Terrane history of the Iapetus Ocean as preserved in the northern Appalachians and western Caledonides

The Iapetus Ocean was the first ancient ocean to be identified following the development of plate tectonics; its history has been fundamental in relating orogenesis and plate motion. The ocean probably formed following 3-way rifting between Laurentia, Baltica, and Amazonia – West Africa (a block that became incorporated in Gondwana). Closure of the ocean trapped numerous terranes during the development of the Appalachian–Caledonide Orogen. Subsequent deformation, including late Paleozoic strike slip, transpression, and transtension, and Mesozoic stretching during Pangea breakup, must be taken into account in models for orogen development. Traditional analyses of Iapetan terranes have focussed on Cambrian sedimentary successions, and on isotopic criteria, to classify terranes into larger domains: Ganderia, Avalonia and Megumia. Detrital zircon data show that these domains did not cross the Iapetus as single entities, while paleomagnetic data reveal significant vertical-axis terrane rotations. We here review and interpret 17 paleomagnetic poles and >350 published detrital zircon data sets from the northern Appalachians and western Caledonides, using consistent and rigorous criteria for the selection and presentation of data. We place these data on an integrated stratigraphic chart to show timing relations and to seek constraints on the provenance and travel of terranes in the Iapetus Ocean. We distinguish groups of terranes that likely travelled together as terrane assemblages. In the Taconian/Grampian Orogeny, Furongian to Katian continent–arc collision involved off-margin blocks along the hyperextended Laurentian margin. In New England, early Taconian collision by 475 Ma involved the Gondwana-derived Moretown assemblage. An assemblage of the Bronson and Popelogan arc terranes probably arrived at the main Laurentian margin 25-30 Myr later. Subduction polarity reversal then led to the progressive accretion of additional terrane assemblages (Salinian Orogeny). The Miramichi–Victoria assemblage arrived close to the Ordovician–Silurian boundary. The Miramichi terrane underwent partial subduction in the Québec re-entrant, whereas the Victoria terrane was juxtaposed with the Newfoundland promontory without major metamorphism. In mid-Silurian time, an assemblage including the Gander terrane of Newfoundland and related portions of Britain and Ireland was accreted to Laurentia, along with Baltica (Scandian Orogeny). The St. Croix – La Poile assemblage may have been accreted slightly later, but is distinguished by the development of a Silurian arc–backarc system (coastal igneous belt) above a northwest-dipping subduction zone. The Avalon–Brookville assemblage encountered this system in Přídolí to Middle Devonian time (Acadian Orogeny), leading to the collapse of the backarc basin and northwest-vergent thrust emplacement onto Laurentia during sinistral transpression in the Appalachian Orogen. Acadian deformation involved mainly sinistral strike slip in Britain and Ireland. Several of the terranes that were accreted to the Laurentian margin carried internal records of earlier deformation that took place near Amazonia – West Africa in Early Ordovician time and earlier (Monian/Penobscottian Orogeny). The Iapetus Ocean thus contained a complex array of terranes, small ocean basins, arcs, and previously emplaced ophiolites analogous to modern southeast Asia. It closed to form a complex array of sutures in an orogen within which no single Iapetus suture can be clearly identified

Insights into the Acadian orogeny, New England Appalachians: a provenance study of the Carrabassett and Kittery formations, Maine

The Central Maine Basin and Merrimack Trough are Silurian basins that formed adjacent to or were accreted to the Laurentian margin during the Acadian orogeny. The Early Devonian Carrabassett Formation of the Central Maine Basin and the Kittery Formation of the Merrimack Trough have major and trace element compositions indicative of a passive continental margin provenance, not unlike the older formations of the Central Maine Basin that are thought to have been derived from Laurentian sources. However, both the Carrabassett and Kittery formations have paleocurrent indicators of outboard sources. The Carrabassett Formation is one of the youngest formations of the Central Maine Basin and was deposited just prior to the Acadian orogeny. The Carrabassett and Kittery formations have major and trace element concentrations suggestive of passive margin turbidites derived from intermediate to felsic sources, inconsistent with a juvenile Avalonian provenance. The Carrabassett Formation contains detrital zircon grains that match the ages of peri-Gondwanan Ganderia. Unlike the dominance of positive bulk-rock εNd values that are characteristic of Avalonia, Ganderia has negative εNd values that are a better match for the negative εNd values of the Carrabassett and Kittery formations. However, Ganderia accreted to Laurentia during the Salinic orogeny, prior to the deposition of the Carrabassett Formation, and was basement to the sediments of the Central Maine Basin upon which the Carrabassett and other formations were deposited. Wedging of Ganderia by Avalonia during the initial stages of the Acadian orogeny may have uplifted Ganderia, forming highlands outboard of the Central Maine Basin that served as the source of the Carrabassett Formation sediments. RÉSUMÉ Le bassin central du Maine et la cuvette de Merrimack constituent des bassins siluriens s’étant formés le long de la marge laurentienne ou s’y étant accrétés au cours de l’orogenèse acadienne. La Formation du Dévonien précoce de Carrabassett, dans le bassin central du Maine, et la Formation de Kittery, de la cuvette de Merrimack, présentent des compositions en éléments majeurs et traces signalant une provenance d’une marge continentale passive, à l’instar des formations plus âgées du bassin central du Maine qu’on pense originaires de sources laurentiennes. Les formations de Carrabassett et de Kittery comportent toutefois des indicateurs de paléocourants de sources extérieures. La Formation de Carrabassett constitue l’une des formations les plus récentes du bassin central du Maine; elle s’est mise en place juste avant l’orogenèse acadienne. Les caractéristiques géochimiques et géochronologique des formations de Carrabassett et de Kittery pourraient par conséquent permettre l’identification du terrane de collision. Les formations de Carrabassett et de Kittery possèdent des concentrations d’éléments majeurs et traces évoquant les turbidites de marge passive en provenance de sources intermédiaires à felsiques, ce qui est contradictoire avec une origine avalonienne juvénile. La Formation de Carrabassett comporte des grains détritiques de zircon correspondant aux âges du Ganderia périgondwanien. Contrairement à la prédominance de concentrations εNd positives de roche en vrac caractéristiques d’Avalonia, Ganderia présentent des concentrations εNd négatives qui cadrent mieux avec les concentrations εNd négatives des formations de Carrabassett et de Kittery. Ganderia s’est toutefois accrété à Laurentia au cours de l’orogenèse salinique, avant le dépôt de la Formation de Carrabassett, et il a constitué le socle des sédiments du bassin central du Maine sur lesquels Carrabassett et d’autres formations se sont déposées. L’enfoncement d’Avalonia sous Ganderia au cours des stades initiaux de l’orogenèse acadienne pourrait avoir soulevé Ganderia, formant un massif à l’extérieur du bassin central du Maine qui a servi de source aux sédiments de la Formation de Carrabassett. [Traduit par la redaction

Provenance and paleogeography of post-Middle Ordovician, pre-Devonian sedimentary basins on the Gander composite terrane, eastern and east-central Maine: implications for Silurian tectonics in the northern Appalachians

Recent mapping in eastern and east-central Maine addresses long-standing regional correlation issues and permits reconstruction of post-Middle Ordovician, pre-Devonian paleogeography of sedimentary basins on the Ganderian composite terrane. Two major Late Ordovician-Silurian depocenters are recognized in eastern Maine and western New Brunswick separated by an emergent Miramichi terrane: the Fredericton trough to the southeast and a single basin comprising the Central Maine and Aroostook-Matapedia sequences to the northwest. This Central Maine/Aroostook-Matapedia (CMAM) basin received sediment from both the Miramichi highland to the east and highlands and islands to the west, including the pre-Late Ordovician Boundary Mountains, Munsungun-Pennington, and Weeksboro-Lunksoos terranes. Lithofacies in the Fredericton trough are truncated and telescoped by faulting along its flanks but suggest a similar basin that received sediment from highlands to the west (Miramichi) and east (St. Croix).Deposition ended in the Fredericton trough following burial and deformation in the Late Silurian, but continued in the CMAM basin until Early Devonian Acadian folding. A westward-migrating Acadian orogenic wedge provided a single eastern source of sediment for the composite CMAM basin after the Salinic/Early Acadian event, replacing the earlier, more local sources. The CMAM, Fredericton, and Connecticut Valley-Gaspé depocenters were active immediately following the Taconian orogeny and probably formed during extension related to post-Taconian plate adjustments. These basins thus predate Acadian foreland sedimentation.Structural analysis and seismic reflection profiles indicate a greater degree of post-depositional crustal shortening than previously interpreted. Late Acadian and post-Acadian strike-slip faulting on the Norumbega and Central Maine Boundary fault systems distorted basin geometries but did not disturb paleogeographic components drastically

Implications of Silurian granite genesis to the tectonic history of the Nashoba terrane, Eastern Massachusetts

Thesis advisor: J. Christopher HepburnThe Nashoba terrane is a highly metamorphosed and sheared Paleozoic tectonic block in eastern Massachusetts. The metamorphic rocks that compose the terrane are intruded by a series of diorites, tonalites, and granites. The Andover Granite is a complex multiphase granitic suite found in the northern part of the Nashoba terrane and is composed of both foliated and unfoliated granites as well as a granodiorite phase. The Sgr Group of granites is a series of unfoliated granites exposed along the Nashoba-Avalon terrane boundary. New crystallization ages for the foliated Andover Granite and the Sudbury Granite, southernmost body of the Sgr Group of granites, are presented. CA-TIMS U-Pb geochronology on zircons collected from these granites yielded 419.43 ± 0.52 Ma and 419.65 ± 0.51 Ma crystallization ages for the foliated Andover Granite and a 420.49 ± 0.52 Ma crystallization age for the Sudbury Granite. Geochemical and petrographic analysis of these granites indicate that the foliated Andover Granite is a high-K calc-alkaline, peralmuminous, S-type, biotite + muscovite granite and the Sudbury granite is high-K calc-alkaline, metaluminous to slightly peraluminous, I-type, biotite granite. These two granites are interpreted to have formed from the anatexis of either Nashoba terrane metasedimentary rocks and/or its underlying basement just prior to the Acadian orogeny. It is proposed that when Silurian diorite/tonalite magmas intruded into the Nashoba terrane, the influx of magmatic heat was sufficient to trigger crustal melting and promote granite genesis. This petrogenetic scenario fits well with regional tectonic models showing the Silurio-Devonian convergence of Avalonia towards Ganderia (which formed the eastern side of composite Laurentia at the time) in the northern Appalachians. Prior to the collision of Avalonia to composite Laurentia, mafic and intermediate composition arc magmas intruded the eastern Ganderian margin. The large amount of heat that accompanied these intrusions is believed to have contributed to Acadian metamorphism and influenced the formation of granitic plutons along the margin. It is therefore proposed that the plutonic record of the Nashoba terrane shows that by the Late Silurian - Early Devonian, Avalonia was still outboard of Laurentia in the vicinity of southern New England.Thesis (MS) — Boston College, 2014.Submitted to: Boston College. Graduate School of Arts and Sciences.Discipline: Earth and Environmental Sciences

Depositional constraints from detrital zircon geochronology of strata from multiple lithotectonic belts in south-central Maine, USA

The bedrock geology of south-central Maine is characterized by a series of fault-bounded lithotectonic terranes that were accreted onto the Laurentian margin during Silurian-Devonian orogenesis.  The multiple phases of deformation and metamorphism associated with this tectonism obscured most primary features in the protolith rocks, leading to uncertainties in their pre-accretionary history. Here we present the results of detrital zircon geochronology from five of these terranes and make interpretations on their depositional ages, sediment provenance, and tectonic setting of deposition.Detrital zircon from Silurian rocks of the Vassalboro Group in the eastern-most portion of the Central Maine basin indicate sediment input in an extensional setting from both Laurentian and Ordovician sources.  Results from Ordovician rocks of the Casco Bay Group of the Liberty-Orrington belt support earlier findings that these rocks have strong peri-Gondwanan affinities.  Detrital zircon from the Appleton Ridge Formation and Ghent phyllite of the Fredericton trough are consistent with a peri-Gondwanan sediment source with no evidence of Laurentian sediment input.  These findings are consistent with that of Dokken et al. (2018) for older Fredericton trough strata (i.e., Digdeguash Formation) east of the Fredericton fault in southern New Brunswick.  Two samples from the Jam Brook complex reveal extreme differences in depositional age (Ordovician vs. Mesoproterozoic) and tectonic affinity and support the hypothesis that this narrow belt represents a fault complex containing a wide variety of stratigraphic units.  Detrital zircon from Ordovician rocks of the Benner Hill Sequence indicate a peri-Gondwanan sediment source with no Laurentian input.Collectively, the pre-Silurian rocks of the Liberty-Orrington belt, Jam Brook complex, Benner Hill Sequence, and Late Ordovician-Early Silurian strata from the Appleton Ridge and Ghent phyllite in the Fredericton trough show peri-Gondwanan affinities with no evidence of Laurentian sediment input.  This suggests a barrier exisited between the Laurentian margin and these peri-Gondwanan terranes prior to about 435 Ma.  In contrast, Silurian strata from the eastern portion of the Central Maine basin do show evidence of a Laurentian sediment source, along with deposition in an extensional setting (lacking in all other samples), thus signaling a fundamental change in tectonic regime

Crustal Evolution of the New England Appalachians: The Rise and Fall of a Long-Lived Orogenic Plateau

The rise and demise of mountain belts, caused by growth, modification, or removal of the continental lithosphere are fundamental processes that influence almost all Earth systems. Understanding the nature, timing, and significance of active processes in the creation and evolution of modern mountain belts is challenged by a lack of middle crustal and lower crustal exposures. Analogues can be found in ancient orogens, whose deeply eroded roots offer a window into deeper processes, yet this record is complicated by overprinting events and complex deformational histories. Research presented herein constrains the tectonic history of multistage Appalachian Orogen, type locality of the Wilson cycle. Data-driven analysis of newly assembled geochronologic, geochemical, and geothermobarometric databases are synthesized with structural fabrics and geophysical imaging to constrain the timing and nature of crustal thickening and thinning events. Results identify a two-stage crustal thickening history in the dominant Acadian Orogeny and suggest the existence of a high elevation, low relief orogenic plateau. This plateau, the Acadian altiplano, formed in central and southern New England by ca. 380 Ma and exited for at least 50 m.y. until underwent orogen parallel collapse ca. 330-310 Ma. Collapse of the plateau likely formed the geophysically observed 12-15 km offset in Moho depth in western New England, and implies that the step has existed for ca. 300 m.y. These data constrain a four-dimensional record of crustal evolution over a period exceeding 100 m.y. Recognition of the Acadian altiplano may have important implications for the genesis of critical Li deposits, paleoclimate, and evolution of the Appalachian basin. Further, present a region that may provide an analogue for studying mid-crustal processes such as partial melting, ductile flow, and plutonism underneath modern plateaus

Age and Origin of the Merrimack Terrane, Southeastern New England: A Detrital Zircon U-Pb Geochronology Study

Thesis advisor: J C. HepburnThesis advisor: Yvette D. KuiperMetasedimentary rocks of the Merrimack terrane (MT) originated as a thick cover sequence on Ganderia consisting of sandstones, calcareous sandstones, pelitic rocks and turbidites. In order to investigate the age, provenance and stratigraphic order of these rocks and correlations with adjoining terranes, detrital zircon suites from 7 formations across the MT along a NNE-trending transect from east-central Massachusetts to SE New Hampshire were analyzed by U-Pb LA-ICP-MS methods on 90-140 grains per sample. The youngest detrital zircons in the western units, the Worcester, Oakdale and Paxton Formations, are ca. 438 Ma while those in the Kittery, Eliot and Berwick Formations in the northeast are ca. 426 Ma. The Tower Hill Formation previously interpreted to form the easternmost unit of the MT in MA, has a distinctly different zircon distribution with its youngest zircon population in the Cambrian. All samples except for the Tower Hill Formation have detrital zircon age distributions with significant peaks in the mid-to late Ordovician, similar abundances of early Paleozoic and late Neoproterozoic zircons, significant input from ~1.0 to ~1.8 Ga sources and limited Archean grains. The similarities in zircon provenance suggest that all units across the terrane, except for the Tower Hill Formation, belong to a single sequence of rocks, with similar sources and with the units in the NE possibly being somewhat younger than those in east-central Massachusetts. The continuous zircon age distributions observed throughout the Mesoproterozoic and late Paleoproterozoic are consistent with an Amazonian source. All samples, except the Tower Hill Formation, show sedimentary input from both Ganderian and Laurentian sources and suggest that Laurentian input increases as the maximum depositional age decreases.Thesis (MS) — Boston College, 2013.Submitted to: Boston College. Graduate School of Arts and Sciences.Discipline: Geology and Geophysics

Early Paleozoic Orogenesis in the Maine-Quebec Appalachians

Accretionary orogens, such as the Appalachian orogen, form by episodic docking of oceanic and continental fragments. Two factors that exert significant control on the development of an accretionary orogen are: (1) the nature and source of the accreting fragments, and (2) the thermal and deformational structure of the crust. This study addresses aspects of both of these controls. In the Northern Appalachians, a long-lived but untested hypothesis suggested that Early Paleozoic accretion in western Maine, which marked the initiation of Appalachian development, involved the docking of an island arc. My goal was to test this hypothesis for the Maine-Qukbec segment of the orogen, where the Boundary Mountains terrane had been identified as a possible collider. Combining the techniques of mapping, structural analysis, petrography, U-Pb zircon and monazite geochronology, geochemistry, and geochemical modeling, I present the following interpretations related to the geologic history of the region. (1) the Chain Lakes massif, which cores the Boundary Mountains, was an Ordovician arc-marginal basin receiving sediments eroded from a Laurentian source. (2) Anatexis of the Chain Lakes massif disrupted the original sedimentaryvolcanic sequence. (3) The Boil Mountain Complex and Jim Pond Formation, which lie along the southern margin of the Chain Lakes massif, do not represent an ophiolite, as previously thought. (4) The Boundary Mountains represent a Laurentian-derived microcontinent that served as the nucleus for part of a regional arc system that collided with Laurentia in the Ordovician. The thermal and deformational processes described herein relate, respectively, to anatexis and pluton emplacement. Review and numerical modeling of the causes of lowpressure anatexis, which affected the Chain Lakes massif, indicate that appropriate pressure-temperature conditions are possible in regions of crustal-scale detachment faulting, percolative magma flow, or where thin lithosphere is accompanied by plutonic activity. Analytical kinematic modeling of the consequences of dike-fed pluton emplacement suggests that if published physical properties of granitic magmas are correct, host rocks surrounding an in-situ expanding pluton must deform at rates several orders of magnitude faster than typical tectonic strain rates. Such strain rates almost certainly must be accommodated by processes other than dislocation creep

New Constraints on the Age of Deposition and Provenance of the Metasedimentary Rocks in the Nashoba Terrane, SE New England

Thesis advisor: J. Christopher HepburnThe Nashoba terrane of SE New England is one of three peri-Gondwanan tectonic blocks caught between Laurentia and Gondwana during the closure of the Iapetus Ocean in the early to mid- Paleozoic. U-Pb analyses (LA-ICP-MS) were carried out on zircon suites from the meta-sedimentary rocks of the Nashoba terrane. The youngest detrital zircons in the meta-sedimentary rocks of the Nashoba terrane are Ordovician in age. There is no significant difference in age between meta-sedimentary units of the Nashoba terrane across the Assabet River Fault Zone, a major fault zone that bisects the NT in a SE and a NW par. Zircon in meta-sedimentary rocks in the Marlboro Fm., the oldest unit of the Nashoba terrane, is rare, which may reflect the basaltic nature of the source material, and is commonly metamict. The Marlboro Fm. contained the oldest detrital grain of all the analyzed samples, with a core of ~3.3 Ga and rim of ~2.6 Ga indicating that it was sourced from Archaen crustal material. Detrital zircons from the Nashoba terrane show a complete age record between the Paleoproterozoic and Paleozoic that strongly supports a provenance from the Oaxiqua margin of Amazonia. The detrital zircon suite of the Nashoba terrane is distinct from both Avalonia and the Merrimack belt; however, they resemble zircon suites from Ganderia. This study proposes that the Nashoba terrane of Massachusetts correlates with the passive trailing edge of Ganderia. Finally, metamorphic zircon analyses of the terrane show that the Nashoba terrane experienced a peak in hydrothermal fluid infiltration during the Neoacadian orogeny.Thesis (MS) — Boston College, 2011.Submitted to: Boston College. Graduate School of Arts and Sciences.Discipline: Earth and Environmental Sciences

Bridging the Gap Between the Foreland and Hinterland II: Geochronology and Tectonic Setting of Ordovician Magmatism and Basin Formation on the Laurentian Margin of New England and Newfoundland

Ordovician strata of the Mohawk Valley and Taconic allochthon of New York and the Humber margin of Newfoundland record multiple magmatic and basin-forming episodes associated with the Taconic orogeny. Here we present new U-Pb zircon geochronology and whole rock geochemistry and neodymium isotopes from Early Paleozoic volcanic ashes and siliciclastic units on the northern Appalachian margin of Laurentia. Volcanic ashes in the Table Point Formation of Newfoundland and the Indian River Formation of the Taconic allochthon in New York yield dates between 466.16 ± 0.12 and 464.20 ± 0.13 Ma. Red, bioturbated slate of the Indian River Formation record a shift to more juvenile neodymium isotope values suggesting sedimentary contributions from the Taconic arc-system by 466 Ma. Eight ashes within the Trenton Group in the Mohawk Valley were dated between 452.63 ± 0.06 and 450.68 ± 0.12 Ma. These ashes contain zircon with Late Ordovician magmatic rims and 1.4 to 1.0 Ga xenocrystic cores that were inherited from Grenville basement, suggesting that the parent magmas erupted through the Laurentian margin. The new geochronological and geochemical data are integrated with a subsidence model and data from the hinterland to refine the tectonic model of the Taconic orogeny. Closure of the Iapetus Ocean by 475 Ma via collision of the peri-Gondwanan Moretown terrane with hyperextended distal fragments of the Laurentian margin is not clearly manifested on the autochthon or the Taconic allochthon other than an increase in sediment accumulation. Pro-foreland basins formed during the Middle Ordovician when these terranes were obducted onto the Laurentian margin. 466 to 464 Ma ashes on the Laurentian margin coincide with a late pulse of magmatism in both the Notre Dame arc in Newfoundland and the Shelburne Falls arc of New England that is potentially related to break-off of an east-dipping slab. Following slab reversal, by 455 Ma, the Bronson Hill arc was established on the new composite Laurentian margin. Thus, we conclude that Late Ordovician strata in the Mohawk Valley and Taconic allochthon of New York and on the Humber margin of Newfoundland were deposited in retro-foreland basins