ブリルアン散乱と誘電分光によるリラクサー強誘電体の電場効果の研究

筑波大学 (University of Tsukuba)201

Porous Carbon Materials as Supreme Metal-Free Counter Electrode for Dye-Sensitized Solar Cells

Counter electrode (CE), as one of the key components of dye-sensitized solar cells (DSSCs), plays a significant role in the overall efficiency and cost of the device. Platinum metal has long been considered one of the most efficient CEs for DSSCs, but its scarcity, high cost, and low stability in I−/I3− redox couple limit its application in the large scale. In this chapter, we provide a broad overview on porous carbon materials as supreme metal-free counter electrode for DSSCs. In the first part, we concisely discuss on the importance and working principle of DSSCs and then the influence of counter electrode on the photovoltaic performance of DSSCs. Afterward, we review different synthetic methods and precursors of porous carbon materials and their efficiency in DSSCs. In the last section, we discuss in detail with example how to characterize and evaluate the device performance using porous carbon materials as counter electrode. Finally, we finish this chapter with a brief summary and outlook of porous carbon materials as counter electrodes in DSSCs

南鳥島およびベンガル堆積盆の浅海性炭酸塩岩の特性評価とそれらの堆積環境・歴史の解明

要約のみTohoku University井龍康文課

南鳥島およびベンガル堆積盆の浅海性炭酸塩岩の特性評価とそれらの堆積環境・歴史の解明

要約のみTohoku University井龍康文課

Role of polar nanoregions with weak random fields in Pb-based perovskite ferroelectrics

In relaxor ferroelectrics, the role of randomly orientated polar nanoregions (PNRs) with weak random fields (RFs) is one of the most puzzling issues of materials science. The relaxation time of polarization fluctuations of PNRs, which manifests themselves as a central peak (CP) in inelastic light scattering, is the important physical quantity to understand the dynamics of PNRs. Here, the angular and temperature dependences of depolarized and polarized CPs in 0.44Pb(Mg1/3Nb2/3)O3-0.56PbTiO3 single crystals with weak RFs have been studied by Raman and Brillouin scattering, respectively. The CPs observed in Raman scattering show the very clear angular dependence which is consistent with the local tetragonal symmetry. It is different from the well-known local rhombohedral symmetry with strong RFs for Pb(Mg1/3Nb2/3)O3. In Brillouin scattering, depolarized and polarized CPs show two relaxation processes corresponding to transverse and longitudinal fluctuations of PNRs. The remarkable slowing down towards the Curie temperature was observed for transverse fluctuations in local tetragonal symmetry

Electric field and aging effects of uniaxial ferroelectrics Sr x Ba1-x Nb2O6 probed by Brillouin scattering

This study was supported in part by the Marubun Research Promotion Foundation and JSPS KAKENHI Grant Number JP17K05030.Static and dynamic heterogeneity of disordered system is one of the current topics in materials science. In disordered ferroelectric materials with random fields, dynamic polar nanoregions (PNRs) appear at Burns temperature and freeze into nanodomain state below Curie temperature (T C). This state is very sensitive to external electric field and aging by which it gradually switches into macrodomain state. However, the role of PNRs in such states below T C is still a puzzling issue of materials science. Electric field and aging effects of uniaxial ferroelectric Sr x Ba1-x Nb2O6 (x = 0.40, SBN40) single crystals were studied using Brillouin scattering to clarify the critical nature of PNRs in domain states below T C. On field heating, a broad anomaly in longitudinal acoustic (LA) velocity at low temperature region was due to an incomplete alignment of nanodomains caused by the interaction between PNRs. A sharp anomaly near T C was attributed to the complete switching of nanodomain to macrodomain state owing to the lack of interaction among PNRs. After isothermal aging below T C, the noticeable increase of LA velocity was observed. It was unaffected by cyclic temperature measurements up to T C, and recovered to initial state outside of a narrow temperature range above and below aging temperature.Japan Society for the Promotion of Scienc

High pressure Ca-VI phase between 158-180 GPa: Stability, electronic structure and superconductivity

We have performed ab initio calculations for new high-pressure phase of Ca-VI between 158-180 GPa. The study includes elastic parameters of mono- and poly-crystalline aggregates, electronic band structure, lattice dynamics and superconductivity. The calculations show that the orthorhombic Pnma structure is mechanically and dynamically stable in the pressure range studied. The structure is superconducting in the entire pressure range and the calculated Tc (~25K) is maximum at ~172 GPa, where the transfer of charges from 4s to 3d may be thought to be completed.Comment: 8 pages, 4 figures; PACS number(s): 74.70.Ad, 62.20.de, 71.20.-b, 74.20.Pq, 74.25.Kc, 74.62.Fj; Keywords: Calcium; High pressure; Electronic band structure; Phonon spectrum; Elastic constants; Superconducto

Characterization of the high-pressure superconductivity in the Pnma phase of calcium

The thermodynamic parameters of the superconducting state in calcium under the pressure at 161 GPa have been calculated within the framework of the Eliashberg approach. It has been shown that the value of the Coulomb pseudopotential is high (0.24) and the critical temperature (25 K) should be determined from the modified Allen-Dynes formula. In addition, it has been found that the basic dimensionless ratios of the thermodynamic parameters significantly diverge from the BCS predictions, and take the following values: (i) The zero temperature energy gap to the critical temperature(R1) is equal to 4.01. (ii) The ratio R2 equals 2.17. (iii) The quantity R3=0.158. Finally, it has been proven that the electron effective mass is large and takes the maximum of 2.32*me at TC.Comment: 8 pages, 9 figures; Phys. Status Solidi B (2012

The superconducting phase of Calcium under the pressure at 200 GPa: the strong-coupling description

The thermodynamic parameters of the superconducting state in Calcium under the pressure at 200 GPa have been determined. The numerical analysis by using the Eliashberg equations in the mixed representation has been conducted. It has been stated, that the critical temperature ($T_{C}$) decreases from 36.15 K to 20.79 K dependently on the assumed value of the Coulomb pseudopotential ($\mu^{*}\in$). Next, the order parameter near the temperature of zero Kelvin ($\Delta(0)$) has been obtained. It has been proven, that the dimensionless ratio $2\Delta(0)/k_{B}T_{C}$ decreases from 4.25 to 3.90 together with the growth of $\mu^{*}$. Finally, the ratio of the electron effective mass to the electron bare mass ($m^{*}_{e}/m_{e}$) has been calculated. It has been shown, that $m^{*}_{e}/m_{e}$ takes the high value in the whole range of the superconducting phase's existence, and its maximum is equal to 2.23 for T=T_{C}.Comment: 5 pages, 5 figure