Reaction flash sintering for producing high quality functional ceramics within seconds

For ceramic materials, it has been recently shown in literature that applying a small electric field and a small DC current through a sample produces sudden sintering (within seconds) at relatively low temperatures. This method is known as Flash Sintering and it has been applied to number of materials. In this work it is shown that both chemical reaction and sintering can be combined into a single flash sintering experiments. This new approach is known as Reaction Flash Sintering. To demonstrate the feasibility of this method, a multiferroic material, BiFeO3, is prepared from a stoichiometric mixture of Bi2O3 and Fe2O3 oxides. Thus, in a single process, dense nanostructured BiFeO3 ceramics are obtained by applying an electric field of 50 V cm-1 and with a current limit of 35 mA mm-2 within seconds at a furnace temperature of about 625 °C. The resulting materials were pure-phase perovskites without any evidence of secondary phases, sillenite or mullite, that are commonly present in materials prepared by conventional procedures. Moreover, samples were electrically insulating, as measured by complex impedance spectroscopy. It is shown here that the synthesis of pure single-phase ceramics of complex oxides from stoichiometric mixtures of single oxides is possible by reaction flash sintering, even for materials difficult to prepare by conventional procedures. This discovery is a breakthrough in materials preparation

Defect chemistry and electrical properties of BiFeO3

BiFeO3 attracts considerable attention for its rich functional properties, including room temperature coexistence of magnetic order and ferroelectricity and more recently, the discovery of conduction pathways along ferroelectric domain walls. Here, insights into the defect chemistry and electrical properties of BiFeO3 are obtained by in situ measurements of electrical conductivity, σ, and Seebeck coefficient, α, of undoped, cation-stoichiometric BiFeO3 and acceptor-doped Bi1−xCaxFeO3−δ ceramics as a function of temperature and oxygen partial pressure pO2. Bi1−xCaxFeO3−δ exhibits p-type conduction; the dependencies of σ and α on pO2 show that Ca dopants are compensated mainly by oxygen vacancies. By contrast, undoped BiFeO3 shows a simultaneous increase of σ and α with increasing pO2, indicating intrinsic behavior with electrons and holes as the main defect species in almost equal concentrations. The pO2-dependency of σ and α cannot be described by a single point defect model but instead, is quantitatively described by a combination of intrinsic and acceptor-doped characteristics attributable to parallel conduction pathways through undoped grains and defect-containing domain walls; both contribute to the total charge transport in BiFeO3. Based on this model, we discuss the charge transport mechanism and carrier mobilities of BiFeO3 and show that several previous experimental findings can readily be explained within the proposed model

Electrical properties of bismuth ferrites:Bi2Fe4O9 and Bi25FeO39

Bi2Fe4O9 was prepared by solid-state reaction and the electrical properties measured by impedance spectroscopy. After annealing in O2 at 900 °C, Bi2Fe4O9 is an electrically-homogeneous insulator. Its high frequency permittivity is constant (∼14.1) over the temperature range 300–400 °C and shows no evidence of incipient ferroelectricity at lower temperatures. On annealing in N2 at 900 °C, the pellets gradually decompose. Bi25FeO39 was prepared by both solid-state reaction and mechanosynthesis. It showed a modest amount of mixed conduction of both oxide ions and holes. Impedance analysis showed a complex response that best fitted an equivalent circuit consisting of a parallel combination of long-range conduction and short range dielectric relaxation elements. The electrical conductivity of both Bi2Fe4O9 and Bi25FeO39 is less than that of BiFeO3 prepared by solid-state reaction, which indicates that any leakage conductivity of BiFeO3 is not due to the possible presence of small amounts of these secondary phases

Reductive lithium insertion into B-cation deficient niobium perovskite oxides.

Reaction between LiH and the AnBn-1O3n cation deficient perovskite phases Ba5Nb4O15, Ba6TiNb4O18 and Ba3LaNb3O12 proceeds by reductive lithium insertion, leading to the formation of Ba5LiNb4O15, Ba6LiTiNb4O18 and Ba3LaLiNb3O12 respectively. During lithium insertion into Ba5Nb4O15 and Ba6TiNb4O18 the respective ccchh and cccchh stacking sequences are converted into entirely cubic stacking sequences, while the B-cation vacancy order of the two phases is faithfully converted into Li-Nb or Li-Nb/Ti cation order in the lithiated products. In contrast lithium insertion into Ba3LaNb3O12 leads to no gross change in structure, with the inserted lithium cations displacing some of the niobium cations leading to a cation disordered material. Transport measurements indicate semiconducting behaviour consistent with variable range hopping for Ba5LiNb4O15 and insulating behaviour for Ba6LiTiNb4O18 and Ba3LaLiNb3O12. Detailed analysis of the crystal structure of Ba6LiTiNb4O18 suggests crystallographic charge ordering in this phase

Bioconstructions of the Eocene South Pyrenean Foreland Basin (Vic and Igualada areas) and of the Upper Cretaceous South Central Pyrenees (Tremp area) Field trip C

Centro de Informacion y Documentacion Cientifica (CINDOC). C/Joaquin Costa, 22. 28002 Madrid. SPAIN / CINDOC - Centro de Informaciòn y Documentaciòn CientìficaSIGLEESSpai

7. international symposium on fossil cnidaria and porifera Abstracts

Centro de Informacion y Documentacion Cientifica (CINDOC). C/Joaquin Costa, 22. 28002 Madrid. SPAIN / CINDOC - Centro de Informaciòn y Documentaciòn CientìficaSIGLEESSpai

Paleozoic cnidaria and porifera from Sierra Morena Field trip D

Centro de Informacion y Documentacion Cientifica (CINDOC). C/Joaquin Costa, 22. 28002 Madrid. SPAIN / CINDOC - Centro de Informaciòn y Documentaciòn CientìficaSIGLEESSpai

Pressure Effect on the Multicycle Activity of Natural Carbonates and a Ca/Zr Composite for Energy Storage of Concentrated Solar Power

This work is focused on the use of the Calcium-Looping process (CaL) in Concentrated Solar Power (CSP) plants for Thermochemical Energy Storage (TCES). Cheap, abundant and nontoxic natural carbonate minerals, such as limestone and dolomite, can be employed in this application to store energy through the cyclic calcination/carbonation of CaCO₃. In a recent work, a closed CO₂ cycle has been proposed for an efficient CaL-CSP integration in which the CO₂ in excess effluent from the carbonator is used to generate electricity by means of a gas turbine. Process simulations show that the thermoelectric efficiency is enhanced as the carbonator pressure and temperature are increased provided that the multicycle CaO conversion is not affected. On the other hand, the use of just one reactor for both calcination and carbonation has been suggested to reduce capital cost. However, the experimental results shown in the present work indicate that sintering is notably enhanced as the pressure in the reactor is increased. Such an adverse effect is mitigated for a ZrO₂/CaCO₃ composite with a low Zr content as compared to natural carbonates. These results are relevant to process simulations for better assessing the global efficiency of the CaL-CSP integration