Redox control of sulfur degassing in silicic magmas

International audienceExplosive eruptions involve mainly silicic magmas in which sulfur solubility and diffusivity are low. This inhibits sulfur exsolution during magma uprise as compared to more mafic magmas such as basalts. Silicic magmas can nevertheless liberate large quantities of sulfur as shown by the monitoring of SO2 in recent explosive silicic eruptions in arc settings, which invariably have displayed an excess of sulfur relative to that calculated from melt degassing. If this excess sulfur is stored in a fluid phase, it implies a strong preference of sulfur for the fluid over the melt under oxidized conditions, with fluid/melt partition coefficients varying between 50 and 2612, depending on melt composition. Experimentally determined sulfur partition coefficients for a dacite bulk composition confirm this trend and show that in volcanic eruptions displaying excess gaseous sulfur, the magmas were probably fluid-saturated at depth. The experiments show that in more reduced silicic magmas, those coexisting only with pyrrhotite, the partition coefficient decreases dramatically to values around 1, because pyrrhotite locks up nearly all the sulfur of the magma. Reevaluation of the sulfur yields of some major historical eruptions in the light of these results shows that for oxidized magmas, the presence of 1-5 wt % fluid may indeed account for the differences observed between the petrologic estimate of the sulfur yield and that constrained from ice core data. Explosive eruptions of very large magnitude but involving reduced and cool silicic magmas, such as the Toba or the Bishop events, release only minor amounts of sulfur and could have consequently negligible long-term (years to centuries) atmospherical effects. This redox control on sulfur release diminishes as the melt composition becomes less silicic and as temperature increases, because both factors favor more efficient melt sulfur degassing owing to the increased diffusivity of sulfur in silicate melts under such conditions

Spatial distribution of hotspot material added to the lithosphere under La Réunion, from wide-angle seismic data

Wide-angle seismic lines recorded by ocean bottom and land seismometers provide a pseudo three dimensional investigation of the crust and upper mantle structure around the volcanically active hotspot island of La Réunion. The submarine part of the edifice has fairly low seismic velocities, without evidence for intrusives. An upper unit with a velocity-depth gradient is interpreted as made of material erupted subaerially then transported and compacted downslope. Between this unit and the top of the oceanic plate, imaged by normal incidence seismic reflection, a more homogeneous unit indicated by shadow zones on several wide-angle sections may correspond to lavas of a different nature, extruded underwater in the earlier phase of volcanism. Coincident wide angle and normal incidence reflections document that the oceanic plate is not generally downwarping toward the island but doming instead toward its southeastern part, with limited evidence for some intracrustal intrusion. Deeper in the lithosphere, the presence of a layer of intermediate velocity between the crust and the mantle is firmly established. It is interpreted as resulting from the advection of hotspot magmatic products. Possibly partially molten, and of a composition for which the crust is a density barrier. The extensive wide-angle coverage constrains the extent of this body. It does not show the elongated shape expected from plate drift above a steady hotspot supply. Alternative propositions can hence be considered, for example, that La Réunion is caused by a solitary wave of hotspot material or by a young hotspot. The size of the underplate, 140 km wide and up to 3 km thick, corresponds to less than half the volume of the edifice on top of the plate. (Résumé d'auteur