3,544 research outputs found
Radial Heterogeneity and Surface Properties of Columns Used in High Performance Liquid Chromatography
The radial heterogeneity of some columns used in high performance liquid chromatography (HPLC) was investigated using an on-column microelectrochemical amperometric detector. Such a detector allowed the recording of the elution profiles at different spatial positions throughout the column exit cross-section. From this, we obtain information about the radial distribution of the mobile phase velocity, column efficiency, and analyte concentration. In all cases, the results obtained show that the spatial distribution of the mobile phase velocity does not follow a piston-flow behavior but exhibits radial heterogeneity with differences not exceeding 5% between the center and wall regions of any column. The efficiency was found to be lower in the wall region of the column than in its core region (the central core with a radius of 1/3 the column inner radius) by up to 40-50% in some columns. The radial distribution of the maximum concentration of the peaks varies throughout the column exit section, partially due to the radial variations of the column efficiency. The technology used in constructing the microelectrochemical detectors was further exploited to fabricate and incorporate an online detector array for a pressurized flat wide column measuring 10x10x0.1 cm in dimensions. Thus, unlike traditional thin layer chromatography, samples in this pressurized flat bed are completely eluted and detected in a time-based mode just like they are in HPLC. Also, a lateral arrangement of the detector array allows for an easy monitoring of the homogeneity of the flat wide column. Also, information on the surface properties of three novel chemically bonded phase packing materials for HPLC was obtained using solid state cross-polarization (CP) magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopic experiments for the 29Si, and 13C nuclei. These packing materials were: Cogent bidentate C18 bonded to type-C silica, hybrid packing materials XTerra MS C18, and XBridge Prep. C18. The spectra obtained using cross-polarization magic angle spinning (CP-MAS) on the Cogent bidentate C18 bonded to type-C silica show the surface to be densely populated with hydride groups (Si-H), with a relative surface coverage exceeding 80%. The hybrid packing materials XTerra and XBridge gave spectra that reveal the silicon atoms to be bonded to alkyl moieties embedded in the molecular structure of these materials with over 90% of the alkyl silicon atoms found within the completely condensed silicon environments
High resolution optical spectroscopy of IRAS 09425-6040 (=GLMP 260)
We present high resolution optical spectroscopic observations of IRAS
09425-6040, a peculiar, extremely red, C-rich AGB star showing prominent O-rich
dust features in its ISO infrared spectrum attributed to crystalline silicates.
Our analysis shows that IRAS 09425-6040 is indeed a C-rich star slightly
enriched in lithium (log (Li/H) + 12 ~ 0.7) with a low 12C/13C = 15+-6 ratio.
We also found some evidence that it may be enriched in s-elements. Combining
our results with other observational data taken from the literature we conclude
that the star is possibly an intermediate-mass TP-AGB star (M > 3 M_sun) close
to the end of its AGB evolution which may have only very recently experienced a
radical change in its chemistry, turning into a carbon-rich AGB star.Comment: 5 pages, 2 figures, accepted for publication in A&
Sorption kinetics and intraparticulate diffusivities of Cd, Pb and Zn ions on maize cob
The kinetics of sorption and intraparticulate diffusivities of Zn, Cd and Pb using maize cob was studied. The amount of the metal ions adsorbed increased with time. The highest sorption rates of the three metal ions were 71% for Z2+, 32% for Cd2+, and 30% for Pb2+. The fractional attainment of equilibrium showed that Zn2+ reached equilibrium before Pb2+ ion and then Cd2+ ion. This study showed that the sorption of Zn2+, Cd2+ and Pb2+ ions on maize cob is particle diffusion controlled. The rate coefficients for particle diffusion were 0.07 min-1 for Zn2+, 0.053min-1 for Pb2+ and 0.081min-1 for Cd2+.African Journal of Biotechnology Vol. 4 (6), pp. 509-512, 200
Magnetic molecules created by hydrogenation of Polycyclic Aromatic Hydrocarbons
Present routes to produce magnetic organic-based materials adopt a common
strategy: the use of magnetic species (atoms, polyradicals, etc.) as building
blocks. We explore an alternative approach which consists of selective
hydrogenation of Polycyclic Aromatic Hydrocarbons. Self-Consistent-Field (SCF)
(Hartree-Fock and DFT) and multi-configurational (CISD and MCSCF) calculations
on coronene and corannulene, both hexa-hydrogenated, show that the formation of
stable high spin species is possible. The spin of the ground states is
discussed in terms of the Hund rule and Lieb's theorem for bipartite lattices
(alternant hydrocarbons in this case). This proposal opens a new door to
magnetism in the organic world.Comment: 6 pages, 4 figures and 2 table
Fluorine in AGB Carbon Stars Revisited
A reanalysis of the fluorine abundance in three Galactic AGB carbon stars (TX
Psc, AQ Sgr and R Scl) has been performed from the molecular HF (1-0) R9 line
at 2.3358 m. High-resolution (R) and high signal to noise
spectra obtained with the CRIRES spectrograph and the VLT telescope or from the
NOAO archive (for TX Psc) have been used. Our abundance analysis uses the
latest generation of MARCS model atmospheres for cool carbon rich stars. Using
spectral synthesis in LTE we derive for these stars fluorine abundances that
are systematically lower by dex in average with respect to the sole
previous estimates by Jorissen, Smith & Lambert (1992). The possible reasons of
this discrepancy are explored. We conclude that the difference may rely on the
blending with C-bearing molecules (CN and C) that were not properly taken
into account in the former study. The new F abundances are in better agreement
with the prediction of full network stellar models of low mass AGB stars. These
models also reproduce the -process elements distribution in the sampled
stars. This result, if confirmed in a larger sample of AGB stars, might
alleviate the current difficulty to explain the largest [F/O] ratios found by
Jorissen et al. In particular, it may not be necessary to search for
alternative nuclear chains affecting the production of F in AGB stars.Comment: 25 pages, 3 figures. to be appear in The Astrophysical Journal (Jan
2009 issue
Measurement of the Higgs Boson Mass with a Linear e+e- Collider
The potential of a linear e+e- collider operated at a centre-of-mass energy
of 350 GeV is studied for the measurement of the Higgs boson mass. An
integrated luminosity of 500 fb-1 is assumed. For Higgs boson masses of 120,
150 and 180 GeV the uncertainty on the Higgs boson mass measurement is
estimated to be 40, 65 and 70 MeV, respectively. The effects of beam related
systematics, namely a bias in the beam energy measurement, the beam energy
spread and the luminosity spectrum due to beamstrahlung, on the precision of
the Higgs boson mass measurement are investigated. In order to keep the
systematic uncertainty on the Higgs boson mass well below the level of the
statistical error, the beam energy measurement must be controlled with a
relative precision better than 10-4.Comment: 19 pages, 10 Figure
Dynamics of a structured slug population model in the absence of seasonal variation
We develop a novel, nonlinear structured population model for the slug Deroceras reticulatum, a highly significant agricultural pest of great economic impact, in both organic and non-organic settings. In the absence of seasonal variations, we numerically explore the effect of life history traits that are dependent on an individual's size and measures of population biomass. We conduct a systematic exploration of parameter space and highlight the main mechanisms and implications of model design. A major conclusion of this work is that strong size dependent predation significantly adjusts the competitive balance, leading to non-monotonic steady state solutions and slowly decaying transients consisting of distinct generational cycles. Furthermore, we demonstrate how a simple ratio of adult to juvenile biomass can act as a useful diagnostic to distinguish between predated and non-predated environments, and may be useful in agricultural settings
Chemical evolution of star clusters
I discuss the chemical evolution of star clusters, with emphasis on old
globular clusters, in relation to their formation histories. Globular clusters
clearly formed in a complex fashion, under markedly different conditions from
any younger clusters presently known. Those special conditions must be linked
to the early formation epoch of the Galaxy and must not have occurred since.
While a link to the formation of globular clusters in dwarf galaxies has been
suggested, present-day dwarf galaxies are not representative of the
gravitational potential wells within which the globular clusters formed.
Instead, a formation deep within the proto-Galaxy or within dark-matter
minihaloes might be favoured. Not all globular clusters may have formed and
evolved similarly. In particular, we may need to distinguish Galactic halo from
Galactic bulge clusters.Comment: 27 pages, 2 figures. To appear as invited review article in a special
issue of the Phil. Trans. Royal Soc. A: Ch. 6 "Star clusters as tracers of
galactic star-formation histories" (ed. R. de Grijs). Fully peer reviewed.
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