Preface Special Issue in Honor of Professor Zhaowu Tian on His 90Birthday

The Journal of Electrochemistry is proud to publish this Special Issue Honoring Professor Zhaowu Tian,on the occasion of his 90birthday,for his enormous contributions to and far-reaching impact in the field of electrochemistry

Distribution pattern of PAHs in Jiulong River Estuary by both measurement and simulation

于2011年12月(冬季)在厦门九龙江河口及西港采集9个表层海水水样,采用固相萃取—气质联用方法(SPE-GC-MS)分析其中16种多环芳烃含量。研究结果表明,总溶解态态∑PAH含量为157.9~858.0 ng/L。在河口区,随着盐度升高,PAHs含量逐渐降低。基于比值法分析,表明厦门九龙江及西港海域海水中的PAHs来源存在多种途径,呈现混合来源的态势。利用LEVEL III逸度模型研究菲,芘和苯并(a)芘在各介质间的分布以及水——气界面的交换通量。模拟结果与本文实测和文献中的实测值相吻合。在16℃时,三种多环芳烃的大气沉降通量分别为17.38,7.86和8.38μg/day/m2。其中菲在大气沉降中占主导地位,约三分之二。三种多环芳烃的大气沉降通量均随温度升高而减少。当温度高于32℃时,苯并(a)芘开始从水体释放。The concentration of 16 polycyclic aromatic hydrocarbons( PAHs) of nine water samples,collected in the Jiulong River Estuary in December,2011,were analyzed using the SPE-GC-MS method. The results showed that the concentration range of total dissolved PAHs( ΣPAHs) was from 157. 9 to 858. 0 ng / L. The horizontal distribution illustrated that the concentration of ΣPAHs decreased as salinity increased. Based on ratio analysis,PAHs have complicated sources. A Level III fugacity model was developed to simulate the multimedia fate of PAHs and to study the air-water exchange fluxes of three PAHs( phenanthrene,pyrene,benzo[a]pyrene) in the Jiulong River Estuary. The calculated concentration of PAHs was similar to that measured in this study or reported in earlier literature. At 16℃,the net atmosphere deposition fluxes of these PAHs were 17. 38,7. 86 and 8. 38 μg / day / m2. Phenanthrene was predominant in the atmospheric deposition. The net atmospheric deposition fluxes of these PAHs all decreased with tem-perature. When the temperature was above 32. 0℃,benzo[a]pyrene was released from the water into the air.国家自然科学基金(40776044);; 福建省自然科学基金(2012J05078);; 福建省杰出青年科学基金(2014J06014);; 中央高校基本科研专项(20720140507

1976 Vol. 24 Number 11

https://engagedscholarship.csuohio.edu/lawpublications_gavel1970s/1100/thumbnail.jp

混凝土中钢筋腐蚀早期过程宏观腐蚀电池与微观腐蚀电池相互作用

建立一种阵列电极技术,通过测量不同时空的微电极腐蚀电位、电偶电流及其动态变化,研究了在腐蚀介质作用下,混凝土中钢筋腐蚀发生、发展早期过程阳极区和阴极区分布特征,探讨了钢筋腐蚀过程宏观腐蚀电池与微观腐蚀电池的相互作用机制.结果表明,伴随着点腐蚀的发生、发展过程,在钢筋/混凝土界面宏观腐蚀电池的作用明显,宏观腐蚀电池电流分布与腐蚀电位有密切的对应关系.混凝土中钢筋腐蚀过程总是存在着宏观腐蚀电池和微观腐蚀电池,二者密切相关、相互作用,对钢筋局部腐蚀的发生、发展过程有重要影响.国家自然科学基金重点项目(批准号:50731004);国家科技支撑计划项目(批准号:2007BAB27B04)资

不断创新的电化学研究方法（厦门大学电化学研究工作简介之二）

不断创新的电化学研究方法（厦门大学电化学研究工作简介之二）林仲华，罗瑾，田中群，孙世刚，林昌健，毛秉伟，杨勇，林华水执笔（固体表面物理化学国家重点实验室，厦门大学化学系，厦门３６１００５）１历史的回顾与自然科学的其它分支学科一样，电化学科学的建立和纵..

Non-cyanide copper plating on steel substrate in alkaline citrate bath

以柠檬酸盐为配位剂,结合胺化合物为辅助配位剂,研究了钢铁基体上无氰镀铜工艺。探索了搅拌方式、温度、PH、铜离子质量浓度和添加剂质量浓度对镀层质量的影响以及该工艺抗fE2+、fE3+、zn2+、Sn4+等杂质的能力。试验结果表明,电流效率在90%左右,并随电流密度、温度和PH的提高而增大;镀液深镀能力达100%。通过极化曲线,解释了配位剂和添加剂的作用。The process of alkaline non-cyanide copper electroplating on steel substrate was studied using citrate as complexing agent and amine compound as assistant complexing agent.The effects of agitation mode, temperature, pH, copper ions concentration and additive content on deposit quality were discussed.The ability of bath to resist impurities such as Fe2+, Fe3+, Zn2+ and Sn4+ was revealed.The test results showed that the current efficiency is about 90% and is increased with increasing current density, temperature and pH.The throwing power of the bath is 100%.The action mechanisms of the complexing agents and additive were explained based on polarization curves.广东省教育部产学研结合专项资金项目(2006D90404019);福建省科技计划重点项目(2008H0086);国家自然科学基金项目(20873114

STUDY ON THE PROCESS of COPPER ELECTRODEPOSITION ON PLATINUM (111)

采用0.001MOl/lCuSO4＋0.5MOl/lH2SO4溶液体系，在PT单晶球电极作循环伏安曲线，得到Cu存在欠电位沉积和本体沉积两个阶段，利用电化学扫描隧道显微镜观察到在欠电位下Cu在PT（111）面上为单层平面生长，本体沉积为三维岛状生长，并随过电位升高，Cu的成核数目增加.用反射电子显微镜法也观察到高过电位时在PT（111）面上的岛状铜.证实了Cu在PT（111）面上的STrAnSkI—krASTAnOV生长机理C-V curves of copper electrodeposition on Pt(111) showed that there were two stages of underpotential and bulk deposition For copper electrodeposition process.Single layer growth at underpotential deposition and three dimensional nucleation growth at bulk deposition had been in situ observed by electrochemical scanning tunneling microscopy (ECSTM) at diFFerent potentials and times.The reFlection electron microscopy (REM) images also revealed three dimensional growth of Cu deposition at high overpotential.All of these results demonstrated Stranski-Krastanov growth mechanism of copper on Pt(111).国家自然科学基金!59471060;厦门大学固体表面物理化学国家重点实验室、中国科学院原子核分析研究室资

闽江口水、间隙水和沉积物中有机氯农药的含量

[摘要]：利用GC2ECD 和GC2MSD 对1999 年11 月闽江口水、间隙水和沉积物中的有机氯农药进行了研究. 结果显 示,闽江口水中有机氯农药的含量范围是01532～1182μg/ L ,间隙水中有机氯农药的含量为4154～1317μg/ L ,沉 积物(干重,以下讨论到的沉积物,无特别说明都是干重表示) :28179～52107μg/ kg ;与其他河口如珠江口、九龙江 口相比,闽江口的污染水平居中. 间隙水的污染物浓度普遍高于其上覆水的浓度,而沉积物中的浓度大于间隙水、 表层水,是由于有机污染物在水体中倾向于吸附在沉积物颗粒,并且通过再悬浮从底层向上迁移. 对水体中有机 氯农药各组分的含量及特征进行了分析,发现有机氯农药的主成分为:β2HCH ,DDE ,Heptachlor (七氯) ,Endosulfan Ⅱ(硫丹) ,Methoxychlor (甲氧滴涕) . DDE、β2HCH、Endosulfan Ⅱ分别占DDTs、HCHs 和硫丹的主要部分;有机氯 农药各组分间有正相关性,表明其河口有机氯农药陆源的土壤输入与相似的环境行为;对该河口的污染水平进行 了初步的评价,HCHs 符合国家海水水质一级标准,DDTs 则超过该标准.[Abstract]:The concentrations of 18 organochlorine pesticedes in water , pore water and surface sediment from Minjiang River Estuary were analyzed by GC2ECD , and confirmed by GC2MSD. The range of organochlorine pesticides was 01532～1182μg/ L at water , 4154～1317μg/ L at pore water , and 28179～52107μg/ kg at sediment . Compared with the results of other estuaries and gulfs (Pearl River Estuary , Jiulong River Estuary and so on) , it showed that the pollu2 tion of organochlorines in Minjiang was some moderate. The concentration difference in surface water , middle water , bottom water , pore water and sediment , due to the higher affinity of these hydrophobic compound for sedimentary phase than to water and a potential flux of pollutants from sediment to overlying water. The predominance ofβ2HCH ,DDE , Heptachlor , Endosulfan Ⅱand Methoxychlor in all water , pore water and sediment were clearly observed. On average , DDE、β2HCH、Endosulfan Ⅱoccupied the most part of total DDTs , HCHs and Endosulfans respectively , indicated the fate of these parent compounds or congeners. At the same time , it was found that thepositive relationship among the in2 dividual organochlorine components (HCHs , DDTs and Endosulfans) , which indicated that the similar of the source and behavior for organochlorine pesticides.海洋环境科学教育部重点实验室开放基金与教育 部重点基金联合资

Analysis on the characteristics of macrobenthis community in the North-west Daya Bay of South China Bay in spring

利用2008年春季在大亚湾西北部海域开展的12个测站的大型底栖动物调查资料,对该海域大型底栖动物的群落特征进行分析。结果表明该海域内大型底栖动物优势种由粗帝汶蛤(TIMOClEA SCAbrA)、波纹巴非蛤(PAPHIA undulATA)、上野蜾蠃蜚(COrOPHIuM uEnOI)、方背鳞虫(lEPIdOnOTuS SQuAMATuS)、刀明樱蛤(MOErEllA CulTEr)和角海蛹(OPHElIA ACuMInATA)等6种组成;可划分为4个群落,群落Ⅱ和群落Ⅰ为主体群落,群落Ⅲ和群落Ⅳ分布区较小,群落间差异较大。大型底栖动物数量上以个体较大的软体动物占优,但群落的组成则以多毛类和甲壳类为主,其组成情况基本上反映了群落的特征。群落Ⅰ以多毛类-甲壳类为表征,群落Ⅱ则以甲壳类-多毛类-软体动物为表征。栖息环境的差异,是造成群落间差异的主要原因;群落多样性水平呈群落Ⅲ>群落Ⅱ>群落Ⅰ>群落Ⅳ,沉积环境的污染状况和人为扰动是影响多样性水平的主要因素;群落整体的稳定性较好,未受到明显的扰动,但分布于航道区域和渔业生产作业区的群落Ⅳ和群落Ⅲ,在航道建设、疏浚和渔业生产的影响下,群落受到一定程度的扰动,稳定性较弱。Based on the data collected from 12 research stations in the North-west Daya Bay,South China Sea in spring 2008,the characteristics of macrobenthis community were examined.The results showed that the dominant macrobenthic species were Timoclea scabra,Paphia undulate,Corophium uenoi,Lepidonotus squamatus,Moerella culter and Ophelia acuminate.The macrobenthos community could be divided into four groups with notable differences.Group Ⅰ and Ⅱ were the dominant groups,while the distribution areas of Groups Ⅲ and Ⅳ were relatively small.Overall,molluscs was dominant in quantity in the macrobenthos community but the community was mainly composed of Annelida and Arthropoda,reflecting the characteristics of the community.The dominant macrobenthic species of group Ⅰ were Timoclea scabra,Nephtys oligobranchia,Theora lata,Sigambra hanaokai,Glycinde gurjanvae,Prionospio malmgreni,Timoclea scabra,Turritella bacillum,Corophium tridentium,Phyllodocidae und.,Nectoneanthes alatopalpis,Ericthonius pugnax,Pseudopythina sp.and Stylochus ijimai.Species belonging to this group distributed in the nearshore area of Aotou Harbor and Nanhai Petrochemicals Basement Group Ⅱ assemblage includes Paphia undulata,Timoclea scabra,Corophium uenoi,Prionospio malmgreni,Sigambra hanaokai,Ophelia acuminata,Mediomastus sp.,Nephtys oligobranchia,Moerella culter,Corophium lamellatum,Paraprionospio pinnata and Prionospio pulchra.These species distributed mainly around the Chunzhou Island where suspended long line culture of oyster was common.The discriminating species for Group Ⅰ were S.hanaokai,N.soligobranchia,P.malmgreni,N.alatopalpis and E.pugnax while group Ⅱ were C.uenoi,P.malmgreni,S.hanaokai,N.oligobranchia,T.scabra,M.sp.,Phyllodocidae und.,P.pinnata,O.acuminata,C.lamellatum,M.culter and Chaetozone sp.Group Ⅲ assemblage were mainly found in the west side of Mabianzhou,where it was a fishing ground for Arthropoda in Daya Bay.Group Ⅳ was distributed in area where main shipping routes passed through,in the east side of area of Group Ⅱ and in between the area of Group Ⅰ and Ⅲ.For each community group,while group Ⅱ Group Ⅰ was dominated by Annelida and Arthropoda while Group Ⅱ was dominated by arthropoda,annelida and mollusca;such difference is mainly because of the difference in habitat conditions.Diversity of macrobentho community was highest in Group Ⅲ,followed by Group Ⅱ,Group Ⅰ and then Group Ⅳ.Poor habitat condition caused by pollution,sedimentation and other human disturbances were the main reasons for the differences in diversity between groups.In general,macrobenthos community in the North-west Daya Bay of South China Sea was stable in spring.However,community structure of Groups Ⅳ and Ⅲ,which distributed in the main navigation route and fishing grounds,were less stable;suggesting the disturbances from maintenance of navigation channel and fishing activities might have reduced community stability.中央级公益性科研院所基本科研业务费专项基金(2007ZD08;2007TS08;2010YD10

Contents of Organochlorine Pesticides in Water , Pore Water and Sediment in Minjiang River Estuary of China

[摘要]：利用GC2ECD 和GC2MSD 对1999 年11 月闽江口水、间隙水和沉积物中的有机氯农药进行了研究. 结果显 示,闽江口水中有机氯农药的含量范围是01532～1182μg/ L ,间隙水中有机氯农药的含量为4154～1317μg/ L ,沉 积物(干重,以下讨论到的沉积物,无特别说明都是干重表示) :28179～52107μg/ kg ;与其他河口如珠江口、九龙江 口相比,闽江口的污染水平居中. 间隙水的污染物浓度普遍高于其上覆水的浓度,而沉积物中的浓度大于间隙水、 表层水,是由于有机污染物在水体中倾向于吸附在沉积物颗粒,并且通过再悬浮从底层向上迁移. 对水体中有机 氯农药各组分的含量及特征进行了分析,发现有机氯农药的主成分为:β2HCH ,DDE ,Heptachlor (七氯) ,Endosulfan Ⅱ(硫丹) ,Methoxychlor (甲氧滴涕) . DDE、β2HCH、Endosulfan Ⅱ分别占DDTs、HCHs 和硫丹的主要部分;有机氯 农药各组分间有正相关性,表明其河口有机氯农药陆源的土壤输入与相似的环境行为;对该河口的污染水平进行 了初步的评价,HCHs 符合国家海水水质一级标准,DDTs 则超过该标准.[Abstract]:The concentrations of 18 organochlorine pesticedes in water , pore water and surface sediment from Minjiang River Estuary were analyzed by GC2ECD , and confirmed by GC2MSD. The range of organochlorine pesticides was 01532～1182μg/ L at water , 4154～1317μg/ L at pore water , and 28179～52107μg/ kg at sediment . Compared with the results of other estuaries and gulfs (Pearl River Estuary , Jiulong River Estuary and so on) , it showed that the pollu2 tion of organochlorines in Minjiang was some moderate. The concentration difference in surface water , middle water , bottom water , pore water and sediment , due to the higher affinity of these hydrophobic compound for sedimentary phase than to water and a potential flux of pollutants from sediment to overlying water. The predominance ofβ2HCH ,DDE , Heptachlor , Endosulfan Ⅱand Methoxychlor in all water , pore water and sediment were clearly observed. On average , DDE、β2HCH、Endosulfan Ⅱoccupied the most part of total DDTs , HCHs and Endosulfans respectively , indicated the fate of these parent compounds or congeners. At the same time , it was found that thepositive relationship among the in2 dividual organochlorine components (HCHs , DDTs and Endosulfans) , which indicated that the similar of the source and behavior for organochlorine pesticides.海洋环境科学教育部重点实验室开放基金与教育 部重点基金联合资