453 research outputs found

    Iron oxyhydroxide aerogels and xerogels by controlled hydrolysis of FeCl3[middle dot]6H2O in organic solvents: stages of formation

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    Iron oxyhydroxide aerogels and xerogels were prepared by controlled hydrolysis of FeCl3[middle dot]6H2O in organic solvents by using a limited amount of water or consuming solely water molecules available from the crystals. Ethanol, ethylene glycol, dimethyl sulfoxide (DMSO) and dimethyl formamide (DMFA) solvents were used, the hydrolysis was promoted with epichlorohydrin proton scavanger. High surface area aerogels were prepared by supercritical CO2 extraction of solvents, surface area and pore distribution measurements were performed on them. Aerogel and xerogel samples were characterized by XRD, Mossbauer spectroscopy and HRTEM methods. The process of hydrolysis was followed by recording Mossbauer spectra of frozen reaction mixtures. Stepwise progress and appearance of transient components were detected in DMSO and DMFA solvents. Aerogel samples exhibit asymmetric spectra with low probability of Mossbauer effect in their as synthesized state. In contrast, frozen reaction mixtures, gels, dry xerogels and compressed aerogels display symmetric spectra with high probability of the Mossbauer resonance. XRD proves the dominant presence of 2-line ferrihydrite. HRTEM studies reveal 4-8 nm typical particle sizes with 0.21-1.0 nm characteristic lattice distances. Different types of coordination environments are distinguished for iron in the formed ferrihydrite nanoparticles due to structural features and imperfections

    Modularity measure of networks with overlapping communities

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    In this paper we introduce a non-fuzzy measure which has been designed to rank the partitions of a network's nodes into overlapping communities. Such a measure can be useful for both quantifying clusters detected by various methods and during finding the overlapping community-structure by optimization methods. The theoretical problem referring to the separation of overlapping modules is discussed, and an example for possible applications is given as well

    Outline analysis of the grapevine (Vitis vinifera L.) berry shape by elliptic Fourier descriptors

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    Grapevine berry morphology is one of the most important features in table grape production. In this study, berry samples of 46 grapevine accessions were investigated for 3 consecutive years with elliptic Fourier descriptors (EFD) to evaluate shape diversity. Ten reference shapes obtained from the OIV descriptor list were involved and principal component (PC) scores summarizing the EFD's were statistically evaluated with Two way ANOVA and discriminant analysis. The cummulative contribution of the five principal components was 96.83 %. Two way ANOVA revealed that berry shape had high variability within the accessions and years. Based on the linear discriminant analysis, reference shapes were compared to those of the accessions and graphic reconstruction was carried out. OIV references were considered as unknown samples and grouped into the accession classes. Overall correct classification of the accessions into their group was 13.88 %. Our results showed that EFD together with reference shapes are a powerful method to discribe berry shape and possibly give the future basis of uvometric evaluation of grapevine cultivars

    Comparison of Raspberry bushy dwarf virus isolates from Hungary and Slovenia

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    In 2006 and 2007 samples of grapevine and Rubus species were collected and analysed by DAS-ELISA to survey the presence of Raspberry bushy dwarf virus (RBDV) in Slovenia and Hungary. Seven varieties of raspberry from one Hungarian collection orchard were found to be infected. In Slovenia the presence of RBDV was confirmed only in three samples of wild Rubus. None of the 133 samples from different locations in Hungary proved to be infected with RBDV, although this virus is found to be widely distributed in grapevine in neighbouring Slovenia. Serological characterisation with three monoclonal antibodies (R2, R5 and D1) was performed on positive samples. Selected positive samples were partially sequenced. The results of serological and molecular analyses were compared with the analyses of raspberry and grapevine isolates obtained in Slovenia from other projects and published RBDV sequences from the GeneBank database to study the variability among hosts and locations. Isolates from grapevine grouped separately from the black raspberry isolate and all the red raspberry isolates. RBDV isolates from Hungarian samples formed a subgroup within red and black raspberry group.Keywords: RBDV, variability, Rubus, raspberry, grapevine, sequences, monoclonal antibodie

    HAT-P-4b: A metal-rich low-density transiting hot Jupiter

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    We describe the discovery of HAT-P-4b, a low-density extrasolar planet transiting BD+36 2593, a V = 11.2 mag slightly evolved metal-rich late F star. The planet's orbital period is 3.056536+/-0.000057 d with a mid-transit epoch of 2,454,245.8154 +/- 0.0003 (HJD). Based on high-precision photometric and spectroscopic data, and by using transit light curve modeling, spectrum analysis and evolutionary models, we derive the following planet parameters: Mp= 0.68 +/- 0.04 MJ, Rp= 1.27 +/- 0.05 RJ, rho = 0.41 +/- 0.06 g cm-3 and a = 0.0446 +/- 0.0012 AU. Because of its relatively large radius, together with its assumed high metallicity of that of its parent star, this planet adds to the theoretical challenges to explain inflated extrasolar planets.Comment: 5 pages, accepted for publication in ApJ

    HAT-P-3b: A heavy-element rich planet transiting a K dwarf star

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    We report the discovery of a Jupiter-size planet transiting a relatively bright (V = 11.56) and metal-rich early K dwarf star with a period of about 2.9 days. On the basis of follow-up photometry and spectroscopy we determine the mass and radius of the planet, HAT-P-3b, to be M_p = 0.599 +/- 0.026 M_Jup and R_p = 0.890 +/- 0.046 R_Jup. The relatively small size of the object for its mass implies the presence of about 75 Earth masses worth of heavy elements (1/3 of the total mass) based on current theories of irradiated extrasolar giant planets, similar to the mass of the core inferred for the transiting planet HD 149026b. The bulk density of HAT-P-3b is found to be rho_p = 1.06 +/- 0.17 g/cm^3, and the planet orbits the star at a distance of 0.03894 AU. Ephemerides for the transit centers are T_c = 2,454,218.7594 +/- 0.0029 + N (2.899703 +/- 0.000054) (HJD).Comment: To appear in ApJ

    HAT-P-17b,c: A Transiting, Eccentric, Hot Saturn and a Long-period, Cold Jupiter

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    We report the discovery of HAT-P-17b,c, a multi-planet system with an inner transiting planet in a short-period, eccentric orbit and an outer planet in a 4.8 yr, nearly circular orbit. The inner planet, HAT-P-17b, transits the bright V = 10.54 early K dwarf star GSC 2717-00417, with an orbital period P = 10.338523 +/- 0.000009 d, orbital eccentricity e = 0.346 +/- 0.007, transit epoch T_c = 2454801.16945 +/- 0.00020, and transit duration 0.1691 +/- 0.0009 d. HAT-P-17b has a mass of 0.530 +/- 0.018 M_J and radius of 1.010 +/- 0.029 R_J yielding a mean density of 0.64 +/- 0.05 g cm^-3. This planet has a relatively low equilibrium temperature in the range 780-927 K, making it an attractive target for follow-up spectroscopic studies. The outer planet, HAT-P-17c, has a significantly longer orbital period P_2 = 1797^+58_-89 d and a minimum mass m_2 sin i_2 = 1.4^+1.1_-0.4 M_J. The orbital inclination of HAT-P-17c is unknown as transits have not been observed and may not be present. The host star has a mass of 0.86 +/- 0.04 M_Sun, radius of 0.84 +/- 0.02, effective temperature 5246 +/- 80 K, and metallicity [Fe/H] = 0.00 +/- 0.08. HAT-P-17 is the second multi-planet system detected from ground-based transit surveys.Comment: Submitted to ApJ, 13 pages, 6 figures, 6 table

    Antagonism between Bacteriostatic and Bactericidal Antibiotics Is Prevalent

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    Combination therapy is rarely used to counter the evolution of resistance in bacterial infections. Expansion of the use of combination therapy requires knowledge of how drugs interact at inhibitory concentrations. More than 50 years ago, it was noted that, if bactericidal drugs are most potent with actively dividing cells, then the inhibition of growth induced by a bacteriostatic drug should result in an overall reduction of efficacy when the drug is used in combination with a bactericidal drug. Our goal here was to investigate this hypothesis systematically. We first constructed time-kill curves using five different antibiotics at clinically relevant concentrations, and we observed antagonism between bactericidal and bacteriostatic drugs. We extended our investigation by performing a screen of pairwise combinations of 21 different antibiotics at subinhibitory concentrations, and we found that strong antagonistic interactions were enriched significantly among combinations of bacteriostatic and bactericidal drugs. Finally, since our hypothesis relies on phenotypic effects produced by different drug classes, we recreated these experiments in a microfluidic device and performed time-lapse microscopy to directly observe and quantify the growth and division of individual cells with controlled antibiotic concentrations. While our single-cell observations supported the antagonism between bacteriostatic and bactericidal drugs, they revealed an unexpected variety of cellular responses to antagonistic drug combinations, suggesting that multiple mechanisms underlie the interactions

    HAT-P-5b: A Jupiter-like hot Jupiter Transiting a Bright Star

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    We report the discovery of a planet transiting a moderately bright (V = 12.00) G star, with an orbital period of 2.788491 +/-0.000025 days. From the transit light curve we determine that the radius of the planet is Rp = 1.257 +/- 0.053 RJup. HAT-P-5b has a mass of Mp = 1.06 +/- 0.11 MJup, similar to the average mass of previously-known transiting exoplanets, and a density of rho = 0.66 +/- 0.11 g cm^-3 . We find that the center of transit is Tc = 2,454,241.77663 +/- 0.00022 (HJD), and the total transit duration is 0.1217 +/- 0.0012 days.Comment: 5 pages, submitted to APJ
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