聚苯乙烯接枝聚甲基丙烯酸甲酯共聚物的形态结构与性能

扫描电镜观察表明，阴离子聚合、基团转移聚合和大分子反应法联用合成的ＰＳ－ｇ－ＰＭ－ＭＡ共聚物的形态结构是分散的ＰＭＭＡ微粒存在于ＰＳ连续相中的两相体系，其形态特征受制样条件和共聚物组分两方面的影响．ＤＴＡ－ＴＧＡ和应力一应变实验反映了这种接枝共聚物的玻璃化温度降低（Ｔｇ１７５℃，Ｔｇ２４０℃），热分解温度提高（Ｔｄ＝５５０℃，失重＜７０％）和强度增大

一步法合成无规支化聚苯乙烯（ABPS）的研究

在无水ＺｎＣｌ２催化下，用ＳＯ２Ｃｌ２／ＣＨ２（ＯＣＨ３）２法对阴离子聚合所得的窄分子量分布聚苯乙烯（Ｄ＜１．１０）进行氯甲基化反应，同时使生成的氯甲基化聚苯乙烯发生大分子间的Ｆｒｉｅｄｅｌ－Ｃｒａｆｔｓ反应，一步合成了结构明确的无规支化聚苯乙

聚苯乙烯接枝聚甲基丙烯酸甲酯共聚物的合成新方法

聚苯乙烯接枝聚甲基丙烯酸甲酯共聚物的合成新方法①郭金全邹友思戴李宗袁亿文潘容华（厦门大学化学系厦门３６１００５）阴离子聚合［１］和基团转移聚合（ＧＴＰ）［２］技术可分别使非极性单体和极性单体进行活性聚合，得到分子量分布窄、实际分子量和设计分子量相近的..

大分子反应与GTP法合成PSt-g-PMMA共聚物及其结构与性能的研究

本文研究了用大分子反应和基团转移聚合（GTP）联合进行分子结构设计，以合成聚苯乙烯接枝聚甲基丙烯酸甲酯共聚物（PSt-g-PMMA),结果表明：(1）将阴离子聚合所得窄分布聚苯乙烯（NDPS）用氯化硫酰一甲缩醛进行氯甲基化生成氯甲基化聚苯乙烯（CMPS），然后在天对ALCL3催化下使之生成无规支化聚苯乙烯（ABPS），用CMPS和ABPS或二者的混合物与GTP合成的PMMA活性聚合物在萘钠或萘锂破杂下发生偶合接枝，能够得到结构明确（主链和支链分子量均可严格控制）的PSt-g=PMMA规模型化合物；（2）用IR光谱作检测手段摸索出“选择性提取与选择性沉淀法相结合”的新方法能够有效地将接技共聚物分...学位：理学硕士院系专业：化学化工学院化学系_物理化学(含化学物理)学号：1991450

Studies of the Flame-retarding EFFect and Mechanism of CHPA on Flexible PU Foam

本文研究了含活性氢的氯羟丙基磷酸酯(CHPA)对聚氨酯(Pu)软泡的化学阻燃作用及其阻燃机理.结果表明,含12PHrCHPA的Pu软泡阻燃性达到gb10800—89/I级.通过对阻燃机理的研究,可以认为,在燃烧初期Pu—CHPA中的C—Cl键断裂释出HCl,HCl可与磷酸酯相互作用生成POCl_3、PCl_3和POCl_5等不燃性物,在气相起阻燃作用;在燃烧过程中,这些含P化合物在高温有氧存在下又形成具有很强脱水作用的各种形态磷酸,它们使含氧的Pu软泡炭化形成阻隔燃烧的覆盖层,这些是使软泡具有较佳阻燃性的原因.The Flame-retarding eFFect and mechanism of chlorohydroxypropylphosphate(CHPA) containing active hydrogen on PU Foam were studied.The results showed the Foam containing 12 PHR CHPA hit the Flame-retarding speciFication of GB10800-89/I.The result of the study of the Flame-retarding mechanism of CHPA showed in the early stage of combustion, the C -Cl bond in PU -CHPA was broken and HC1 was released to interact with the phosphate so that incombustible compounds such as POC13, PCl3 ,POCl5 were given ofF to act as Flame-retardants.In the very stage of combustion, under higher temperaturs the compoundes containing phosphorus reacted with oxygen to lead to the producing of varieties of phosphoric acids, whose extremely strong eFFect of dehydration carbonized the PU Foam to Form an insulation surFace layer to prevent the material From Further comubstion.These two aspects were the major reasons because of which the Foam had a Fairly good Flame-retardant property

STUDIES of FLAME-RETARDING MECHANISM of CHPA ON FLEXIBLE PU FOAM

采用含活性氢的氯羟丙基磷酸酯（CHPA）参与Pu发泡配方中的异氰酸酯反应，使生成的软质聚氨酯泡沫（软Puf）分子含阻燃元素Cl、P而实现其阻燃化。研究结果表明，含12PHrCHPA的软质Puf的阻燃性能可达gb10800-89/Ⅰ级。着重研究了CHPA对软质Puf的阻燃机理，提出燃烧初期Puf/CHPA中的C-Cl键断裂，释放出HCl与磷酸酯作用，生成POCl3、PCl3、PCl5等不燃性化合物。此P/Cl化合物一方面因其散发速度比HCl慢，而延长在燃烧区域的停滞时间，更有效地在气相起阻燃作用；另一方面，在高温有氧存在下，与氧作用生成各种形态的磷酸，其强烈的脱水作用使含氧的Puf在层碳化而生成阻隔燃烧的覆盖层，起到固相阻燃的作用。二者的协同是使软质Puf呈较佳阻燃效应的原因。In the Foaming of PU,chlorohydroxypropylphosphate(CHPA) was used to react with the isocyanate to participate the Foaming recipe so that Fire-extinguishing elements such as P,Cl was made to join in the molecular chain of PU to make the Foam Flame-retarding.It was studied to show that the Flame-retarding eFFect of the Flexible PUF containing 12 phr CHPA hit the speciFication of GB-10800-89/I.In this paper,the Flame-retarding mechanism is investigated to show that in the early stage of the combustion,C-Cl bond in PU-CHPA is broken and HCl is given ofF to interact with the phosphate so that incombustible compounds such as POCl_3 PCl_3,PCl_3 are released.On the one hand,they have a smaller volatizing speed than HCl and consequently a longer interval of time to suspend in the material,so they can act more eFFiciently under gas phase;on the other hand,under high temperatures,they react with oxygen in the enviroment to produce varieties of phosphoric acids whose extremelt strong eFFect of dehydration carbonizes the PU Foam to Form an insulation surFace layer to prevent the material From Further combustion,that is,act under solid phase.The cooperation of the two aspects is the major reason to give the PUF a Fairly good Flame-retarding eFFect

ANTISTATIC MODIFYING of ALKYLAMIDE ON THE SURFACE LAYER of PRINTINGPOTTERY-PLASTIC FLOOR BOARD

研究了烷基酰胺ECH—2对陶塑地砖PVC面层抗静电改性的可能性,证明其面层的电阻率、透明度等物性与抗静电剂的用量、配比有关,找到ECH—2最适用量为0.8~0.9份,在与溴磷酸酯协同改性时,又可提高PVC透明膜的阻燃性。用这种改性PVC薄膜作面层,与印花陶塑底层复合制成地砖的性能:表面电阻率3.7x10--8Ω、氧指数30等。达到既抗静电又阻燃的改性效果。The possibility of antistatic modiFying using alkylamide ECH-2 on the surFace layer of printing pottery - plastic PVC Floor board was studied (the results show that the properties of the surFace layer such as electrical resistivity and transparency had relations with the dosage and the mix ratio of the antistatic agent.The optium dosage was proved to be 0.8 - 0.9%.When mixed with bromophoshate to comodiFy.ECH -2 could improve the Flame - resistivity of the material.The compounded Floor board molded of modiFied PVC as surFace layer and printing pottery-plastic as bottom layer had special properties 1,0, 3.7X108,OI 30.The double eFFect of antistatic and Flame-retarding was thus reached