17 research outputs found

    Arsenate and arsenite removal from contaminated water by iron oxides nanoparticles formed inside a bacterial exopolysaccharide

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    In the last decades, the presence of high As levels in groundwaters poses a serious limitation to the use of this resources for drinking purposes in several parts of the world. Treatment of As-rich waters selected iron oxides filters as more effective, low cost and selective technology. Green and biologically-driven pathways to synthetize new nanostructured iron oxy-hydroxides are becoming always more attractive. We tested the suitability of FeOOH nanoparticles (9–15 nm) produced by Klebsiella oxytoca strain DSM 29614 and encapsulated in EPS gel structure to treat arsenic rich water. Different gel:water volume ratios were tested to treat 5000 μg As/L solution. 20% FeEPS solution was able to remove 95% of As(V) while in 5% solution removal was reduced to 60%. Arsenic adsorption was very fast and follows pseudo-2nd order kinetic with maximum adsorption capacity reached at about 30 min. Adsorption followed Langmuir model for As(V) with qmax=31.8 mgAs/gFe and BET for As(III) with 8 mgAs/gFe for the first layer in 10% FeEPS solution. FeEPS dried into powder showed noticeable removal only after 2 h, hence not suitable for drinking water treatment. Treatment of natural As levels in mimicked groundwaters showed 87–95% As(V) and 45–61% As(III) removal after 5 min. FeEPS gel immobilized onto bivalve shell debris was used in packed-bed filters. It retained 49.8 mgAs/gFe from 150 μg/L As(V) spiked groundwater before reaching breakthrough at 8000 BVs. Biologically produced FeEPS gel showed good potentialities as eco-friendly material to remove As from contaminated groundwater

    A comparative analysis of bacterial adhesion on different long-term provisional fixed prostheses fabricated by CAD/CAM milling, 3D printing, and heat cure technique: An In Vivo study

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    Objectives: This study compares the bacterial susceptibility to three different provisional restorations manufactured with different laboratory techniques, i.e., heat cure, CAD/CAM, and 3D printing. Materials and Methods: Totally, 45 health patients with age group of 30–60 years undergoing complete veneer crown treatment were selected for the study and divided into three groups with 15 samples in each as Group I: the crowns were made from polymethyl methacrylate polymer fabricated by the conventional heat cure method, Group 2: the crowns were made from polymethyl methacrylate fabricated by subtractive manufacturing CAD/CAM method, and Group 3: the crowns were made from oligomers fabricated by additive manufacturing 3D printing. The samples were examined for bacterial adherence at scanning electron microscope. The colony-forming units (CFUs) were calculated, and statistically analyzed. Results: It has been determined that the digitally fabricated provisional restorations prove to be superior in terms of surface topography than to the conventionally fabricated provisional restorations. Conclusion: The study concludes that 3D-printed provisional restorations are more precise with reduced bacterial susceptibility than milled ones

    Changes in the thermodynamical profiles of the subsurface ocean and atmosphere induce cyclones to congregate over the Eastern Arabian Sea

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    Abstract The Arabian Sea accounts for a small fraction of Tropical Cyclones—about 2% of the annual global mean. However, the damage they might inflict there and along its coastlines, which are thickly populated, is considerable. This study explores the influence of the changes in the vertical profiles of atmosphere and oceanic environment throughout the seasons of March–June (MAMJ) and October–December (OND) in clustering the cyclogenesis over the Eastern Arabian Sea (EAS) next to the Indian West coast in recent decades. Further investigation has been done into the precise contribution of atmospheric and oceanic factors to fluctuations in cyclone intensity throughout the MAMJ and OND seasons separately. Two seasons have been studied independently in order to better understand the distinct influences of the vertical fluctuation of atmospheric factors and the thermal structure of the oceanic subsurface on cyclogenesis. More severe cyclones are caused by high tropical cyclone heat potential, and ocean subsurface warming present in this sea region influences the genesis of storms mostly during MAMJ. On the other hand, mid tropospheric relative humidity and thermal instability influences more on increasing cyclogenesis and its clustering over EAS during OND season. The findings suggest that large-scale oceanic subsurface conditions have a crucial influence on cyclogenesis over EAS through oceanic sensitivity to atmospheric forcing. This cyclone tendency and its clustering over EAS needs attention in terms of forecasting, catastrophe risk reduction, and climate change adaptation due to the security of coastal urban and rural habitats, livelihoods, and essential infrastructure along the coasts

    Assessment of survival rate of dental implants in patients with bruxism: A 5-year retrospective study

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    Background: Dental implants are associated with failure such as early or late failure. Systemic conditions such as diabetes, hypertension, and bruxism affect the success rate. The present study was conducted to assess complications in dental implants in bruxism patients. Materials and Methods: This 5-year retrospective study was conducted on 450 patients (640 dental implants) who received implants during the period and followed up for 5 years from June 2010 to June 2016. Among these patients, 124 had bruxism habit. Dental radiographs or patients' recalled records were evaluated for the presence of complications such as fracture of implant, fracture of ceramic, screw loosening, screw fracture, and decementation of unit. Results: In 240 males and 210 females, 380 implants and 260 implants were inserted, respectively. The difference was statistically nonsignificant (P = 0.1). A total of 145 screw-type and 130 cemented-type fixations had complications. The difference was statistically nonsignificant (P = 0.5). Complications were seen in single crown (45), partial prostheses (125), and complete prostheses (105). The difference was statistically significant (P = 0.012). The common complication was fracture of ceramic (70) in cemented-type fixation and fracture of ceramic (85) in screw-type fixation. The difference was statistically significant (P = 0.01). Forty-two single crowns showed decementation, 85 partial prostheses had fracture of ceramic/porcelain, and 50 complete prostheses showed fracture of ceramic/porcelain. The failure rate was 42.9%. Survival rate of dental implants in males with bruxism habit was 90% after 1 year, 87% after 2 years, 85% after 3 years, 75% after 4 years, and 72% after 5 years. Survival rate of dental implants in females with bruxism habit was 92% after 1 year, 90% after 2 years, 85% after 3 years, 75% after 4 years, and 70% after 5 years. The difference among genders was statistically nonsignificant (P = 0.21). Conclusion: Bruxism is a parafunctional habit which affects the survival rate of dental implants. There is requirement to follow certain specific protocols in bruxism patients to prevent the developing complications
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