Nonresonant valence-to-core x-ray emission spectroscopy of niobium

The valence-to-core (V2C) portion of x-ray emission spectroscopy (XES) measures the electron states close to the Fermi level. These states are involved in bonding, thus providing a measure of the chemistry of the material. In this article, we show the V2C XES spectra for several niobium compounds. The K β ′′ peak in the V2C XES results from the transition of a ligand 2 s electron into the 1 s core-hole of the niobium, a transition allowed by hybridization with the niobium 4 p . This location in energy of this weak peak shows a strong ligand dependence, thus providing a sensitive probe of the ligand environment about the niobium

Water Formation Reaction under Interfacial Confinement: Al0.25Si0.75O2 on O-Ru(0001)

Confined nanosized spaces at the interface between a metal and a seemingly inert material, such as a silicate, have recently been shown to influence the chemistry at the metal surface. In prior work, we observed that a bilayer (BL) silica on Ru(0001) can change the reaction pathway of the water formation reaction (WFR) near room temperature when compared to the bare metal. In this work, we looked at the effect of doping the silicate with Al, resulting in a stoichiometry of AlSiO . We investigated the kinetics of WFR at elevated H pressures and various temperatures under interfacial confinement using ambient pressure X-ray photoelectron spectroscopy. The apparent activation energy was lower than that on bare Ru(0001) but higher than that on the BL-silica/Ru(0001). The apparent reaction order with respect to H was also determined. The increased residence time of water at the surface, resulting from the presence of the BL-aluminosilicate (and its subsequent electrostatic stabilization), favors the so-called disproportionation reaction pathway (*HO + *O ↔ 2 *OH), but with a higher energy barrier than for pure BL-silica.Research was carried out in part at the 23-ID-2 (IOS) beamline of the National Synchrotron Light Source II and the Center for Functional Nanomaterials, which are U.S. DOE Office of Science Facilities, and the Scientific Data and Computing Center, a component of the Computational Science Initiative, at Brookhaven National Laboratory under Contract No. DE-SC0012704. This research used resources of the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. J.C. thanks the Spanish Ministry of Science, Innovation and Universities for a “Severo Ochoa” grant (BES-2015-075748) through “Severo Ochoa” Excellence Programme (SEV-2016-0683). Z.D. is supported by ACS PRF grant #61059-ND5

A novel GH1 functional mutation in a family with isolated growth hormone deficiency

[No abstract available

Sentinel-2 Analysis of Spruce Crown Transparency Levels and their Environmental Drivers after Summer Drought in the Northern Eifel (Germany)

Droughts in recent years weaken the forest stands in Central Europe, where especially the spruce suffers from an increase in defoliation and mortality. Forest surveys monitor this trend based on sample trees at the local scale, whereas earth observation is able to provide area-wide information. With freely available cloud computing infrastructures such as Google Earth Engine, access to satellite data and high-performance computing resources has become straightforward. In this study, a simple approach for supporting the spruce monitoring by Sentinel-2 satellite data is developed. Based on forest statistics and the spruce NDVI cumulative distribution function of a reference year, a training data set is obtained to classify the satellite data of a target year. This provides insights into the changes in tree crown transparency levels. For the Northern Eifel region, Germany, the evaluation shows an increase in damaged trees from 2018 to 2020, which is in line with the forest inventory of North Rhine-Westphalia. An analysis of tree damages according to precipitation, land surface temperature, elevation, aspect, and slope provides insights into vulnerable spruce habitats of the region and enables to identify locations where the forest management may focus on a transformation from spruce monocultures to mixed forests with higher biodiversity and resilience to further changes in the climate system

COMBINATION OF HIRSCHSPRUNG DISEASE AND A NOVEL DEFINED MUTATION RELATED CONGENITAL ADRENAL HYPERPLASIA IN CYP21A2 GENE: CASE PRESENTATION

WOS: 000412595405015

A NOVEL FRAMESHIFT MUTATION IN ESCO2 GENE CAUSE ROBERTS SYNDROME: CASE PRESENTATION

WOS: 000412595404145