23 research outputs found

    Enzyme mass-transfer coefficient in aqueous two-phase systems using static mixer extraction column

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    Selective removal of silyl protecting groups from hydroxyl functions with ammonium chloride in aqueous acetonitrile

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    1972-1974Silyl ethers are efficiently hydrolyzed to their corresponding alcohols with NH4Cl in aqueous acetonitrile. Benzylic, secondary and tert-trimethyl silyl ethers are readily cleaved at room temperature, whereas deproteetion of primary and some crowded secondary trimethyl silyl ethers takes place at 80oC

    Phase Change Process in a Zigzag Plate Latent Heat Storage System during Melting and Solidification

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    Applying a well-performing heat exchanger is an efficient way to fortify the relatively low thermal response of phase-change materials (PCMs), which have broad application prospects in the fields of thermal management and energy storage. In this study, an improved PCM melting and solidification in corrugated (zigzag) plate heat exchanger are numerically examined compared with smooth (flat) plate heat exchanger in both horizontal and vertical positions. The effects of the channel width (0.5 W, W, and 2 W) and the airflow temperature (318 K, 323 K, and 328 K) are exclusively studied and reported. The results reveal the much better performance of the horizontal corrugated configuration compared with the smooth channel during both melting and solidification modes. It is found that the melting rate is about 8% faster, and the average temperature is 4 K higher in the corrugated region compared with the smooth region because of the large heat-exchange surface area, which facilitates higher rates of heat transfer into the PCM channel. In addition to the higher performance, a more compact unit can be achieved using the corrugated system. Moreover, applying the half-width PCM channel accelerates the melting rate by eight times compared to the double-width channel. Meanwhile, applying thicker channels provides faster solidification rates. The melting rate is proportional to the airflow temperature. The PCM melts within 274 s when the airflow temperature is 328 K. However, the melting time increases to 460 s for the airflow temperature of 308 K. Moreover, the PCM solidifies in 250 s and 405 s in the cases of 318 K and 328 K airflow temperatures, respectively
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