Quantum Nature of the Proton in Water-Hydroxyl Overlayers on Metal Surfaces

Using ab initio path-integral molecular dynamics, we show that water-hydroxyl overlayers on transition metal surfaces exhibit surprisingly pronounced quantum nuclear effects. The metal substrates serve to reduce the classical proton transfer barriers within the overlayers and, in analogy to ice under high pressure, to shorten the corresponding intermolecular hydrogen bonds. Depending on the substrate and the intermolecular separations it imposes, the traditional distinction between covalent and hydrogen bonds is lost partially [e.g., on Pt(111) and Ru(0001)] or almost entirely [e.g., on Ni(111)]. We suggest that these systems provide an excellent platform on which to systematically explore the magnitude of quantum nuclear effects in hydrogen bonds

Direct CP violation in neutral kaon decays

The final result is presented of the NA48 Experiment performed at CERN SPS neutral kaon beams on the direct CP violation parameter Re(epsilon'/epsilon), as maesured from the decay rates of neutral kaons into two pions. The data collected in years 1997-2001 yield the evidence for direct CP violation with Re(epsilon'/epsilon)=(14.7+-2.2)10^-4. Description of expermental method and systematics, comparison with world data and some discussion of implications for theory are given.Comment: 5 pp., 3 figs, presented on behalf of NA48 Collaboration at PASCOS 2003 Conference, Mumbai, India, 2-8 Jan 2003, to appear in Praman

Berry's phase in noncommutative spaces

We introduce the perturbative aspects of noncommutative quantum mechanics. Then we study the Berry's phase in the framework of noncommutative quantum mechanics. The results show deviations from the usual quantum mechanics which depend on the parameter of space/space noncommtativity.Comment: 7 pages, no figur

Polymers near Metal Surfaces: Selective Adsorption and Global Conformations

We study the properties of a polycarbonate melt near a nickel surface as a model system for the interaction of polymers with metal surfaces by employing a multiscale modeling approach. For bulk properties a suitably coarse grained bead spring model is simulated by molecular dynamics (MD) methods with model parameters directly derived from quantum chemical calculations. The surface interactions are parameterized and incorporated by extensive quantum mechanical density functional calculations using the Car-Parrinello method. We find strong chemisorption of chain ends, resulting in significant modifications of the melt composition when compared to an inert wall.Comment: 8 pages, 3 figures (2 color), 1 tabl

The Noncommutative Anandan's Quantum Phase

In this work we study the noncommutative nonrelativistic quantum dynamics of a neutral particle, that possesses permanent magnetic and electric dipole momenta, in the presence of an electric and magnetic fields. We use the Foldy-Wouthuysen transformation of the Dirac spinor with a non-minimal coupling to obtain the nonrelativistic limit. In this limit, we will study the noncommutative quantum dynamics and obtain the noncommutative Anandan's geometric phase. We analyze the situation where magnetic dipole moment of the particle is zero and we obtain the noncommutative version of the He-McKellar-Wilkens effect. We demonstrate that this phase in the noncommutative case is a geometric dispersive phase. We also investigate this geometric phase considering the noncommutativity in the phase space and the Anandan's phase is obtained.Comment: 15 pages, revtex4, version to appear in Physical Review

Heisenberg quantization for the systems of identical particles and the Pauli exclusion principle in noncommutative spaces

We study the Heisenberg quantization for the systems of identical particles in noncommtative spaces. We get fermions and bosons as a special cases of our argument, in the same way as commutative case and therefore we conclude that the Pauli exclusion principle is also valid in noncommutative spaces.Comment: 8 pages, 1 figur

Noncommutative fluid dynamics in the Snyder space-time

In this paper, we construct for the first time the non-commutative fluid with the deformed Poincare invariance. To this end, the realization formalism of the noncommutative spaces is employed and the results are particularized to the Snyder space. The non-commutative fluid generalizes the fluid model in the action functional formulation to the noncommutative space. The fluid equations of motion and the conserved energy-momentum tensor are obtained.Comment: 12 pages. Version published by Phys. Rev.

An evaluation of total starch and starch gelatinization methodologies in pelleted animal feed

Citation: Zhu, L., Jones, C., Guo, Q., Lewis, L., Stark, C. R., & Alavi, S. (2016). An evaluation of total starch and starch gelatinization methodologies in pelleted animal feed. Journal of Animal Science, 94(4), 1501-1507. doi:10.2527/jas2015-9822The quantification of total starch content (TS) or degree of starch gelatinization (DG) in animal feed is always challenging because of the potential interference from other ingredients. In this study, the differences in TS or DG measurement in pelleted swine feed due to variations in analytical methodology were quantified. Pelleted swine feed was used to create 6 different diets manufactured with various processing conditions in a 2 x 3 factorial design (2 conditioning temperatures, 77 or 88 degrees C, and 3 conditioning retention times, 15, 30, or 60 s). Samples at each processing stage (cold mash, hot mash, hot pelletized feed, and final cooled pelletized feed) were collected for each of the 6 treatments and analyzed for TS and DG. Two different methodologies were evaluated for TS determination (the AOAC International method 996.11 vs. the modified glucoamylase method) and DG determination (the modified glucoamylase method vs. differential scanning calorimetry [DSC]). For TS determination, the AOAC International method 996.11 measured lower TS values in cold pellets compared with the modified glucoamylase method. The AOAC International method resulted in lower TS in cold mash than cooled pelletized feed, whereas the modified glucoamylase method showed no significant differences in TS content before or after pelleting. For DG, the modified glucoamylase method demonstrated increased DG with each processing step. Furthermore, increasing the conditioning temperature and time resulted in a greater DG when evaluated by the modified glucoamylase method. However, results demonstrated that DSC is not suitable as a quantitative tool for determining DG in multicomponent animal feeds due to interferences from nonstarch transformations, such as protein denaturation

IT-ENABLED KNOWLEDGE MANAGEMENT IN HEALTHCARE DELIVERY: THE CASE OF EMERGENCY CARE

IT is viewed as integral to achieving substantial quality and efficiency improvements in U.S. healthcare delivery and management. A key idea behind these suggestions is the use of IT to support knowledge management to enhance and facilitate evidence-based clinical decisionmaking. Yet, it is not clear to what extent IT-enabled knowledge management systems will be effective for physicians who make complex clinical decisions under time pressure and high degree of uncertainty. To address this gap, we are conducting a field study to examine the impact of ITenabled knowledge management systems in an emergency department at a major university hospital in the Southeast region of the US. The preliminary results of our analyses show that the use of IT-enabled knowledge application tools indeed influence the healthcare professional’s clinical decision-making behaviors, which in turn influence the outcome of patient care

Low-temperature Thermodynamic Study of the Empty Clathrate Hydrates

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