Aluminium distribution in ZSM-5 revisited: the role of Al-Al interactions

We present a theoretical study of the distribution of Al atoms in zeolite ZSM-5 with Si/Al=47, where we focus on the role of Al-Al interactions rather than on the energetics of Al/Si substitutions at individual sites. Using interatomic potential methods, we evaluate the energies of the full set of symmetrically independent configurations of Al siting in a Si94Al2O192 cell. The equilibrium Al distribution is determined by the interplay of two factors: the energetics of the Al/Si substitution at an individual site, which tends to populate particular T sites (e.g. the T14 site), and the Al-Al interaction, which at this Si/Al maximises Al-Al distances in agreement with Dempsey’s rule. However, it is found that the interaction energy changes approximately as the inverse of the square of the distance between the two Al atoms, rather than the inverse of the distance expected if this were merely charge repulsion. Moreover, we find that the anisotropic nature of the framework density plays an important role in determining the magnitude of the interactions, which are not simply dependent on Al-Al distances

Comparison of Munsell® color chart assessments with primary schoolchildren's self-reported skin color

BACKGROUND : Skin color is related to human health outcomes, including the risks of skin cancer and vitamin D insufficiency. Self-perceptions of skin color may influence health behaviours, including the adoption of practices protective against harmful solar ultraviolet radiation levels. Misperception of personal risk may have negative health implications. The aim of this study is to determine whether Munsell color chart assessments align with child self-reported skin color. METHODS : Two-trained investigators, with assessed color acuity, visually classified student inner upper arm constitutive skin color. The Munsell classifications obtained were converted to Individual Typology Angle (ITA) values and respective Del Bino skin color categories after spectrocolorimeter measurements based on published values/data. As part of a written questionnaire on sun protection knowledge, attitudes, and behaviours, self-completed in class time, students classified their end of winter skin color. Student self-reports were compared with the ITA-based Del Bino classifications. A total of 477 New Zealand primary students attending 27 randomly selected schools from five geographic regions. The main measures were selfreported skin color and visually observed skin color. RESULTS : A monotonic association was observed between the distribution of spectrophotometer ITA scores obtained for Munsell tiles and child self-reports of skin color, providing some evidence for the validity of self-report among New Zealand primary school children, although the lighter colored ITA defined groups were most numerous in this study sample. Statistically significant differences in ITA scores were found by ethnicity, self-reported skin color, and geographic residence (P < 0.001). Certain Munsell color tiles were frequently selected as providing a best match to skin color. CONCLUSION : Assessment using Munsell color charts was simple, inexpensive, and practical for field use and acceptable to children. The results suggest that this method may prove useful for making comparisons with other studies using visual tools to assess skin color. Alignment between the ITA distribution derived from the Munsell assessment and child skin color self-reports could probably be improved, particularly with the addition of another ‘light’/’white’ color category in the self-report instrument.The Cancer Society of New Zealand Inc., the National Institute of Water and Atmospheric Research, the National Research Foundation of South Africa and the University of Otago.http://onlinelibrary.wiley.com/journal/10.1111/(ISSN)1600-08462016-11-30hb2016Geography, Geoinformatics and Meteorolog

IRMPD spectroscopy sheds new (InfraRed) light on the sulfate pattern of carbohydrates

Contains fulltext : 169008.pdf (publisher's version ) (Closed access

Economic assessment of use of pond ash in pavements

The paper introduces a new type of industrial waste-based subbase material which can replace conventional subbase material (CSM) in pavement construction. Utilisation of this industrial waste, namely pond coal ash produced from a thermal power plant in road construction will help to reduce the disposal problem of this waste and also will help to reduce the problem of scarcity of CSM. Lime and fibre were also added to the pond ash at various percentages to improve the suitability of this type of mix as subbase material. The optimum service life of pavement is studied with the help of numerical modelling and the cost benefit is also presented in the current study. The study reveals that stabilisation of the coal ash with 2% lime may produce an optimal material and, even though a greater thickness may be required to deliver the same pavement performance, direct cost savings of around 10% may be achieved in addition to less easily quantifiable environmental benefits. Design charts are provided to exploit the findings

Topological mirror symmetry with fluxes

Motivated by SU(3) structure compactifications, we show explicitly how to construct half--flat topological mirrors to Calabi--Yau manifolds with NS fluxes. Units of flux are exchanged with torsion factors in the cohomology of the mirror; this is the topological complement of previous differential--geometric mirror rules. The construction modifies explicit SYZ fibrations for compact Calabi--Yaus. The results are of independent interest for SU(3) compactifications. For example one can exhibit explicitly which massive forms should be used for Kaluza--Klein reduction, proving previous conjectures. Formality shows that these forms carry no topological information; this is also confirmed by infrared limits and old classification theorems.Comment: 35 pages, 5 figure

The PL calibration for Milky Way Cepheids and its implications for the distance scale

The rationale behind recent calibrations of the Cepheid PL relation using the Wesenheit formulation is reviewed and reanalyzed, and it is shown that recent conclusions regarding a possible change in slope of the PL relation for short-period and long-period Cepheids are tied to a pathological distribution of HST calibrators within the instability strip. A recalibration of the period-luminosity relation is obtained using Galactic Cepheids in open clusters and groups, the resulting relationship, described by log L/L_sun = 2.415(+-0.035) + 1.148(+-0.044)log P, exhibiting only the moderate scatter expected from color spread within the instability strip. The relationship is confirmed by Cepheids with HST parallaxes, although without the need for Lutz-Kelker corrections, and in general by Cepheids with revised Hipparcos parallaxes, albeit with concerns about the cited precisions of the latter. A Wesenheit formulation of Wv = -2.259(+-0.083) - 4.185(+-0.103)log P for Galactic Cepheids is tested successfully using Cepheids in the inner regions of the galaxy NGC 4258, confirming the independent geometrical distance established for the galaxy from OH masers. Differences between the extinction properties of interstellar and extragalactic dust may yet play an important role in the further calibration of the Cepheid PL relation and its application to the extragalactic distance scale.Comment: Accepted for Publication (Astrophysics & Space Science

Talented suppliers? Strategic change and innovation in the UK aerospace industry

The 1990s marked the start of extensive re-structuring in the aerospace industry throughout the world. While the ensuing consolidation among prime contractors has been widely researched, the changes affecting the aerospace supply chain have received less attention. This study focuses on the re-structuring taking place within the supply chain of the UK aerospace industry. The findings point to extensive re-structuring. Unlike most earlier studies the lean supply model was found to be a powerful influence, with suppliers moving away from subcontractor status and instead taking on the mantle of ‘talented’ suppliers. While some of the implications of lean supply, in terms of the dynamics of innovation, were not apparent, there were modest signs of increased process innovation on the part of some suppliers

Nongeometric Flux Compactifications

We investigate a simple class of type II string compactifications which incorporate nongeometric "fluxes" in addition to "geometric flux" and the usual H-field and R-R fluxes. These compactifications are nongeometric analogues of the twisted torus. We develop T-duality rules for NS-NS geometric and nongeometric fluxes, which we use to construct a superpotential for the dimensionally reduced four-dimensional theory. The resulting structure is invariant under T-duality, so that the distribution of vacua in the IIA and IIB theories is identical when nongeometric fluxes are included. This gives a concrete framework in which to investigate the possibility that generic string compactifications may be nongeometric in any duality frame. The framework developed in this paper also provides some concrete hints for how mirror symmetry can be generalized to compactifications with arbitrary H-flux, whose mirrors are generically nongeometric.Comment: 26 pages, JHEP3. v3: references, minor corrections, and clarifications added. v4: sign correcte

Synchronization and resonance in a driven system of coupled oscillators

We study the noise effects in a driven system of globally coupled oscillators, with particular attention to the interplay between driving and noise. The self-consistency equation for the order parameter, which measures the collective synchronization of the system, is derived; it is found that the total order parameter decreases monotonically with noise, indicating overall suppression of synchronization. Still, for large coupling strengths, there exists an optimal noise level at which the periodic (ac) component of the order parameter reaches its maximum. The response of the phase velocity is also examined and found to display resonance behavior.Comment: 17 pages, 3 figure

Adiabatic following criterion, estimation of the nonadiabatic excitation fraction and quantum jumps

An accurate theory describing adiabatic following of the dark, nonabsorbing state in the three-level system is developed. An analytical solution for the wave function of the particle experiencing Raman excitation is found as an expansion in terms of the time varying nonadiabatic perturbation parameter. The solution can be presented as a sum of adiabatic and nonadiabatic parts. Both are estimated quantitatively. It is shown that the limiting value to which the amplitude of the nonadiabatic part tends is equal to the Fourier component of the nonadiabatic perturbation parameter taken at the Rabi frequency of the Raman excitation. The time scale of the variation of both parts is found. While the adiabatic part of the solution varies slowly and follows the change of the nonadiabatic perturbation parameter, the nonadiabatic part appears almost instantly, revealing a jumpwise transition between the dark and bright states. This jump happens when the nonadiabatic perturbation parameter takes its maximum value.Comment: 33 pages, 8 figures, submitted to PRA on 28 Oct. 200