14 research outputs found

    Microstructure and mechanical behavior of superelastic Ti-24Nb-0.5O and Ti-24Nb-0.5N biomedical alloys

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    International audienceIn this study, the microstructure and the mechanical properties of two new biocompatible superelastic alloys, Ti-24Nb-0.5O and Ti-24Nb-0.5N (at.%), were investigated. Special attention was focused on the role of O and N addition on α″ formation, supereleastic recovery and mechanical strength by comparison with the Ti-24Nb and Ti-26Nb (at.%) alloy compositions taken as references. Microstructures were characterized by optical microscopy, X-ray diffraction and transmission electron microscopy before and after deformation. The mechanical properties and the superelastic behavior were evaluated by conventional and cyclic tensile tests. High tensile strength, low Young's modulus, rather high superelastic recovery and excellent ductility were observed for both superelastic Ti-24Nb-0.5O and Ti-24Nb-0.5N alloys. Deformation twinning was shown to accommodate the plastic deformation in these alloys and only the {332}〈113〉 twinning system was observed to be activated by electron backscattered diffraction analyses

    Elaboration et caractérisation d'alliages de type Ti-Nb-X (X = O, N) pour des applications biomédicales Synthesis and characterisation of Ti-Nb-X (X = O, N) alloys for biomedical application

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    Dans cette Ă©tude, trois alliages de titane ÎČ-mĂ©tastables de composition Ti-27Nb, Ti-24Nb-0.5N et Ti-24Nb-0.5O ont Ă©tĂ© Ă©laborĂ©s par fusion. Ces trois alliages prĂ©sentent des propriĂ©tĂ©s superĂ©lastiques lors des essais de traction. Des essais de traction in-situ sous rayonnement synchrotron nous ont permis de monter que cette superĂ©lasticitĂ© est due Ă  une transformation martensitique rĂ©versible ÎČ â†’ α” bien connue pour deux alliages alors que celui contenant de l'oxygĂšne prĂ©sente un comportement moins conventionnel. Les tempĂ©ratures caractĂ©ristiques (MS, MF) de la transformation martensitique ÎČ (austĂ©nite) vers α” (martensite) et celles (AS, AF) de la transformation inverse α” vers ÎČ ont aussi Ă©tĂ© dĂ©terminĂ©es par des essais mĂ©caniques dynamiques. Ces tempĂ©ratures caractĂ©ristiques augmentent linĂ©airement avec la contrainte externe et cette augmentation suit la relation de Clausius Clapeyron. <br> Ti-Nb based alloys are well known to their good mechanical properties, shape memory effect, superelasticity, as well as good biocompatibility. Our study is focused on the improvement of their mechanical properties by adding alloying element such as oxygen or nitrogen. Superelasticity was drastically improved by addition of a few amount (0.5 at %) of oxygen or nitrogen. Martensitic transformation between the ÎČ parent phase (austenite) and α” product phase (martensite), responsible for the superelastic property, has been extensively studied by Dynamic Mechanical Analysis (DMA) and in-situ tensile test under X-ray synchrotron diffraction

    Synthesis and characterization of new superelastic and low elastic modulus Ti-Nb-X alloys for biomedical application.

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    International audienceTi-Nb based alloys are well known to their good mech. properties, shape memory effect, superelasticity, as well as good biocompatibility. The Ti-24Nb (at%) binary alloy presents a shape memory behavior and low elastic modulus. Our study is focused on the improvement of their mech. properties by adding a third alloying element (oxygen, nitrogen or silicon). Addn. of 0.5 at% of N or O modifies drastically the mech. behavior of Ti-24Nb alloy that exhibits superelastic behavior instead of shape memory one. On the other hand, addn. of 0.5 at% of Si increased yield strength of the Ti-24Nb shape memory alloy. [on SciFinder(R)

    In situ synchrotron X-ray diffraction study of the martensitic transformation in superelastic Ti-24Nb-0.5N and Ti-24Nb-0.5O alloys.

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    International audienceMechanisms of superelasticity were investigated by in situ cyclic tensile tests performed under synchrotron X-ray radiation on Ti-24Nb-0.5N and Ti-24Nb-0.5O compns. of metastable ÎČ titanium alloys. Analyses of diffraction patterns acquired under load and after unloading for each cycle were used to det. the characteristics of the potential mechanisms of deformation in both alloys. The Ti-24Nb-0.5N alloy exhibits the conventional behavior of superelastic ÎČ titanium alloys. Synchrotron X-ray diffraction (SXRD) expts. proved that superelasticity is exclusively due to the occurrence of a stress-induced martensitic (SIM) transformation from the ÎČ phase to the α'' phase. The evolution of vol. fraction of α'' martensite corresponds exactly to the variation of the recovery strain of the cyclic tensile curve. Conversely, the Ti-24Nb-0.5O alloy displays a non-conventional behavior. SXRD expts. showed a huge ability of the ÎČ phase to deform elastically until 2.1%. Surprisingly, a reversible SIM transformation also occurs in this alloy but starts after 1% of applied strain that corresponds to the yield point of the stress-strain curve. Although the SIM transformation occurs, the ÎČ phase simultaneously continues to deform elastically. The superelasticity of this alloy is unexpectedly due to a combination of a high elastic deformability of the ÎČ phase and a reversible SIM transformation. In both alloys, the lattice parameters of the α'' martensite evolve similarly in accordance with the initial texture of the ÎČ phase and the crystallog. of the transformation
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