818 research outputs found
On-line Oxidation Of Cr(lll) To Cr(vi) For Use With The Flow Injection Analysis Technique
An on-line procedure for the oxidation of Cr(III) to Cr(VI) was developed. The extent of oxidation was followed using the 1,5-diphenylcarbazide (DPC) spectrophotometric method accommodated in a flow injection analysis (FIA) system. Cerium(IV) sulphate and potassium peroxydisulphate were tested as oxidising agents. Despite the high oxidation power of the peroxydisulphate ion in acidic solution, the use of Ce(IV) is more convenient under dynamic conditions. The best experimental conditions were obtained at 45°C using a 0.025% m/\/Ce(IV) solution in 0.07 M H2SO4 with the Cr(III) solutions containing up to 3.0 × 10-2 M H 2S04.109564564
Crystal Structure and Physical Properties of U3T3Sn4 (T = Ni, Cu) Single-Crystals
Heat capacity experiments, crystal structure determination and transmission
electron microscopy have been carried out on U3Cu3Sn4 single-crystals. U3Cu3Sn4
was confirmed to be a heavy-fermion antiferromagnet (TN=13(1) K) with a low
temperature electronic heat capacity coefficient gamma=390 mJ/molUK2. Low
temperature heat capacity experiments on a U3Ni3Sn4 single-crystal indicate
that below 0.4 K there is a crossover between the previously observed non-Fermi
liquid behavior and a Fermi liquid state.Comment: 12 pages (incl. 2 tables & 4 figures), to appear in Physica
Spectrophotometric Determination Of Boron In Plants Using Monosegmented Continuous Flow Analysis
A monosegmented continuous flow analysis (MCFA) procedure for the spectrophotometric determination of boron using azomethine-H as colour reagent is presented. Under the experimental conditions described the calibration graph is linear up to 4.00 μg ml-1. The detection limit found is 0.02 μg ml-1, calculated from three times the standard deviation of the blank signal. The common interfering elements present in plants were investigated under dynamic MCFA conditions. As expected, iron and copper present the most severe interferences. This MCFA method for the determination of boron was used with test samples from the Plant Sample Exchange Programme (PSEP) of the Wageningen Agricultural University. The results compared favourably with those obtained by the conventional static procedure and those published by the PSEP.113289293CNRS/IN2P3; NSF; Arthritis National Research Foundation; NRF-2012004024; ANRF; Arthritis National Research Foundatio
Spin transport of electrons through quantum wires with spatially-modulated strength of the Rashba spin-orbit interaction
We study ballistic transport of spin-polarized electrons through quantum
wires in which the strength of the Rashba spin-orbit interaction (SOI) is
spatially modulated. Subband mixing, due to SOI, between the two lowest
subbands is taken into account. Simplified approximate expressions for the
transmission are obtained for electron energies close to the bottom of the
first subband and near the value for which anticrossing of the two lowest
subbands occurs. In structures with periodically varied SOI strength, {\it
square-wave} modulation on the spin transmission is found when only one subband
is occupied and its possible application to the spin transistor is discussed.
When two subbands are occupied the transmission is strongly affected by the
existence of SOI interfaces as well as by the subband mixing
Novel sources of Flavor Changed Neutral Currents in the model
Sources of Flavor Changed Neutral Currents (FCNC) naturally emerge from a
well motivated framework called 3-3-1 with right-handed neutrinos model,
for short, mediated by an extra neutral gauge boson .
Following previous works we calculate these sources and in addition we derive
new ones coming from CP-even and -odd neutral scalars which appear due to their
non-diagonal interactions with the physical standard quarks. Furthermore we
show that bounds related to the neutral mesons systems and may be significantly strengthened in the presence of these new
interactions allowing us to infer stronger constraints on the parameter space
of the model.Comment: Published version. 10 pages, 6 figure
UPLC-MS-ESI-QTOF analysis and antifungal activity of the spondias tuberosa arruda leaf and root hydroalcoholic extracts
The aim of this study was to identify and evaluate the chemical compositions and effects of the S. tuberosa leaf and root hydroalcoholic extracts (HELST and HERST) against different strains of Candida. Chemical analysis was performed by Ultra-Performance Liquid Chromatography Coupled to Quadrupole/Time of Flight System (UPLC-MS-ESI-QTOF). The Inhibitory Concentration of 50% of the growth (IC50) as well as the intrinsic and combined action of the extracts with the antifungal fluconazole (FCZ) were determined by the microdilution method while the minimum fungicidal concentrations (MFCs) and the effect on fungal morphological transitions were analyzed by subculture and in humid chambers, respectively. From the preliminary phytochemical analysis, the phenols and flavonoids were the most abundant. The intrinsic IC50 values for HELST ranged from 5716.3 to 7805.8 \ub5g/mL and from 6175.4 to 51070.9 \ub5g/mL for the HERST, whereas the combination of the extracts with fluconazole presented IC50 values from 2.65 to 278.41 \ub5g/mL. The MFC of the extracts, individually, for all the tested strains was 6516384 \ub5g/mL. When fluconazole was combined with each extract, the MFC against CA URM 5974 was reduced (HELST: 2048 and HERST: 4096 \ub5g/mL). Synergism was observed against standard C. albicans (CA) and C. tropicalis (CT) strains and with the root extract against the CT isolate. The leaf extract inhibited the morphological transition of all strains while the root extract inhibited only CT strains
Dilatonic current-carrying cosmic strings
We investigate the nature of ordinary cosmic vortices in some scalar-tensor
extensions of gravity. We find solutions for which the dilaton field condenses
inside the vortex core. These solutions can be interpreted as raising the
degeneracy between the eigenvalues of the effective stress-energy tensor,
namely the energy per unit length U and the tension T, by picking a privileged
spacelike or timelike coordinate direction; in the latter case, a phase
frequency threshold occurs that is similar to what is found in ordinary neutral
current-carrying cosmic strings. We find that the dilaton contribution for the
equation of state, once averaged along the string worldsheet, vanishes, leading
to an effective Nambu-Goto behavior of such a string network in cosmology, i.e.
on very large scales. It is found also that on small scales, the energy per
unit length and tension depend on the string internal coordinates in such a way
as to permit the existence of centrifugally supported equilibrium
configuration, also known as vortons, whose stability, depending on the very
short distance (unknown) physics, can lead to catastrophic consequences on the
evolution of the Universe.Comment: 10 pages, ReVTeX, 2 figures, minor typos corrected. This version to
appear in Phys. Rev.
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