10 research outputs found

    Distribution of rhenium in molybdenite from porphyry Cu-Mo and Mo-Cu deposits of Russia (Siberia) and Mongolia

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    Rhenium was determined in representative molybdenite samples (concentrates) from the Aksug, Erdenetuin-Obo, Zhireken, Shakhtama and Sora porphyry Cu-Mo and Mo-Cu deposits of Russia (Siberia) and Mongolia. The Re contents in the majority of the concentrates are low, ranging from 6 to 460 ppm. The maximum Re contents were determined in molybdenite concentrates from the Aksug (460 ppm Re) and Erdenetuin-Obo (199 ppm Re) Co-Mo porphyry deposits and are significantly higher than those from the Zhireken, Shakhtama and Sora Mo-Cu porphyry deposits. The Re content of molybdenite concentrates from the studied Mo-Cu porphyry deposits (6 to 57 ppm) are, however, comparable to those from comparable deposits worldwide. The Aksug and Erdenetuin-Obo deposits, with relatively elevated Re content, differ from the Zhireken, Shakhtama and Sora deposits with lower Re contents in terms of (1) higher Cu/Mo ratio; (2) lower δ34S and 87Sr/86Sr values; (3) silica and alkali contents of the host rocks; (4) the alteration type of the associated rocks; (5) the elevated Cl activity in the fluid; (6) the lower temperature of the molybdenite formation; and (7) the higher oxidized conditions. The Re contents of molybdenite from porphyry Cu-Mo deposits may therefore be related to the composition of parent magmas themselves and/or fractionation, sources of the material, and variations of physical and chemical conditions of crystallization (fO2, Cl activity, P, T). © 2005 Elsevier B.V. All rights reserved

    First finding of merenskyite (Pd,Pt)Te2 in porphyry Cu-Mo ores in Russia

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    Contents of Pt and Pd were determined in weakly mineralized rocks, ores, and flotation concentrates of the Aksug porphyry Cu-Mo deposit, northeastern Tuva. In all studied samples they are above the detection limits: Pt = 17-96 ppb and Pd = 9-924 ppb. These elements are unevenly distributed throughout the rocks and ores, with Pd/Pt varying from 0.5 to 37. Study of Pd-rich ores (up to 924 ppb, Pd/Pt = 37) on a JEOL JSM 5600 scanning electron microscope revealed finest (2-5 μm) merenskyite inclusions (25.20% Pd, 1.21% Pt, 72.31% Te) in chalcopyrite. The calculated crystallochemical formula of merenskyite from ores of the Aksug deposit is (Pd0.862Pt0.023Cu0.026Fe0.025)Te2.064. The merenskyite is associated with electrum (79.92% Au, 18.96% Ag), monazite, cobaltite, tennantite, and Sr-containing barite (4.6-18.0% Sr). Palladium mineralization occurs in massive chalcopyrite veinlets in zones of intensely propylitized rocks. The Devonian Aksug ore-bearing porphyry complex developed in the field of Early-Middle Cambrian intrusions of gabbro-diorite-plagiogranites associated with basalt-andesite effusions of island-arc complex. This might have led to high PGE contents in the Aksug rocks. The deposit formation proceeded with the participation of ore-bearing Cl-enriched fluids favoring the concentration and transport of PGE in porphyry copper systems. © 2007

    Pilot study of the multicentre DISCHARGE Trial: image quality and protocol adherence results of computed tomography and invasive coronary angiography

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    Objective To implement detailed EU cardiac computed tomography angiography (CCTA) quality criteria in the multicentre DISCHARGE trial (FP72007-2013, EC-GA 603266), we reviewed image quality and adherence to CCTA protocol and to the recommendations of invasive coronary angiography (ICA) in a pilot study. Materials and methods From every clinical centre, imaging datasets of three patients per arm were assessed for adherence to the inclusion/exclusion criteria of the pilot study, predefined standards for the CCTA protocol and ICA recommendations, image quality and non-diagnostic (NDX) rate. These parameters were compared via multinomial regression and ANOVA. If a site did not reach the minimum quality level, additional datasets had to be sent before entering into the final accepted database (FADB). Results We analysed 226 cases (150 CCTA/76 ICA). The inclusion/exclusion criteria were not met by 6 of the 226 (2.7%) datasets. The predefined standard was not met by 13 of 76 ICA datasets (17.1%). This percentage decreased between the initial CCTA database and the FADB (multinomial regression, 53 of 70 vs 17 of 75 [76%] vs [23%]). The signal-to-noise ratio and contrast-to-noise ratio of the FADB did not improve significantly (ANOVA, p = 0.20; p = 0.09). The CTA NDX rate was reduced, but not significantly (initial CCTA database 15 of 70 [21.4%]) and FADB 9 of 75 [12%]; p = 0.13). Conclusion We were able to increase conformity to the inclusion/exclusion criteria and CCTA protocol, improve image quality and decrease the CCTA NDX rate by implementing EU CCTA quality criteria and ICA recommendations.Cardiovascular Aspects of Radiolog
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