Gold-platinum alloys and Vegard's law on the nanoscale

The structure of gold-platinum nanoparticles is heavily debated as theoretical calculations predict core-shell particles, whereas x-ray diffraction experiments frequently detect randomly mixed alloys. By calculating the structure of gold-platinum nanoparticles with diameters of up to approximate to 3.5 nm and simulating their x-ray diffraction patterns, we show that these seemingly opposing findings need not be in contradiction: Shells of gold are hardly visible in usual x-ray scattering, and the interpretation of Vegard's law is ambiguous on the nanoscale. DOI: 10.1103/PhysRevB.86.241403DFG [SFB 840]DF

Visibilidade da enfermagem nas midias impressa e online

OBJECTIVE: to describe the coverage of news concerning the nursing profession in the Portuguese media: informative sites on the Internet and in print media. METHOD: a total of 1,271 health news items were collected in September and October of 2011 (956 online news items and 325 news items originating from the press review of the Portuguese Order of Nurses). Statistical analysis was used to characterize the variables. RESULTS: nurses were the sources of information in 6.6% of cases, suggesting limited media exposure. The health news collected is characterized by a production based on limited information sources, that is, male and official sources, on information disseminated by news agencies focused on economic and political issues in the health field. CONCLUSION: the presence of nurses in the news concerning nursing health is reduced. We suggest that nurses develop public communication skills to disseminate the importance of their profession in society and their relationship with the media.OBJETIVO: describir la cobertura noticiosa de la profesión de enfermería en los medios de comunicación portugueses: a) sitios informativos de la Internet e b) prensa escrita. MÉTODOS: fueron recolectadas 1.271 noticias de salud en los meses de Septiembre y Octubre de 2011 (956 noticias online y 325 provenientes de reseñas del periódico de la Orden de los Enfermeros Portugueses); recurrió al análisis estadístico para caracterizar las variables definidas. RESULTADOS: los enfermeros se constituyeron en fuentes de información en 6,6% de los casos, lo que sugiere una baja visibilidad mediática. Las noticias de salud recolectadas se caracterizan por una producción noticiosa basada en fuentes de información poco variadas, oficiales y de género masculino; esta información es divulgada por agencias noticiosas y se enfocan en cuestiones económicas y políticas de la salud. CONCLUSIÓN: la presencia de los enfermeros en las noticias de salud es reducida. Se sugiere que éstos desarrollen competencias de comunicación pública, que objetive la divulgación de la importancia de la profesión para la sociedad y la relación con los medios de comunicación.OBJETIVO: descrever a cobertura noticiosa da profissão de enfermagem nas mídias portuguesas - sítios informativos da Internet e imprensa escrita. MÉTODOS: foram colhidas 1.271 notícias de saúde nos meses de setembro e outubro de 2011 (956 notícias online e 325 provenientes da resenha de imprensa da Ordem dos Enfermeiros Portugueses) e recorreu-se à análise estatística para caracterizar as variáveis definidas. RESULTADOS: os enfermeiros constituíram-se como fontes de informação em 6,6% dos casos, o que sugere baixa visibilidade mediática. As notícias de saúde colhidas são caracterizadas por produção noticiosa baseada em fontes de informação pouco variadas, oficiais e de gênero masculino, em informação divulgada por agências noticiosas e focada em questões econômicas e políticas da saúde. CONCLUSãO: a presença dos enfermeiros nas notícias de saúde é reduzida. Sugere-se que esses desenvolvam competências de comunicação pública, que visem a divulgação da importância da profissão para a sociedade e a relação com as mídias

Desempenho de cultivares de milho para produção de milho verde, minimilho e forragem

Maize has multiple functions and can be used for human consumption, animal feed, or in industrial processes. Grain production has made Brazil a world reference. However, few cultivars are available despite the relevance of sweet corn, especially for family farmers. This is similar to baby corn, in which sweet corn or popcorn is used for its production. In the Brazilian semi-arid region, plant and animal production are limited by water deficit in the dry season. Therefore, the production of sweet and baby corn generates income from the commercialization of the ears and roughage production with the whole-plant harvest. This research has aimed to assess the agronomic performance of five cultivars for sweet corn, baby corn, and fodder production in Agreste Meridional, a semi-arid region of Pernambuco, Brazil. Two experiments were carried out in a randomized block design with five treatments (AG 1051, Alagoano, Branquinha, São Luiz, and PV2 Viçosense) and four blocks. The 1st experiment assessed the performance of the cultivars for sweet corn and fodder yield, in which the cultivars AG 1051 and Branquinha had higher yields for ears (21.9 and 20.3 Mg ha-1) and fodder (10.7 and 10.9 Mg DM ha-1), respectively. The 2nd experiment assessed the performance of the cultivars for baby corn and fodder yield, in which the cultivars AG 1051 and PV2 Viçosense obtained the highest yield for ears (3.1 and 2.9 Mg ha-1, respectively); Branquinha had a higher yield for fodder (8.9 Mg DM ha-1). Therefore, these cultivars have desirable characteristics and can be used in intensive or extensive production.O milho apresenta múltiplas funções, podendo ser utilizado no consumo humano, alimentação animal ou em processos industriais. A produção de grãos tornou o Brasil uma referência mundial. Porém, apesar da relevância do milho verde, principalmente para agricultores familiares, são poucos os cultivares disponíveis. Do mesmo modo, para o minimilho, em que são utilizados milho doce ou pipoca para sua obtenção. Na região semiárida, as produções vegetal e animal são limitadas pelo déficit hídrico na época seca. Portanto, com a produção de milho verde e minimilho é possível obter renda com a comercialização das espigas e produzir volumoso com a colheita da planta inteira. O objetivo dessa pesquisa foi avaliar o desempenho agronômico de cinco cultivares para produção de milho verde e minimilho e produção de forragem no Agreste Meridional, região semiárida de Pernambuco. Foram realizados dois experimentos no delineamento em blocos casualizados, com cinco tratamentos (AG 1051, Alagoano, Branquinha, São Luiz e PV2 Viçosense) e quatro blocos. No primeiro experimento avaliou-se o desempenho dos cultivares para produção de milho verde e forragem, em que os cultivares AG 1051 e Branquinha tiveram, respectivamente, maiores produtividades de espigas comerciais (21,9 e 20,3 Mg ha-1) e de forragem (10,7 e 10,9 Mg MS ha-1). No segundo experimento, avaliou-se o desempenho dos cultivares para a produção de minimilho e forragem, em que os cultivares AG 1051 e PV2 Viçosense obtiveram a maior produtividade de espiguetas comerciais (3,1 e 2,9 Mg ha-1, respetivamente); Branquinha, maior produtividade de forragem (8,9 Mg MS ha-1). Portanto, esses cultivares reúnem características desejáveis, podendo ser utilizados em sistemas intensivos ou extensivos de produção

Supramolecular zippers elicit interbilayer adhesion of membranes producing cell death

Background: The fluorescent dye 10-N-nonyl acridine orange (NAO) is widely used as a mitochondrial marker. NAO was reported to have cytotoxic effects in cultured eukaryotic cells when incubated at high concentrations. Although the biochemical response of NAO-induced toxicity has been well identified, the underlying molecular mechanism has not yet been explored in detail. Methods: We use optical techniques, including fluorescence confocal microscopy and lifetime imaging microscopy (FLIM) both in model membranes built up as giant unilamellar vesicles (GUVs) and cultured cells. These experiments are complemented with computational studies to unravel the molecular mechanism that makes NAO cytotoxic. Results: We have obtained direct evidence that NAO promotes strong membrane adhesion of negatively charged vesicles. The attractive forces are derived from van der Waals interactions between anti-parallel H-dimers of NAO molecules from opposing bilayers. Semi-empirical calculations have confirmed the supramolecular scenario by which anti-parallel NAO molecules form a zipper of bonds at the contact region. The membrane remodeling effect of NAO, as well as the formation of H-dimers, was also confirmed in cultured fibroblasts, as shown by the ultrastructure alteration of the mitochondrial cristae. Conclusions: We conclude that membrane adhesion induced by NAO stacking accounts for the supramolecular basis of its cytotoxicity. General significance: Mitochondria are a potential target for cancer and gene therapies. The alteration of the mitochondrial structure by membrane remodeling agents able to form supramolecular assemblies via adhesion properties could be envisaged as a new therapeutic strategy

The exposure of the nursing profession in online and print media

OBJECTIVE: to describe the coverage of news concerning the nursing profession in the Portuguese media: informative sites on the Internet and in print media. METHOD: a total of 1,271 health news items were collected in September and October of 2011 (956 online news items and 325 news items originating from the press review of the Portuguese Order of Nurses). Statistical analysis was used to characterize the variables. RESULTS: nurses were the sources of information in 6.6% of cases, suggesting limited media exposure. The health news collected is characterized by a production based on limited information sources, that is, male and official sources, on information disseminated by news agencies focused on economic and political issues in the health field. CONCLUSION: the presence of nurses in the news concerning nursing health is reduced. We suggest that nurses develop public communication skills to disseminate the importance of their profession in society and their relationship with the media

Pervasive gaps in Amazonian ecological research

Biodiversity loss is one of the main challenges of our time,1,2 and attempts to address it require a clear un derstanding of how ecological communities respond to environmental change across time and space.3,4 While the increasing availability of global databases on ecological communities has advanced our knowledge of biodiversity sensitivity to environmental changes,5–7 vast areas of the tropics remain understudied.8–11 In the American tropics, Amazonia stands out as the world’s most diverse rainforest and the primary source of Neotropical biodiversity,12 but it remains among the least known forests in America and is often underrepre sented in biodiversity databases.13–15 To worsen this situation, human-induced modifications16,17 may elim inate pieces of the Amazon’s biodiversity puzzle before we can use them to understand how ecological com munities are responding. To increase generalization and applicability of biodiversity knowledge,18,19 it is thus crucial to reduce biases in ecological research, particularly in regions projected to face the most pronounced environmental changes. We integrate ecological community metadata of 7,694 sampling sites for multiple or ganism groups in a machine learning model framework to map the research probability across the Brazilian Amazonia, while identifying the region’s vulnerability to environmental change. 15%–18% of the most ne glected areas in ecological research are expected to experience severe climate or land use changes by 2050. This means that unless we take immediate action, we will not be able to establish their current status, much less monitor how it is changing and what is being lostinfo:eu-repo/semantics/publishedVersio

Geographic patterns of tree dispersal modes in Amazonia and their ecological correlates

Aim: To investigate the geographic patterns and ecological correlates in the geographic distribution of the most common tree dispersal modes in Amazonia (endozoochory, synzoochory, anemochory and hydrochory). We examined if the proportional abundance of these dispersal modes could be explained by the availability of dispersal agents (disperser-availability hypothesis) and/or the availability of resources for constructing zoochorous fruits (resource-availability hypothesis). Time period: Tree-inventory plots established between 1934 and 2019. Major taxa studied: Trees with a diameter at breast height (DBH) ≥ 9.55 cm. Location: Amazonia, here defined as the lowland rain forests of the Amazon River basin and the Guiana Shield. Methods: We assigned dispersal modes to a total of 5433 species and morphospecies within 1877 tree-inventory plots across terra-firme, seasonally flooded, and permanently flooded forests. We investigated geographic patterns in the proportional abundance of dispersal modes. We performed an abundance-weighted mean pairwise distance (MPD) test and fit generalized linear models (GLMs) to explain the geographic distribution of dispersal modes. Results: Anemochory was significantly, positively associated with mean annual wind speed, and hydrochory was significantly higher in flooded forests. Dispersal modes did not consistently show significant associations with the availability of resources for constructing zoochorous fruits. A lower dissimilarity in dispersal modes, resulting from a higher dominance of endozoochory, occurred in terra-firme forests (excluding podzols) compared to flooded forests. Main conclusions: The disperser-availability hypothesis was well supported for abiotic dispersal modes (anemochory and hydrochory). The availability of resources for constructing zoochorous fruits seems an unlikely explanation for the distribution of dispersal modes in Amazonia. The association between frugivores and the proportional abundance of zoochory requires further research, as tree recruitment not only depends on dispersal vectors but also on conditions that favour or limit seedling recruitment across forest types

Mapping density, diversity and species-richness of the Amazon tree flora

Using 2.046 botanically-inventoried tree plots across the largest tropical forest on Earth, we mapped tree species-diversity and tree species-richness at 0.1-degree resolution, and investigated drivers for diversity and richness. Using only location, stratified by forest type, as predictor, our spatial model, to the best of our knowledge, provides the most accurate map of tree diversity in Amazonia to date, explaining approximately 70% of the tree diversity and species-richness. Large soil-forest combinations determine a significant percentage of the variation in tree species-richness and tree alpha-diversity in Amazonian forest-plots. We suggest that the size and fragmentation of these systems drive their large-scale diversity patterns and hence local diversity. A model not using location but cumulative water deficit, tree density, and temperature seasonality explains 47% of the tree species-richness in the terra-firme forest in Amazonia. Over large areas across Amazonia, residuals of this relationship are small and poorly spatially structured, suggesting that much of the residual variation may be local. The Guyana Shield area has consistently negative residuals, showing that this area has lower tree species-richness than expected by our models. We provide extensive plot meta-data, including tree density, tree alpha-diversity and tree species-richness results and gridded maps at 0.1-degree resolution