Optical Properties of Quantum-Dot-Doped Liquid Scintillators

Semiconductor nanoparticles (quantum dots) were studied in the context of liquid scintillator development for upcoming neutrino experiments. The unique optical and chemical properties of quantum dots are particularly promising for the use in neutrinoless double beta decay experiments. Liquid scintillators for large scale neutrino detectors have to meet specific requirements which are reviewed, highlighting the peculiarities of quantum-dot-doping. In this paper, we report results on laboratory-scale measurements of the attenuation length and the fluorescence properties of three commercial quantum dot samples. The results include absorbance and emission stability measurements, improvement in transparency due to filtering of the quantum dot samples, precipitation tests to isolate the quantum dots from solution and energy transfer studies with quantum dots and the fluorophore PPO.Comment: version 2, minor text update

Transit Time and Charge Correlations of Single Photoelectron Events in R7081 PMTs

During the calibration phase of the photomultiplier tubes (PMT) for the Double Chooz experiment the PMT response to light with single photoelectron (SPE) intensity was analysed. With our setup we were able to measure the combined transit time and charge response of the PMT and therefore we could deconstruct and analyse all physical effects having an influence on the PMT signal. Based on this analysis charge and time correlated probability density functions were developed to include the PMT response in a Monte Carlo simulation.Comment: minor changes by referee reques

Transit Time and Charge Correlations of Single Photoelectron Events in R7081 PMTs

During the calibration phase of the photomultiplier tubes (PMT) for the Double Chooz experiment the PMT response to light with single photoelectron (SPE) intensity was analysed. With our setup we were able to measure the combined transit time and charge response of the PMT and therefore we could deconstruct and analyse all physical effects having an influence on the PMT signal. Based on this analysis charge and time correlated probability density functions were developed to include the PMT response in a Monte Carlo simulation.Comment: minor changes by referee reques

Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection

Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "Gamma Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table

Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection

Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "Gamma Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table

Large scale Gd-beta-diketonate based organic liquid scintillator production for antineutrino detection

Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "Gamma Catcher" of the Double Chooz detectors.Comment: 16 pages, 4 figures, 5 table

Optimierung der Fluoreszenzcharakteristik von Flüssigszintillatoren des Double Chooz Reaktorneutrinoexperiments

The goal of the reactor neutrino experiment Double Chooz is to search for the last remaining unknown neutrino mixing angle 13 of the PMNS matrix. This disappearence experiment aims at detecting possible oscillations of electron antineutrinos at a distance of one kilometer. A relative measurement will be done between a far and a near detector, each of them containing several cubic meters of Gadoliniumloaded organic liquid scintillator as a neutrino target. A second unloaded scintillator surrounds the neutrino target and acts as a Gamma Catcher. Different compositions of scintillators have been studied to optimize their properties. Light yields and time probability density functions of the scintillator emission have been measured. A model has been developed describing the energy transfer to predict the light yield of different scintillator compositions. The predictions have been checked with a Compton backscatter peak method. The result of the optimization process is a light yield and density matching of the two chemically different scintillators with per cent accuracy. Different time PDFs could be used for a pulse shape discrimination in Double Chooz. The results of this work determine the mixing ratios and the concentrations for the target and the gamma catcher scintillator of Double Chooz

Spectral fingerprinting for specific algal groups on sediments in situ: a new sensor

Currently it is still extremely difficult to adequately sample populations of microalgae on sediments for large-scale biomass determination. We have now devised a prototype of a new benthic sensor (BenthoFluor) for the quantitative and qualitative assessment of microphytobenthos populations in situ. This sensor enables a high spatial and temporal resolution and a rapid evaluation of the community structure and distribution. These determinations are based on the concept that five spectral excitation ranges can be used to differentiate groups of microalgae, in situ, within a few seconds. In addition, because sediments contain a lot of yellow substances, which can affect the fluorescence and optical differentiation of the algae, the device was equipped with a UV-LED for yellow substances correction. The device was calibrated against HPLC with cultures and tested in the field. Our real-time approach can be used to monitor algal assemblage composition on sediments and is an ideal tool for investigations on the large-scale spatial and temporal variation of algal populations in sediments. Apart from the differentiation of algal populations, the BenthoFluor allows instantaneous monitoring of the chlorophyll concentrations and determination of which algae are responsible for this on the uppermost surface of sediments in the field and in experimental set-ups