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On the implications of aerosol liquid water and phase separation for modeled organic aerosol mass
Water is an important component of PM2.5 Many traditional SOA species are highly soluble and thus can be considered extractable Water can influence the partitioning of compounds traditionally considered insoluble in models Organic aerosol takes up water according to RH Organic aerosol interacts with inorganic water Deviations in ideality (solubility) must be considered
Fine particle pH and the partitioning of nitric acid during winter in the northeastern United States
Particle pH is a critical but poorly constrained quantity that affects many aerosol processes and properties, including aerosol composition, concentrations, and toxicity. We assess PM1 pH as a function of geographical location and altitude, focusing on the northeastern U.S., based on aircraft measurements from the Wintertime Investigation of Transport, Emissions, and Reactivity campaign (1 February to 15 March 2015). Particle pH and water were predicted with the ISORROPIA-II thermodynamic model and validated by comparing predicted to observed partitioning of inorganic nitrate between the gas and particle phases. Good agreement was found for relative humidity (RH) above 40%; at lower RH observed particle nitrate was higher than predicted, possibly due to organic-inorganic phase separations or nitrate measurement uncertainties associated with low concentrations (nitrate \u3c 1 µg m−3). Including refractory ions in the pH calculations did not improve model predictions, suggesting they were externally mixed with PM1 sulfate, nitrate, and ammonium. Sample line volatilization artifacts were found to be minimal. Overall, particle pH for altitudes up to 5000 m ranged between −0.51 and 1.9 (10th and 90th percentiles) with a study mean of 0.77 ± 0.96, similar to those reported for the southeastern U.S. and eastern Mediterranean. This expansive aircraft data set is used to investigate causes in variability in pH and pH-dependent aerosol components, such as PM1 nitrate, over a wide range of temperatures (−21 to 19°C), RH (20 to 95%), inorganic gas, and particle concentrations and also provides further evidence that particles with low pH are ubiquitous
Proceedings of the 2011 New York Workshop on Computer, Earth and Space Science
The purpose of the New York Workshop on Computer, Earth and Space Sciences is
to bring together the New York area's finest Astronomers, Statisticians,
Computer Scientists, Space and Earth Scientists to explore potential synergies
between their respective fields. The 2011 edition (CESS2011) was a great
success, and we would like to thank all of the presenters and participants for
attending. This year was also special as it included authors from the upcoming
book titled "Advances in Machine Learning and Data Mining for Astronomy". Over
two days, the latest advanced techniques used to analyze the vast amounts of
information now available for the understanding of our universe and our planet
were presented. These proceedings attempt to provide a small window into what
the current state of research is in this vast interdisciplinary field and we'd
like to thank the speakers who spent the time to contribute to this volume.Comment: Author lists modified. 82 pages. Workshop Proceedings from CESS 2011
in New York City, Goddard Institute for Space Studie
Audio Source Separation Using Sparse Representations
This is the author's final version of the article, first published as A. Nesbit, M. G. Jafari, E. Vincent and M. D. Plumbley. Audio Source Separation Using Sparse Representations. In W. Wang (Ed), Machine Audition: Principles, Algorithms and Systems. Chapter 10, pp. 246-264. IGI Global, 2011. ISBN 978-1-61520-919-4. DOI: 10.4018/978-1-61520-919-4.ch010file: NesbitJafariVincentP11-audio.pdf:n\NesbitJafariVincentP11-audio.pdf:PDF owner: markp timestamp: 2011.02.04file: NesbitJafariVincentP11-audio.pdf:n\NesbitJafariVincentP11-audio.pdf:PDF owner: markp timestamp: 2011.02.04The authors address the problem of audio source separation, namely, the recovery of audio signals from recordings of mixtures of those signals. The sparse component analysis framework is a powerful method for achieving this. Sparse orthogonal transforms, in which only few transform coefficients differ significantly from zero, are developed; once the signal has been transformed, energy is apportioned from each transform coefficient to each estimated source, and, finally, the signal is reconstructed using the inverse transform. The overriding aim of this chapter is to demonstrate how this framework, as exemplified here by two different decomposition methods which adapt to the signal to represent it sparsely, can be used to solve different problems in different mixing scenarios. To address the instantaneous (neither delays nor echoes) and underdetermined (more sources than mixtures) mixing model, a lapped orthogonal transform is adapted to the signal by selecting a basis from a library of predetermined bases. This method is highly related to the windowing methods used in the MPEG audio coding framework. In considering the anechoic (delays but no echoes) and determined (equal number of sources and mixtures) mixing case, a greedy adaptive transform is used based on orthogonal basis functions that are learned from the observed data, instead of being selected from a predetermined library of bases. This is found to encode the signal characteristics, by introducing a feedback system between the bases and the observed data. Experiments on mixtures of speech and music signals demonstrate that these methods give good signal approximations and separation performance, and indicate promising directions for future research
Acoustic Space Learning for Sound Source Separation and Localization on Binaural Manifolds
In this paper we address the problems of modeling the acoustic space
generated by a full-spectrum sound source and of using the learned model for
the localization and separation of multiple sources that simultaneously emit
sparse-spectrum sounds. We lay theoretical and methodological grounds in order
to introduce the binaural manifold paradigm. We perform an in-depth study of
the latent low-dimensional structure of the high-dimensional interaural
spectral data, based on a corpus recorded with a human-like audiomotor robot
head. A non-linear dimensionality reduction technique is used to show that
these data lie on a two-dimensional (2D) smooth manifold parameterized by the
motor states of the listener, or equivalently, the sound source directions. We
propose a probabilistic piecewise affine mapping model (PPAM) specifically
designed to deal with high-dimensional data exhibiting an intrinsic piecewise
linear structure. We derive a closed-form expectation-maximization (EM)
procedure for estimating the model parameters, followed by Bayes inversion for
obtaining the full posterior density function of a sound source direction. We
extend this solution to deal with missing data and redundancy in real world
spectrograms, and hence for 2D localization of natural sound sources such as
speech. We further generalize the model to the challenging case of multiple
sound sources and we propose a variational EM framework. The associated
algorithm, referred to as variational EM for source separation and localization
(VESSL) yields a Bayesian estimation of the 2D locations and time-frequency
masks of all the sources. Comparisons of the proposed approach with several
existing methods reveal that the combination of acoustic-space learning with
Bayesian inference enables our method to outperform state-of-the-art methods.Comment: 19 pages, 9 figures, 3 table
Sparse component separation for accurate CMB map estimation
The Cosmological Microwave Background (CMB) is of premier importance for the
cosmologists to study the birth of our universe. Unfortunately, most CMB
experiments such as COBE, WMAP or Planck do not provide a direct measure of the
cosmological signal; CMB is mixed up with galactic foregrounds and point
sources. For the sake of scientific exploitation, measuring the CMB requires
extracting several different astrophysical components (CMB, Sunyaev-Zel'dovich
clusters, galactic dust) form multi-wavelength observations. Mathematically
speaking, the problem of disentangling the CMB map from the galactic
foregrounds amounts to a component or source separation problem. In the field
of CMB studies, a very large range of source separation methods have been
applied which all differ from each other in the way they model the data and the
criteria they rely on to separate components. Two main difficulties are i) the
instrument's beam varies across frequencies and ii) the emission laws of most
astrophysical components vary across pixels. This paper aims at introducing a
very accurate modeling of CMB data, based on sparsity, accounting for beams
variability across frequencies as well as spatial variations of the components'
spectral characteristics. Based on this new sparse modeling of the data, a
sparsity-based component separation method coined Local-Generalized
Morphological Component Analysis (L-GMCA) is described. Extensive numerical
experiments have been carried out with simulated Planck data. These experiments
show the high efficiency of the proposed component separation methods to
estimate a clean CMB map with a very low foreground contamination, which makes
L-GMCA of prime interest for CMB studies.Comment: submitted to A&
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Predicting Water Cycle Characteristics from Percolation Theory and Observational Data.
The fate of water and water-soluble toxic wastes in the subsurface is of high importance for many scientific and practical applications. Although solute transport is proportional to water flow rates, theoretical and experimental studies show that heavy-tailed (power-law) solute transport distribution can cause chemical transport retardation, prolonging clean-up time-scales greatly. However, no consensus exists as to the physical basis of such transport laws. In percolation theory, the scaling behavior of such transport rarely relates to specific medium characteristics, but strongly to the dimensionality of the connectivity of the flow paths (for example, two- or three-dimensional, as in fractured-porous media or heterogeneous sediments), as well as to the saturation characteristics (i.e., wetting, drying, and entrapped air). In accordance with the proposed relevance of percolation models of solute transport to environmental clean-up, these predictions also prove relevant to transport-limited chemical weathering and soil formation, where the heavy-tailed distributions slow chemical weathering over time. The predictions of percolation theory have been tested in laboratory and field experiments on reactive solute transport, chemical weathering, and soil formation and found accurate. Recently, this theoretical framework has also been applied to the water partitioning at the Earth's surface between evapotranspiration, ET, and run-off, Q, known as the water balance. A well-known phenomenological model by Budyko addressed the relationship between the ratio of the actual evapotranspiration (ET) and precipitation, ET/P, versus the aridity index, ET0/P, with P being the precipitation and ET0 being the potential evapotranspiration. Existing work was able to predict the global fractions of P represented by Q and ET through an optimization of plant productivity, in which downward water fluxes affect soil depth, and upward fluxes plant growth. In the present work, based likewise on the concepts of percolation theory, we extend Budyko's model, and address the partitioning of run-off Q into its surface and subsurface components, as well as the contribution of interception to ET. Using various published data sources on the magnitudes of interception and information regarding the partitioning of Q, we address the variability in ET resulting from these processes. The global success of this prediction demonstrated here provides additional support for the universal applicability of percolation theory for solute transport as well as guidance in predicting the component of subsurface run-off, important for predicting natural flow rates through contaminated aquifers
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