Evolution of organic and inorganic components of aerosol during a Saharan dust episode observed in the French Alps

International audienceA Saharan dust event was observed in a rural area in the Maurienne Valley (French Alps) in summer 2000. Detailed data on PM10, particle numbers, and aerosol chemistry (ionic species and Elemental Carbon (EC) and Organic Carbon (OC)) are presented. The comparative evolutions of particle numbers and chemistry (calcium, sodium, and sulfate) show that the overall period included two episodes of dust particles with very distinct chemistry, followed by an episode with a large increase of the concentrations of species with an anthropogenic origin. The overall data set does not indicate large interactions between the dust particles and compounds from anthropogenic origin (sulfate, nitrate) or with organic carbon, all of these species showing very low concentrations. Simplistic calculations indicate that these concentrations are consistent with our current knowledge of adsorption processes of gases on mineral dust in a clean air mass

Fission Product Distribution in ORR Fuel Elements

The gamma rays emitted by ORR fuel elements and by the fuel section of shim rods are measured as a function of position along the elements with a very small graphite ionization chamber. Comparison of the fuel burnup calculated from the gamma measurements and by the flux-time method shows good agreement. This means that the gammaray distribution measurements could be a good method of determining the U/sup 235/ consumption in fuel elements. Distributions of the macroscopic absorption cross section and the infinite multiplication factor along fuel elements are computed from the gamma dose rate distribution. The limited usefulness of the shim rod fuel section is discussed in the last section. (auth

Halogenated organic species over the tropical South American rainforest

Airborne measurements of the halogenated trace gases methyl chloride, methyl bromide and chloroform were conducted over the Atlantic Ocean and about 1000 km of pristine tropical rainforest in Suriname and French Guyana (3–6° N, 51–59° W) in October 2005. In the boundary layer (0–1.4 km), maritime air masses, advected over the forest by southeasterly trade winds, were measured at various distances from the coast. Since the organohalogens presented here have relatively long atmospheric lifetimes (0.4–1.0 years) in comparison to the advection times from the coast (1–2 days), emissions will accumulate in air traversing the rainforest. The distributions of methyl chloride, methyl bromide and chloroform were analyzed as a function of time the air spent over land and the respective relationship used to determine net fluxes from the rainforest for one week within the long dry season. <br><br> Net fluxes from the rainforest ecosystem have been calculated for methyl chloride and chloroform as 9.5 (±3.8 2σ) and 0.35 (±0.15 2σ)μg m<sup>-2</sup> h<sup>−1</sup>, respectively. No significant flux was observed for methyl bromide within the limits of these measurements. <br><br> The global budget of methyl chloride contains large uncertainties, in particular with regard to a possible source from tropical vegetation. Our measurements are used in a large-scale approach to determine the net flux from a tropical ecosystem to the planetary boundary layer. The obtained global net flux of 1.5 (±0.6 2σ) Tg yr<sup>-1</sup> for methyl chloride is at the lower end of current estimates for tropical vegetation sources, which helps to constrain the range of tropical sources and sinks (0.82 to 8.2 Tg yr<sup>-1</sup> from tropical plants, 0.03 to 2.5 Tg yr<sup>-1</sup> from senescent/dead leaves and a sink of 0.1 to 1.6 Tg yr<sup>-1</sup> by soil uptake). Nevertheless, these results show that the contribution of the rainforest ecosystem is the major source in the global budget of methyl chloride. <br><br> For chloroform, the extrapolated global net flux from tropical ecosystems is 56 (±23 2σ) Gg yr<sup>−1</sup>, which is of minor importance compared to the total global sources and might be already contained in the soil emission term

Energy analysis of organic crop systems. Impact of intensification level.

This study reveals a wide variability in the major parameters of the energy analysis applied to 44 four-year-long organic crop sequences. The intensification level of the systems in terms of the use or nonuse of organic fertilisation on cereals and of irrigation on summer crops (mainly pulses) is largely responsible for this variability. Average energy consumption ranges from 5 000 to 12 270 MJ/ha/year depending on the intensification level. Energy production varies from 35 500 to 43 950 MJ/ha/year. Since energy consumption and production both vary in the same direction with the degree of intensification, the energy gain is stable at an average value of 29300 MJ/ha/year. Energy efficiency decreases from 7.1 MJ/MJ for unfertilised and unirrigated crop sequences, to 3.5 MJ/MJ for fertilised and irrigated sequences, where soy and faba bean are among the major crops

KNOWING, CHARACTERIZING AND ASSESSING SYSTEMS OF ORGANIC CROP ROTATIONS

The choice of crop rotations in organic stockless cropping systems is the first leverage used to manage technical issues (to maintain soil fertility, to control pest and weeds) and economic issues (to insure income). The RotAB project (French Casdar funding 2008-2010) implemented complementary approaches to better knowing, characterizing and assessing arable crop rotations. Their conception depends on numerous factors such as the types of soil and climate (on which depend the types of crops, yield potential, possibility of mechanical weed control…) or the economic context (existence of outlets and continuity of markets). If nitrogen supply and weed control are the most important agronomic issues of organic farmers in stockless cropping systems, phosphorus availability appears to be the next important issue for soil fertility and system sustainability

A radio continuum survey of the southern sky at 1420 MHz. Observations and data reduction

We describe the equipment, observational method and reduction procedure of an absolutely calibrated radio continuum survey of the South Celestial Hemisphere at a frequency of 1420 MHz. These observations cover the area 0h < R.A. < 24h for declinations less than -10 degree. The sensitivity is about 50 mK T_B (full beam brightness) and the angular resolution (HPBW) is 35.4', which matches the existing northern sky survey at the same frequency.Comment: 9 pages with 9 figures, A&A, in pres

Seasonal variations in aerosol particle composition at the puy-de-Dôme research station in France

Detailed investigations of the chemical and microphysical properties of atmospheric aerosol particles were performed at the puy-de-Dôme (pdD) research station (1465 m) in autumn (September and October 2008), winter (February and March 2009), and summer (June 2010) using a compact Time-of-Flight Aerosol Mass Spectrometer (cToF-AMS). Over the three campaigns, the average mass concentrations of the non-refractory submicron particles ranged from 10 μg m&lt;sup&gt;&amp;minus;3&lt;/sup&gt; up to 27 μg m&lt;sup&gt;&amp;minus;3&lt;/sup&gt;. Highest nitrate and ammonium mass concentrations were measured during the winter and during periods when marine modified airmasses were arriving at the site, whereas highest concentrations of organic particles were measured during the summer and during periods when continental airmasses arrived at the site. The measurements reported in this paper show that atmospheric particle composition is strongly influenced by both the season and the origin of the airmass. The total organic mass spectra were analysed using positive matrix factorisation to separate individual organic components contributing to the overall organic particle mass concentrations. These organic components include a low volatility oxygenated organic aerosol particle (LV-OOA) and a semi-volatile organic aerosol particle (SV-OOA). Correlations of the LV-OOA components with fragments of &lt;i&gt;m/z&lt;/i&gt; 60 and &lt;i&gt;m/z&lt;/i&gt; 73 (mass spectral markers of wood burning) during the winter campaign suggest that wintertime LV-OOA are related to aged biomass burning emissions, whereas organic aerosol particles measured during the summer are likely linked to biogenic sources. Equivalent potential temperature calculations, gas-phase, and LIDAR measurements define whether the research site is in the planetary boundary layer (PBL) or in the free troposphere (FT)/residual layer (RL). We observe that SV-OOA and nitrate particles are associated with air masses arriving from the PBL where as particle composition measured from RL/FT airmasses contain high mass fractions of sulphate and LV-OOA. This study provides unique insights into the effects of season and airmass variability on regional aerosol particles measured at an elevated site

Advancing national greenhouse gas inventories for agriculture in developing countries : improving activity data, emission factors and software technology

Peer reviewedPublisher PD