漳浦县石寨窑发掘简报

漳浦县石寨窑址是闽南一处专门仿烧龙泉青瓷的窑场,从元代开始,一直延续到明初。其产品种类较少,釉色比较丰富。窑业技术颇具特色,出现了介于分室龙窑和横室阶级窑之间的窑炉结构,对研究闽南地区横室阶级窑的起源与发展具有重要意义

Development of Novel Catalysts for Steam-reforming of Methanol or Ethanol to Generate Hydrogen

新型替代清洁能源的开发是大势所趋.氢能作为理想的清洁能源之一,已引起人们广泛重视.但氢能广泛地应用,尤其是用作电动车燃料电池的燃料,必须解决其储存和输运的技术问题.采用液体作为氢的载体,通过其重整即时产生燃料H2在商业上具有重要实用价值.在诸多可重整制H2的液体燃料中,甲醇、乙醇以其反应温度和压力低,H/C比高,无nOX、SOX排放,并可利用现行动力燃料输配系统等优点而占据优势.本文介绍甲醇、乙醇制氢技术的研发动态,重点报道本实验室在甲醇、乙醇经水蒸气重整制氢用高效高稳定性催化剂的研发进展.There is an ongoing trend to move toward exploitation of clean alternative energy sources.As one of the ideal energy sources,hydrogen has drawn great attention and been intensively studied.In order for hydrogen to be more widely used,especially serving as power-fuel for hydrogen-fuel-cell-driven vehicles,it is critical to solve issues associated with the storage and transportation of hydrogen.Liquid hydrogen-carriers,which can generate hydrogen in situ through conversion/reforming,are commercially important for practical applications.Among the many liquid-fuels that can generate hydrogen through reforming,methanol and ethanol have displayed some advantages in relatively lower reaction temperature and pressure,higher H/C ratio,no emission of NOxand SOxas by-products,and making use of the existing power-fuel transportation-distribution systems.In this article,we review recent developments in the hydrogen generation from methanol or ethanol,highlighting the progress in our lab on the development of catalysts for hydrogen generation from methanol or ethanol through steam reforming.国家重点基础研究发展计划(973计划)(2011CBA00508); 优秀国家重点实验室基金项目(20923004); 教育部创新团队项目(IRT1036

A Novel Sc-promoted CuO-ZnO-Al_2O_3 Catalyst for Dehydrogenation of Cyclohexanol to Cyclohexanone

用SC2O3作为促进剂,研发出一种高效新型SC2O3促进的Cu-znO-Al2O3基催化剂(记为CuIznJAlk-XSCX),考察其对环己醇脱氢制环己酮的催化性能.实验结果显示,在组成经优化的Cu6zn3Al0.7SC0.3催化剂上,常压,523 k,n(C6H11OH)∶n(n2)=1∶19和空速(gHSV)=43 200Ml/(H·g)的反应条件下,环己醇脱氢的转化率达53.7%,产物环己酮的时空产率为5 344Mg/(H·g),这2个值均为不含SC2O3的基质催化剂Cu6zn3Al1的相应值(42.4%,4 222Mg/(H·g))的1.27倍.催化剂的表征结果显示,SC2O3的修饰调变作用可能是由于SC2O3在znO晶格中高的溶解度.少量SC2O3在znO晶格中的溶解在znO表面产生阳离子空位形式的SCHOTTky缺陷,通过这些表面阳离子空位接纳Cu+离子使Cuy0-Cu+原子簇得以稳定化.这有助于抑制催化活性Cuy0纳米颗粒的团聚烧结,保持Cu组分的高分散度,于是显著地提高催化剂的活性和操作稳定性.该催化剂具有应用前景.A type of Sc2O3-promoted Cu-ZnO-Al2O3 catalyst was developed.The catalyst displays excellent performance for dehydrogenation of cyclohexanol to cyclohexanone.Over a Cu6Zn3Al0.7Sc0.3catalyst under the reaction condition of atmospheric pressure,523 K,n(C6H11OH)∶n(N2)=1∶19and GHSV=43 200 mL/(h·g),the conversion of cyclohexanol dehydrogenation reached53.7%,with the STY of cyclohexanone being 5 344mg/(h·g);both values were 1.27 times of those obtained with the Cu-ZnOAl2O3 catalyst not containing Sc2O3,42.4% and 4 222 mg/(h·g).Characterization of the catalyst revealed that the pronounced modification action of Sc3+may be due to the high solubility of Sc2O3 in the ZnO lattice.Solution of a small amount of Sc2O3 in the ZnO lattice resulted in the formation of Schottky defects in the form of cationic vacancies at the surface of ZnO,where the Cuy0-Cu+clusters can be better stabilized through the Cu+accommodated at the surface vacant cation-sites.This would be conducive to inhibiting the aggregation and sintering of the catalytically active Cuy0nano-particles and preserving high dispersion degree of Cu composition,so that the activity and operating stability of the catalyst were markedly improved.国家重点基础研究发展计划(973)项目(2011CBA00508); 优秀国家重点实验室基金项目(20923004); 教育部创新团队项目(IRT1036

Research Progress in Catalytic Synthesis and Applications of Carbon Nanotubes

通信作者: [email protected][中文文摘]概述近10年来国内外在碳纳米管催化合成及其应用研究领域的发展动态,着重介绍本研究组在多壁碳纳米管的催化合成、规模化生产及其用作某些加氢过程催化剂的新型载体或促进剂等领域的研究进展. [英文文摘]In this review article,recent progresses in catalytic synthesis and production-commercialization of multi-walled carbon nanotubes(MWCNTs) and in applied research of MWCNTs in catalysis are summarized and briefly reviewed,with an emphasis on description of the research progress in our laboratory here.国家重点基础研究发展计划(973)项目(2011CBA00508);福建省重大专项专题项目(2009HZ0002-1);福建省发改委高技术项目(闽发改高技2009-1030

The suitable distribution area of Tsuga longibracteata revealed by a climate and spatial constraint model under future climate change scenarios

长苞铁杉(Tsuga longibracteata)是中国特有的珍贵树种,不仅对研究裸子植物的系统发育、古生态和古气候具有重要作用,而且该树种具有造林、用材和药用等方面的较高价值。研究长苞铁杉在气候变化下的分布格局变化是制定其保护和可持续利用的重要基础。采用最大熵模型(MaxEnt),结合不同时期(当前、2050年和2070年)和不同二氧化碳排放情境下(RCP2.6和RCP8.5)的气候因子变量,探讨气候变化与物种地理分布格局的关系,预测长苞铁杉的潜在分布区变迁。本研究考虑了空间约束对物种分布的限制作用,构建了气候因子预测模型(C)和气候+空间约束因子预测模型(C+S)分别进行潜在分布区预测,比较其结果差异。结果显示,最干月降水量和温度年较差是影响长苞铁杉地理分布的主导气候因子,空间约束因子对长苞铁杉未来的地理分布有重要影响。随时间年限增加,长苞铁杉总潜在适生区面积降低,特别是中高等级的适生区面积有不同程度地减少,分布范围总体向北移动,这些变化趋势在RCP8.5情境下更加突出。这一结果表明未来气候变化会导致长苞铁杉种群分布范围收缩和生境适宜度下降,加剧其受胁程度。加入空间约束因子后,C+S模型的预测精度更高,结果更符合长苞铁杉的迁移、扩散特性。长苞铁杉未来的核心分布区仍位于现存的湘、桂、黔结合部,表明其具有原地避难的特性,应进一步加强对现有野生资源的保护。渝、川、鄂结合部的大巴山等地区是未来气候变化下长苞铁杉的理论分布区域,可作为长苞铁杉应对未来气候变化的引种地区,应提早进行人工引种、栽培等前期研究。研究结果可为气候变化背景下长苞铁杉的保护、物种迁地保存和可持续管理提供科学依据,也可为准确预测濒危、珍稀植物的地理分布范围提供方法参考

中国毒理学会会议论文集

目的:通过慢性应激模型和药理学手段研究NR2B亚基在抑郁症发病中的作用,选择性拮抗NR2B亚基的快速抗抑郁样作用及其神经生物学机制。方法:采用大鼠慢性应激抑郁模型,通过核团微注射方法研究内侧前额叶皮层内谷氨酸能NMDA受体不同亚基功能与抑郁样行为的关系。通过微透析技术及Western blot方法来检测内侧前额叶皮层内谷氨酸水平及相关分子的变化;通过多个抑郁模型及多种行为学测试(包括强迫游泳测试,&nbsp;</p