Applying rare earth elements, Uranium, and 87Sr/86Sr to disentangle structurally forced confluence of regional groundwater resources: The case of the Lower Yarmouk Gorge

The conjoint discussion of tectonic features, correlations of element concentrations, δ18O, δD, and 87Sr/86Sr of groundwater leads to new insight into sources of groundwater, their flow patterns, and salinization in the Yarmouk Basin. The sources of groundwater are precipitation infiltrating into basaltic rock or limestone aquifers. Leaching of relic brines and dissolution of gypsum and calcite from the limestone host rocks generate enhanced salinity in groundwater in different degrees. High U(VI) suggests leaching of U from phosphorite-rich Upper Cretaceous B2 formation. Both very low U(VI) and specific rare earth element including yttrium (REY) distribution patterns indicate interaction with ferric oxyhydroxides formed during weathering of widespread alkali olivine basalts in the catchment area. REY patterns of groundwater generated in basaltic aquifers are modified by interaction with underlying limestones. Repeated sampling over 18 years revealed that the flow paths towards certain wells of groundwater varied as documented by changes in concentrations of dissolved species and REY patterns and U(VI) contents. In the Yarmouk Gorge, groundwater with basaltic REY patterns but high U(VI) and low Sr2+ and intermediate sulfate concentrations mainly ascends in artesian wells tapping a buried flower structure fault system crossing the trend of the gorge

A Novel Method to Assess the Impact of a Government’s Water Strategy on Research: A Case Study of Azraq Basin, Jordan

Water scarcity drives governments in arid and semi-arid regions to promote strategies for improving water use efficiency. Water-related research generally also plays an important role in the same countries and for the same reason. However, it remains unclear how to link the implementation of new government strategies and water-related research. This article’s principal objective is to present a novel approach that defines water-related research gaps from the point of view of a government strategy. The proposed methodology is based on an extensive literature review, followed by a systematic evaluation of the topics covered both in grey and peer-reviewed literature. Finally, we assess if and how the different literature sources contribute to the goals of the water strategy. The methodology was tested by investigating the impact of the water strategy of Jordan’s government (2008–2022) on the research conducted in the Azraq Basin, considering 99 grey and peer-reviewed documents. The results showed an increase in the number of water-related research documents from 37 published between 1985 and 2007 to 62 published between 2008 and 2018. This increase should not, however, be seen as a positive impact of increased research activity from the development of Jordan’s water strategy. In fact, the increase in water-related research activity matches the increasing trend in research production in Jordan generally. Moreover, the results showed that only about 80% of the documents align with the goals identified in the water strategy. In addition, the distribution of the documents among the different goals of the strategy is heterogeneous; hence, research gaps can be identified, i.e., goals of the water-strategy that are not addressed by any of the documents sourced. To foster innovative and demand-based research in the future, a matrix was developed that linked basin-specific research focus areas (RFAs) with the MWI strategy topics. In doing so, the goals that are not covered by a particular RFA are highlighted. This analysis can inspire researchers to develop and apply new topics in the Azraq Basin to address the research gaps and strengthen the connection between the RFAs and the strategy topics and goals. Moreover, the application of the proposed methodology can motivate future research to become demand-driven, innovative, and contribute to solving societal challenges

Pharmaceuticals, Their Metabolites, and Other Polar Pollutants in Field-Grown Vegetables Irrigated with Treated Municipal Wastewater

The reuse of treated municipal wastewater for crop irrigation is a necessity in arid and semiarid regions but a potential entrance for emerging contaminants into the food chain. However, little attention has yet been paid to the detection of micropollutants and possible metabolites in vegetables grown under realistic field conditions. In this study, the uptake of 28 micropollutants and carbamazepine metabolites in 10 different field-grown vegetable species (among them carrot, lettuce, potato, and zucchini) from Jordan was studied. A total of 12 micropollutants and six carbamazepine metabolites, four of which have never been analyzed before in plant-uptake studies, could be detected in all of the samples in concentrations ranging from 1.7 to 216 ng per g of dry weight. In edible tissues, the total concentration of micropollutants decreased in the order of leafy (247–533) > root (73–126) > fruit-bearing (5–76 ng per g of dry weight) vegetables. A preliminary health-risk assessment for nine compounds according to the TTC concept shows no risk for seven of the micropollutats; for ciprofloxacin and 10,11-epoxycarbamazepine, however, more-specific toxicity data would be required for a refined risk assessment