98 research outputs found
Construction of a numerical groundwater flow model in areas of intense mine drainage, as exemplified by the Olkusz Zinc and Lead Ore Mining Area in southwest Poland
Areas of intense mine drainage that are subjected to numerical modelling require the construction of a complex model
structure that will properly reflect actual conditions. This paper presents the process and results of constructing such a
structure for the Olkusz Zinc and Lead Ore Mining Area, an area situated in a cone of depression the extent of which
reaches 500 km 2 . This size range calls for a selection of appropriate external boundaries, properly separated from these
of the mine drainage area. The complex geological structure of the Olkusz area, associated with considerable variation
in the thickness of rock formations, discontinuities of rock levels and occurrence of numerous faults, must be schema-
tised so that calculation layers can be identified. The faults in the study area have to be reflected in the regional model
structure, although only those faults that actually affect groundwater flows should be selected. The model structure
needs to include detailed recognition and reflection of hydraulic contacts between aquifer levels, together with a selec-
tion of hydrogeological parameters that are different for particular formations. Only a complex structure built in such a
manner may be the foundation of further model studies
PLZT microfibers technology optimization
Electrocaloric (EC) structures for a new generation of cooling or heating elements utilize the temperature dependence of spontaneous polarization in some ferroelectric materials to convert waste heat into electricity and vice versa. A (Pb0.93La0.07) (Zr0.65Ti0.35)O3 material, have the largest recorded pyroelectric coefficient. An effective predicted form for such applications is fiber, due to small heat capacitance and quick response time, even for nano second laser excitation. Consequently, the presented work provides a description of the optimization of structural, ferroelectric and piezoelectric properties of obtained fibers, finally concluding on necessity of sintering temperature reduction in 100°C in contrast to bulk form to effectively prevent its destruction
Dielectric and Impedance Studies of (Ba,Ca)TiO3 Ceramics Obtained from Mechanically Synthesized Powders
Mechanochemical synthesis o ers unique possibility of perovskite phase formation at
ambient conditions that is very attractive (simplifies production, allows strict stoichiometry control and
brings economic benefits). In this work the mechanochemical synthesis has been used for preparation
ofBa1xCaxTiO3 (0.2 x 0.3) powders from simple oxides. The 20 h milled powders have been
uniaxially pressed and sintered in order to get the ceramic samples. The sample morphologies
have been observed by scanning electron microscopy. Dielectric and impedance studies have
been performed on ceramics. The obtained results indicate that the two mechanism of doping
occurred. The first one is observed for the lower calcium concentration (below 0.3) and consists of the
introduction of calcium ion into the A site of the perovskite structure. The second one is observed for
the higher calcium concentration (equal 0.3). In this case the calcium ions partially occupies the B site
in the perovskite structure. Both cases have di erent influence on the final properties of the ceramics
because they induce di erent defects
Influence of calcium doping on microstructure, dielectric and electric properties of BaBi2Nb2O9 ceramics
Barium bismuth niobiate (BaBi2Nb2O9) ceramics modified by calcium were prepared by solid state synthesis
and two-step sintering process. An impact of calcium substitution on the A site of perovskite block is presented.
The investigations are focused on dielectric as well as electric aspects of the modification. The presented results
reveal that the concentration of a space charge is not preserved, what is surprising due to the homovalent
nature of the dopant and no reason for creating additional lattice defects and charges connected. However, not
only the valence of ions, but also the calcium-oxygen and barium–oxygen bond strength should be taken into
consideration. Since the calcium–oxygen bond is probably weaker the loss of the bismuth oxide is expected to
increase with an increase in the calcium content. Such a scenario results in appearance of a large number of
negative charge carriers connected with unsaturated oxygen ions
Correlation Between Structure, Microstructure and Dielectric Properties of Bi7Fe3Ti3O21 Ceramics Obtained in Different Conditions
Multiferroic six-layer Aurivillius type Bi7Fe3Ti3O21 ceramics was obtained by conventional mixed oxides method. The final
sintering process was taken in several different sintering times, which determined changes in properties of discussed ceramic material.
The structure and dielectric properties of the material are reported. In order to examine the technological conditions on the crystal
structure, XRD analysis was carried out. The microstructure, as well as the quantitative and qualitative analysis of the chemical composition
were investigated by scanning electron microscope with an energy dispersion spectrometer. The main purpose of the paper is to
present the effect of sintering time on the microstructure, crystallographic structure and dielectric properties of Bi7Fe3Ti3O21 ceramics
Electric and dielectric properties of (Ba0.6Pb0.4)TiO3 ceramics modified with special glass in the range of phase transition
Perovskite ceramics (Ba0.6Pb0.4)TiO3 modified with PbO-B2O3-Al2O3-WO3 special glass was prepared with the
conventional mixed oxide method. X-ray diffraction analysis (XRD) of the obtained materials confirmed singlephase
and pure tetragonal structure. The Rietveld method was used to determine unit cell parameters. Uniform
deformation of the tetragonal parameter was observed with addition of the glass. Dielectric measurements
revealed the remarkable influence of special glass admixture on the value of dielectric permittivity and dielectric
losses, as well as the Curie temperature. However, the most important achievement of the investigations is
obtaining a significant PTCR effect in the sample containing 6 wt.% of special glass admixture
Neural circuit of verbal humor comprehension in schizophrenia : an fMRI study
Individuals with schizophrenia exhibit problems with understanding the figurative meaning of language. This study evaluates neural correlates of diminished humor comprehension observed in schizophrenia. The study included chronic schizophrenia (SCH) outpatients (n = 20), and sex, age and education level matched healthy controls (n = 20). The fMRI punchline based humor comprehension task consisted of 60 stories of which 20 had funny, 20 nonsensical and 20 neutral (not funny) punchlines. After the punchlines were presented, the participants were asked to indicate whether the story was comprehensible and how funny it was. Three contrasts were analyzed in both groups reflecting stages of humor processing: abstract vs neutral stories - incongruity detection; funny vs abstract - incongruity resolution and elaboration; and funny vs neutral - complete humor processing. Additionally, parametric modulation analysis was performed using both subjective ratings separately. Between-group comparisons revealed that the SCH subjects had attenuated activation in the right posterior superior temporal gyrus (BA 41) in case of irresolvable incongruity processing of nonsensical puns; in the left dorsomedial middle and superior frontal gyri (BA 8/9) in case of incongruity resolution and elaboration processing of funny puns; and in the interhemispheric dorsal anterior cingulate cortex (BA 24) in case of complete processing of funny puns. Additionally, during comprehensibility ratings the SCH group showed a suppressed activity in the left dorsomedial middle and superior frontal gyri (BA 8/9) and revealed weaker activation during funniness ratings in the left dorsal anterior cingulate cortex (BA 24). Interestingly, these differences in the SCH group were accompanied behaviorally by a protraction of time in both types of rating responses and by indicating funny punchlines less comprehensible. Summarizing, our results indicate neural substrates of humor comprehension processing impairments in schizophrenia, which is accompanied by fronto-temporal hypoactivation
Bovine serum albumin as a platform for designing biologically active nanocarriers : experimental and computational studies
Due to the specificity of their structure, protein systems are adapted to carry various ligands. The structure of many proteins potentially allows for two types of immobilization of a therapeutic agent, either on the outer surface of the protein or within the protein structure. The existence of two active sites in BSA’s structure, the so-called Sudlow I and II, was confirmed. The conducted research involved determining the effectiveness of BSA as a potential carrier of 5-fluorouracil (5FU). 5-fluorouracil is a broad-spectrum anticancer drug targeting solid tumors. The research was carried out to estimate the physicochemical properties of the system using complementary measurement techniques. The optimization of the complex formation conditions made it possible to obtain significant correlations between the form of the drug and the effective localization of the active substance in the structure of the protein molecule. The presence of two amino groups in the 5FU structure contributes to the deprotonation of the molecule at high pH values (pH > 8) and the transition to the anionic form (AN1 and AN3). To investigate the binding affinity of the tautomeric form with BSA, UV-vis absorption, fluorescence quenching, zeta potential, QCM-D, and CD spectroscopic studies were performed. The experimental research was supported by molecular dynamics (MD) simulations and molecular docking. The simulations confirm the potential location of 5FU tautomers inside the BSA structure and on its surface
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