36 research outputs found

    Scaling and commensurate-incommensurate crossover for the d=2, z=2 quantum critical point of itinerant antiferromagnets

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    Quantum critical points exist at zero temperature, yet, experimentally their influence seems to extend over a large part of the phase diagram of systems such as heavy-fermion compounds and high-temperature superconductors. Theoretically, however, it is generally not known over what range of parameters the physics is governed by the quantum critical point. We answer this question for the spin-density wave to fermi-liquid quantum critical point in the two-dimensional Hubbard model. This problem is in the d=2,z=2d=2,z=2 universality class. We use the Two-Particle Self-Consistent approach, which is accurate from weak to intermediate coupling, and whose critical behavior is the same as for the self-consistent-renormalized approach of Moriya. Despite the presence of logarithmic corrections, numerical results demonstrate that quantum critical scaling for the static magnetic susceptibility can extend up to very high temperatures but that the commensurate to incommensurate crossover leads to deviations to scaling.Comment: Unchanged numerical results. It is now shown analytically that the approach includes logarithmic corrections and that the critical behavior is equivalent to the theory of Moriya. 6 pages, 3 figures, Late

    The hidden world within plants: ecological and evolutionary considerations for defining functioning of microbial endophytes

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    All plants are inhabited internally by diverse microbial communities comprising bacterial, archaeal, fungal, and protistic taxa. These microorganisms showing endophytic lifestyles play crucial roles in plant development, growth, fitness, and diversification. The increasing awareness of and information on endophytes provide insight into the complexity of the plant microbiome. The nature of plant-endophyte interactions ranges from mutualism to pathogenicity. This depends on a set of abiotic and biotic factors, including the genotypes of plants and microbes, environmental conditions, and the dynamic network of interactions within the plant biome. In this review, we address the concept of endophytism, considering the latest insights into evolution, plant ecosystem functioning, and multipartite interactions.EU Cost Action [FA1103, 312117]; FWF (Austrian Science Foundation) [P26203-B22, P24569-B25]; Portuguese FCT (Foundation for Science and Technology) [SFRH/BPD/78931/2011]info:eu-repo/semantics/publishedVersio

    Ueber die Reaction auf Schwefelverbindungen mit Nitroprussidnatrium

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    Ueber den Einfluss einiger organischer Lösungsmittel auf das optische Drehungsvermögen

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    Development and Application of Efficient Ag‐based Hydrogenation Catalysts Prepared from Rice Husk Waste

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    The development of strategies for the sustainable management and valorization of agricultural waste is of outmost importance. With this in mind, we report the use of rice husk (RH) as feedstock for the preparation of heterogeneous catalysts for hydrogenation reactions. The catalysts were prepared by impregnating the milled RH with a silver nitrate solution followed by carbothermal reduction. The composition and morphology of the prepared catalysts were fully assessed by IR, AAS, ICP-MS, XPS, XRD and STEM techniques. This novel bio-genic silver-based catalysts showed excellent activity and remarkable selectivity in the hydrogenation of nitro groups in both aromatic and aliphatic substrates, even in the presence of reactive functionalities like halogens, carbonyls, borate esters or nitriles. Recycling experiments showed that the catalysts can be easily recovered and reused multiple times without significant drop in performance and without requiring re-activation. © 2021 The Authors. ChemCatChem published by Wiley-VCH Gmb
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