and well-being in the retail sector. Inˆes Sena was supported by FCT PhD grant UI/BD/153348/2022

Development of multifunctional liposomes containing magnetic/plasmonic MnFe2O4/Au core/shell nanoparticles

Multifunctional liposomes containing manganese ferrite/gold core/shell nanoparticles were developed. These magnetic/plasmonic nanoparticles were covered by a lipid bilayer or entrapped in liposomes, which form solid or aqueous magnetoliposomes as nanocarriers for simultaneous chemotherapy and phototherapy. The core/shell nanoparticles were characterized by UV/Visible absorption, X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), and Superconducting Quantum Interference Device (SQUID). The magnetoliposomes were characterized by Dynamic Light Scattering (DLS) and TEM. Fluorescence-based techniques (FRET, steady-state emission, and anisotropy) investigated the incorporation of a potential anti-tumor drug (a thienopyridine derivative) in these nanosystems. The core/shell nanoparticles exhibit sizes of 25 ± 2 nm (from TEM), a plasmonic absorption band (λmax = 550 nm), and keep magnetic character. XRD measurements allowed for the estimation of 13.3 nm diameter for manganese ferrite core and 11.7 nm due to the gold shell. Aqueous magnetoliposomes, with hydrodynamic diameters of 152 ± 18 nm, interact with model membranes by fusion and are able to transport the anti-tumor compound in the lipid membrane, with a high encapsulation efficiency (EE (%) = 98.4 ± 0.8). Solid magnetoliposomes exhibit hydrodynamic diameters around 140 nm and also carry successfully the anticancer drug (with EE (%) = 91.2 ± 5.2), while also being promising as agents for phototherapy. The developed multifunctional liposomes can be promising as therapeutic agents for combined chemo/phototherapy.European Fund of Regional Development (FEDER), COMPETE2020 and Portugal2020. This research was funded by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding of CF-UM-UP (UID/FIS/04650/2013) and CQUM (UID/QUI/00686/2016) and through the research project PTDC/QUI-QFI/28020/2017 (POCI-01-0145-FEDER-028020), financed by the European Fund of Regional Development (FEDER), COMPETE2020 and Portugal2020. The APC was also funded by FCT. A.R.O.R. acknowledges FCT for a research grant under UID/FIS/04650/2013 funding.info:eu-repo/semantics/publishedVersio