A two-colour heterojunction unipolar nanowire light-emitting diode by tunnel injection

We present a systematic study of the current-voltage characteristics and electroluminescence of gallium nitride (GaN) nanowire on silicon (Si) substrate heterostructures where both semiconductors are n-type. A novel feature of this device is that by reversing the polarity of the applied voltage the luminescence can be selectively obtained from either the nanowire or the substrate. For one polarity of the applied voltage, ultraviolet (and visible) light is generated in the GaN nanowire, while for the opposite polarity infrared light is emitted from the Si substrate. We propose a model, which explains the key features of the data, based on electron tunnelling from the valence band of one semiconductor into the conduction band of the other semiconductor. For example, for one polarity of the applied voltage, given a sufficient potential energy difference between the two semiconductors, electrons can tunnel from the valence band of GaN into the Si conduction band. This process results in the creation of holes in GaN, which can recombine with conduction band electrons generating GaN band-to-band luminescence. A similar process applies under the opposite polarity for Si light emission. This device structure affords an additional experimental handle to the study of electroluminescence in single nanowires and, furthermore, could be used as a novel approach to two-colour light-emitting devices.Comment: 9 pages, 11 figure

Vanadium dioxide as a natural disordered metamaterial: perfect thermal emission and large broadband negative differential thermal emittance

We experimentally demonstrate that a thin (~150 nm) film of vanadium dioxide (VO2) deposited on sapphire has an anomalous thermal emittance profile when heated, which arises due to the optical interaction between the film and the substrate when the VO2 is at an intermediate state of its insulator-metal transition (IMT). Within the IMT region, the VO2 film comprises nanoscale islands of metal- and dielectric-phase, and can thus be viewed as a natural, disordered metamaterial. This structure displays "perfect" blackbody-like thermal emissivity over a narrow wavelength range (~40 cm-1), surpassing the emissivity of our black soot reference. We observed large broadband negative differential thermal emittance over a >10 {\deg}C range: upon heating, the VO2/sapphire structure emitted less thermal radiation and appeared colder on an infrared camera. We anticipate that emissivity engineering with thin film geometries comprising VO2 will find applications in infrared camouflage, thermal regulation, infrared tagging and labeling.Comment: 3 figure

Nonlinear feedback oscillations in resonant tunneling through double barriers

We analyze the dynamical evolution of the resonant tunneling of an ensemble of electrons through a double barrier in the presence of the self-consistent potential created by the charge accumulation in the well. The intrinsic nonlinearity of the transmission process is shown to lead to oscillations of the stored charge and of the transmitted and reflected fluxes. The dependence on the electrostatic feedback induced by the self-consistent potential and on the energy width of the incident distribution is discussed.Comment: 10 pages, TeX, 5 Postscript figure

Comparison of latest and innovative silica-based consolidants for volcanic stones

This research explores the new perspectives in conservation and protection of two macroporous tuff stones, widely employed in the architectural heritage of Campania region, characterized by highly heterogeneous rock fabric and texture and a variable mineralogical composition that represent crucial factors responsible for their weak durability. The consolidation treatments were performed with a recently and widely used suspension of nano-silica crystals in water and with a lithium silicate solution that has received up to now scarce attention as a consolidant agent. Physical investigations (open porosity, Hg porosimetry, water absorption), morphological observations (SEM analyses) and visual appearance test (colorimetric measurements), along with assessments of performance indicators such as ultrasonic pulse velocity, surface cohesion test (peeling test) and durability test (salt crystallization), were carried out to investigate the consolidation effectiveness. Overall, lithium silicate consolidant showed a better behavior in terms of superficial cohesion, a most successful strengthening action and a considerable enhancement of salt resistance