13 research outputs found
Kinetics of Deposition of Oriented Superdisks
We use numerical Monte Carlo simulation to study kinetics of deposition of
oriented superdisks, bounded by the Lame curves of the form
, on regular planar substrate. It was recently shown that
the maximum packing density, as well as jamming density , exhibit
discontinuous derivative at , when the shape changes from convex to
concave form. By careful examination of the late-stage approach to the jamming
limit, we find that the leading term in temporal development is also
nonanalytic at , and offer heuristic excluded-area arguments for this
behavior
A Numerical Transfer-Matrix Study of Surface-Tension Anisotropy in Ising Models on Square and Cubic Lattices
We compute by numerical transfer-matrix methods the surface free energy
the surface stiffness coefficient and the single-step
free energy for Ising ferromagnets with
square-lattice and cubic-lattice geometries, into
which an interface is introduced by imposing antiperiodic or plus/minus
boundary conditions in one transverse direction. These quantities occur in
expansions of the angle-dependent surface tension, either for rough or for
smooth interfaces. The finite-size scaling behavior of the interfacial
correlation length provides the means of investigating and
The resulting transfer-matrix estimates are fully consistent with previous
series and Monte Carlo studies, although current computational technology does
not permit transfer-matrix studies of sufficiently large systems to show
quantitative improvement over the previous estimates.Comment: 40 pages, 17 figures available on request. RevTeX version 2.
Visible light absorption of surface-modified Al2O3 powders: A comparative DFT and experimental study
Surface modification of Al2O3 powders, prepared using reproducible sol-gel synthetic route with small colorless organic molecules, induces charge transfer complex formation and the appearance of absorption in the visible spectral region. Comprehensive microstructural characterization involving transmission electron microscopy, X-ray diffraction analysis, and nitrogen adsorption–desorption isotherms, revealed that γ-crystalline alumina powders consist of mesoporous particles in the size range from 0.1 to 0.3 μm, with specific surface area of 54.8 m2/g, and pore radius between 3 and 4 nm. The attachment of catecholate-type of ligands (catechol, caffeic acid, gallic acid, dopamine and 2,3-dihydroxy naphthalene), salicylate-type of ligands (salicylic acid and 5-amino salicylic acid), and ascorbic acid, to the surface such γ-Al2O3 particles leads to the formation of colored powders and activates their absorption in visible-light spectral region. To the best of our knowledge, similar transformation of an insulator (Al2O3), with the band gap energy of 8.7 eV, into a semiconductor-like hybrid material with tunable optical properties has not been reported in the literature before. The density functional theory (DFT) calculations with periodic boundary conditions were performed in order to estimate the energy gaps of various inorganic/organic hybrids. The calculated values compare well with the experimental data. The good agreement between the calculated and experimentally determined band gaps was found, thus demonstrating predictive ability of the theory when proper model is used