28 research outputs found
Suzuki-Miyaura Cross-Coupling Reaction Based on Novel Palladium(II) Diphenylphosphine Derivative Catalyst
Get PDFThe synthesis and characterization of palladium complexes ((CH3)3SiC6H4PPh2)2PdCl2,4a, and ((CH3)3SiC12H8PPh2)2PdCl2, 4b, containing phosphine (CH3)3SiC6H4PPh2, 3a and (CH3)3SiC12H8PPh2, 3b ligands are reported. The phosphine ligands are prepared conveniently in high yield by treatment of the corresponding 1,4-dibromoarene with one equivalent of butyl lithium, and one equivalent of ClPPh2 at -78 °C under an atmosphere of argon. The palladium complexes are synthesized by the reaction of Pd(cod)Cl2 with two equivalent of the above mentioned phosphine ligands. The new complexes were fully characterized by spectroscopic methods  and elemental analysis. Furthermore, the use of the palladium (II) complexes of such system as pre-catalysts for the Suzuki-Miyaura coupling of some arylbromides and arylchloride with substituted  phenyl boronic acid has been tested. Keywords:1,4-dibromoarene, Palladium complex, Suzuki coupling, catalyst
Development of HPLC Methods for the Determination of Vancomycin in Human Plasma, Mouse Serum and Bronchoalveolar Lavage Fluid
No full textThermal and Structural Studies of a 1D Zinc(II) Coordination Polymer – [Zn(μ-4,4′-bipy)(H2O)4]n(CCl3COO)2n·(4,4′-bipy)2n (4,4′-bipy = 4,4′-bipyridine), with Shorted Cl···Cl Interactions
No full text
2∞[Cu2(μ5-btb)(μ-OH)(μ-H2O)]: a two-dimensional coordination polymer built from ferromagnetically coupled Cu2 units (btb = benzene-1,2,3-tricarboxylate)
No full textCrystal structures and solid-state CPMAS 13C NMR correlations in luminescent zinc(II) and cadmium(II) mixed-ligand coordination polymers constructed from 1,2-bis(1,2,4-triazol-4-yl)ethane and benzenedicarboxylate
No full textA hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties
No full text
