131,304 research outputs found
Enargite by XPS
X-ray photoelectron spectroscopy was used for characterizing the enargite surface. Freshly cleaved samples were analyzed at liquid nitrogen temperature. Enargite is a copper arsenic sulfide of formula Cu3AsS4; it is used as a minor ore of copper. Enargite is a potential source of arsenic and may create environmental problems through the release of toxic elements upon oxidatio
A study of Pt-/alpha-Fe2O3 nanocomposites by XPS
alpha-Fe2O3 matrices were deposited on Fluorine-doped Tin Oxide (FTO) substrates by Plasma Enhanced-
Chemical Vapor Deposition (PE-CVD) from Fe(hfa)_2TMEDA (hfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate; TMEDA =
N,N,N’,N’-tetramethylethylenediamine). The obtained nanosystems were subsequently functionalized by platinum nanoparticles (NPs) via Radio Frequency (RF)-sputtering, exposing samples either to a pre- or post-sputtering thermal treatment at 650°C for one hour in air. Interestingly, Pt oxidation state in the final composite systems strongly depended on the adopted processing conditions. In this work, a detailed X-ray Photoelectron Spectroscopy (XPS) analysis was carried out in order to investigate the material chemical composition, with particular regard to the relative Pt(0)/Pt(II)/Pt(IV) content. The obtained results evidenced that, when annealing is performed prior to sputtering, only PtO and PtO2 are revealed in the final Pt/alpha-Fe2O3 nanocomposite. In a different way, annealing after sputtering results in the co-presence of Pt(0), Pt(II) and Pt(IV) species, the former arising from the thermal decomposition of PtO2 to metallic platinum
XPS as a Probe of Gap Opening in Many Electron Systems
Core hole photoemission (XPS) provides a powerful indirect probe of the low
energy excitations of a many electron system. We argue that XPS can be used to
study the way in which a gap opens at a metal-superconductor or metal-
insulator transition. We consider the "universal" physics of how the loss of
low energy excitations modifies XPS spectra in the context of several simple
models, considering in particular the case of a two dimensional d-wave
superconductor.Comment: 8 pages, 9 eps figure
The MRO-accompanied modes of Re-implantation into SiO2-host matrix: XPS and DFT based scenarios
The following scenarios of Re-embedding into SiO2-host by pulsed
Re-implantation were derived and discussed after XPS-and-DFT electronic
structure qualification: (i) low Re-impurity concentration mode -> the
formation of combined substitutional and interstitial impurities with
Re2O7-like atomic and electronic structures in the vicinity of oxygen
vacancies; (ii) high Re-impurity concentration mode -> the fabrication of
interstitial Re-metal clusters with the accompanied formation of ReO2-like
atomic structures and (iii) an intermediate transient mode with Re-impurity
concentration increase, when the precursors of interstitial defect clusters are
appeared and growing in the host-matrix structure occur. An amplification
regime of Re-metal contribution majority to the final Valence Band structure
was found as one of the sequences of intermediate transient mode. It was shown
that most of the qualified and discussed modes were accompanied by the MRO
(middle range ordering) distortions in the initial oxygen subnetwork of the
a-SiO2 host-matrix because of the appeared mixed defect configurations.Comment: 19 pages, 7 figures, accepted to J. Alloys and Compound
The Origin of the Spatial Distribution of X-ray luminous AGN in Massive Galaxy Clusters
We study the spatial distribution of a 95% complete sample of 508 X-ray point
sources (XPS) detected in the 0.5-2.0 keV band in Chandra ACIS-I observations
of 51 massive galaxy clusters found in the MACS survey. Covering the redshift
range z=0.3-0.7, our cluster sample is statistically complete and comprises all
MACS clusters with X-ray luminosities in excess of 4.5 x 10^44 erg/s (0.1-2.4
keV, h_0=0.7, LCDM). Also studied are 20 control fields that do not contain
clusters. We find the XPS surface density, computed in the cluster restframe,
to exhibit a pronounced excess within 3.5 Mpc of the cluster centers. The
excess, believed to be caused by AGN in the cluster, is significant at the 8.0
sigma confidence level compared to the XPS density observed at the field edges.
No significant central excess is found in the control fields. To investigate
the physical origin of the AGN excess, we study the radial AGN density profile
for a subset of 24 virialized clusters. We find a pronounced central spike
(r<0.5 Mpc), followed by a depletion region at about 1.5 Mpc, and a broad
secondary excess centered at approximately the virial radius of the host
clusters (~2.5 Mpc). We present evidence that the central AGN excess reflects
increased nuclear activity triggered by close encounters between infalling
galaxies and the giant cD-type elliptical occupying the very cluster center. By
contrast, the secondary excess at the cluster-field interface is likely due to
black holes being fueled by galaxy mergers. In-depth spectroscopic and
photometric follow-up observations of the optical counterparts of the XPS in a
subset of our sample are being conducted to confirm this picture.Comment: ApJ Letters, accepted (4 pages, 3 figures, uses emulateapj
Disentangling Vacancy Oxidation on Metallicity-Sorted Carbon Nanotubes
Pristine single-walled carbon nanotubes (SWCNTs) are rather inert to O
and N, which for low doses chemisorb only on defect sites or vacancies of
the SWCNTs at the ppm level. However, very low doping has a major effect on the
electronic properties and conductivity of the SWCNTs. Already at low O
doses (80 L), the X-ray photoelectron spectroscopy (XPS) O 1s signal becomes
saturated, indicating nearly all the SWCNT's vacancies have been oxidized. As a
result, probing vacancy oxidation on SWCNTs via XPS yields spectra with rather
low signal-to-noise ratios, even for metallicity-sorted SWCNTs. We show that,
even under these conditions, the first principles density functional theory
calculated Kohn-Sham O 1s binding energies may be used to assign the XPS O 1s
spectra for oxidized vacancies on SWCNTs into its individual components. This
allows one to determine the specific functional groups or bonding environments
measured. We find the XPS O 1s signal is mostly due to three O-containing
functional groups on SWCNT vacancies: epoxy (CO), carbonyl
(CCO), and ketene (CCO), as ordered by abundance. Upon
oxidation of nearly all the SWCNT's vacancies, the central peak's intensity for
the metallic SWCNT sample is 60\% greater than for the semiconducting SWCNT
sample. This suggests a greater abundance of O-containing defect structures on
the metallic SWCNT sample. For both metallic and semiconducting SWCNTs, we find
O does not contribute to the measured XPS O~1s spectra
Electronic structure of Pr2MnNiO6 from x-ray photoemission, absorption and density functional theory
The electronic structure of double perovskite Pr2MnNiO6 is studied using core
x-ray photoelectron spectroscopy and x-ray absorption spectroscopy. The 2p
x-ray absorption spectra show that Mn and Ni are in 2+ and 4+ states
respectively. Using charge transfer multiplet analysis of Ni and Mn 2p XPS
spectra, we find charge transfer energies {\Delta} of 3.5 and 2.5 eV for Ni and
Mn respectively. The ground state of Ni2+ and Mn4+ reveal a higher d electron
count of 8.21 and 3.38 respectively as compared to the atomic values of 8.00
and 3.00 respectively thereby indicating the covalent nature of the system. The
O 1s edge absorption spectra reveal a band gap of 0.9 eV which is comparable to
the value obtained from first principle calculations for U-J >= 2 eV. The
density of states clearly reveal a strong p-d type charge transfer character of
the system, with band gap proportional to average charge transfer energy of
Ni2+ and Mn4+ ions.Comment: 18 pages, 9 figure
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