Collective effects in spin-crossover chains with exchange interaction

The collective properties of spin-crossover chains are studied. Spin-crossover compounds contain ions with a low-spin ground state and low lying high-spin excited states and are of interest for molecular memory applications. Some of them naturally form one-dimensional chains. Elastic interaction and Ising exchange interaction are taken into account. The transfer-matrix approach is used to calculate the partition function, the fraction of ions in the high-spin state, the magnetization, susceptibility, etc., exactly. The high-spin-low-spin degree of freedom leads to collective effects not present in simple spin chains. The ground-state phase diagram is mapped out and compared to the case with Heisenberg exchange interaction. The various phases give rise to characteristic behavior at nonzero temperatures, including sharp crossovers between low- and high-temperature regimes. A Curie-Weiss law for the susceptibility is derived and the paramagnetic Curie temperature is calculated. Possible experiments to determine the exchange coupling are discussed.Comment: 9 pages, 13 color figures, published versio

Real time contrast enhanced ultrasonography in detection of liver metastases from gastrointestinal cancer

Background: Contrast enhanced ultrasound (CEUS) is an imaging technique which appeared on the market around the year 2000 and proposed for the detection of liver metastases in gastrointestinal cancer patients, a setting in which accurate staging plays a significant role in the choice of treatment. Methods: A total of 109 patients with colorectal (n = 92)or gastric cancer prospectively underwent computed tomography (CT) scan and conventional US evaluation followed by real time CEUS. A diagnosis of metastases was made by CT or, for lesions not visibile at CT, the diagnosis was achieved by histopathology or by a malignant behavior during follow-up. Results: Of 109 patients, 65 were found to have metastases at presentation. CEUS improved sensitivity in metastatic livers from 76.9% of patients (US) to 95.4% (p < 0.01), while CT scan reached 90.8% (p = n.s. vs CEUS, p < 0.01 vs US). CEUS and CT were more sensitive than US also for detection of single lesions (87 with US, 122 with CEUS, 113 with CT). In 15 patients (13.8%), CEUS revealed more metastases than CT, while CT revealed more metastases than CEUS in 9 patients (8.2%) (p = n.s.). Conclusion: CEUS is more sensitive than conventional US in the detection of liver metastases and could be usefully employed in the staging of patients with gastrointestinal cancer. Findings at CEUS and CT appear to be complementary in achieving maximum sensitivity. © 2007 Piscaglia et al; licensee BioMed Central Ltd

Electric-field-induced charge-transfer phase transition: a promising approach toward electrically switchable devices

Much research has been directed toward the development of electrically switchable optical materials for applications in memory and display devices. Here we present experimental evidence for an electric-field-induced charge-transfer phase transition in two cyanometalate complexes: Rb₀․₈Mn-[Fe(CN)₆]₀․₉₃•1.62H₂O and Co₃[W(CN)₈]₂(pyrimidine)₄•6H₂O, involving changes in their magnetic, optical, and electronic properties as well. Application of an electric field above a threshold value and within the thermal hysteresis region leads to a transition from the high- to the low-temperature phase in these compounds. A model is proposed to explain the main observations on the basis of a para-ferroelectric transition. Our observations suggest that this new concept of electrical switching, based on materials exhibiting charge-transfer phase transitions with large thermal hysteresis loops, may open up doors for novel electro-optical devices

Investigation of Prussian Blue Analogs by XMCD at the K-edge of transition metals

International audienc

Mode de détection des produits de contraste échographique [Detection modes of ultrasound contrast agents]

Ultrasound contrast agents have been used for many many years in cardiology. Their application in other fields is more recent, related to the availability of agents that can pass through the pulmonary circulation. Physical properties of contrast microbubbles are closely bound to their gas content, shell composition, frequency of ultrasound beam, pulse repetition frequency, acoustic power and wave phase. Specific ultrasound sequences have to be used to adequately exploit microbubble-specific interactions with the ultrasound beam. The aim of this paper is to review physical properties of ultrasound contrast agents, present imaging sequences developed for optimal use of these contrasts and general applications

Faster Algorithms for Bound-Consistency of the Sortedness and the Alldifferent Constraint

We present narrowing algorithms for the sortedness and the alldifferent constraint which achieve bound-consistency. The algorithm for the sortedness constraint takes as input 2n intervals X1 , ..., Xn , Y1 , ..., Yn from a linearly ordered set D. Let S denote the set of all tuples t 2 X1 Xn Y1 Yn such that the last n components of t are obtained by sorting the first n components. Our algorithm determines whether S is non-empty and if so reduces the intervals to bound-consistency. The running time of the algorithm is asymptotically the same as for sorting the interval endpoints. In problems where this is faster than O(n log n), this improves upon previous results. The algorithm for the alldifferent constraint takes as input n integer intervals Z1 , ..., Zn . Let T denote all tuples t 2 Z1 Zn where all components are pairwise different. The algorithm checks whether T is non-empty and if so reduces the ranges to bound-consistency. The running time is also asymptotically the same as for sorting the interval endpoints. When the constraint is for example a permutation constraint, i.e. Z i [1; n] for all i, the running time is linear. This also improves upon previous results

Comparison between Doppler ultrasonography and multiphase multidetector-row computed tomography in the detection of liver involvement in Rendu-Osler disease: An analysis of 62 patients

International audienc

Photo-excitation from dia- to ferri-magnetism in a Rb-Co-hexacyanoferrate Prussian blue analogue

PACS. 75.50.Xx Molecular magnets - 78.40.Ha Other nonmetallic inorganics - 82.20.Mj Nonequilibrium kinetics,