PPH dendrimers grafted on silica nanoparticles: surface chemistry, characterization, silver colloids hosting and antibacterial activity

Polyphosphorhydrazone (PPH) dendrimers have been grafted on silica nanoparticles, and the surface functions of the dendrimers have been derivatized to phosphonates with lateral poly(ethyleneglycol) (PEG) chains. All materials have been thoroughly characterized by MAS NMR, FT-IR, electron microscopy, TGA and elemental analysis. These materials successfully hosted silver and silver oxide nanoparticles. The resulting composites exhibit antibacterial activity

Engineering Crowdsourced Stream Processing Systems

A crowdsourced stream processing system (CSP) is a system that incorporates crowdsourced tasks in the processing of a data stream. This can be seen as enabling crowdsourcing work to be applied on a sample of large-scale data at high speed, or equivalently, enabling stream processing to employ human intelligence. It also leads to a substantial expansion of the capabilities of data processing systems. Engineering a CSP system requires the combination of human and machine computation elements. From a general systems theory perspective, this means taking into account inherited as well as emerging properties from both these elements. In this paper, we position CSP systems within a broader taxonomy, outline a series of design principles and evaluation metrics, present an extensible framework for their design, and describe several design patterns. We showcase the capabilities of CSP systems by performing a case study that applies our proposed framework to the design and analysis of a real system (AIDR) that classifies social media messages during time-critical crisis events. Results show that compared to a pure stream processing system, AIDR can achieve a higher data classification accuracy, while compared to a pure crowdsourcing solution, the system makes better use of human workers by requiring much less manual work effort

Katakan tidak pada rasuah

Isu atau masalah rasuah menjadi topik utama sama ada di peringkat antarabangsa mahupun di peringkat dalam negara. Pertubuhan Bangsa- bangsa Bersatu menegaskan komitmen komuniti antarabangsa bertegas untuk mencegah dan mengawal rasuah melalui buku bertajuk United Nations Convention against Corruption. Hal yang sama berlaku di Malaysia. Melalui pernyataan visi oleh mantan Perdana Menteri Malaysia, Tun Dr. Mahathir bin Mohamed memberikan indikasi bahawa kerajaan Malaysia komited untuk mencapai aspirasi agar Malaysia dikenali kerana integriti dan bukannya rasuah. Justeru, tujuan penulisan bab ini adalah untuk membincangkan rasuah dari beberapa sudut termasuk perbincangan dari sudut agama Islam, faktor-faktor berlakunya gejala rasuah, dan usaha-usaha yang dijalankan di Malaysia untuk membanteras gejala rasuah. Perkara ini penting bagi mengenalpasti penjawat awam menanamkan keyakinan dalam melaksanakan tanggungjawab dengan menghindari diri daripada rasuah agar mereka sentiasa peka mengutamakan kepentingan awam

Towards adaptive multi-robot systems: self-organization and self-adaptation

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.The development of complex systems ensembles that operate in uncertain environments is a major challenge. The reason for this is that system designers are not able to fully specify the system during specification and development and before it is being deployed. Natural swarm systems enjoy similar characteristics, yet, being self-adaptive and being able to self-organize, these systems show beneficial emergent behaviour. Similar concepts can be extremely helpful for artificial systems, especially when it comes to multi-robot scenarios, which require such solution in order to be applicable to highly uncertain real world application. In this article, we present a comprehensive overview over state-of-the-art solutions in emergent systems, self-organization, self-adaptation, and robotics. We discuss these approaches in the light of a framework for multi-robot systems and identify similarities, differences missing links and open gaps that have to be addressed in order to make this framework possible

Kinetic Intersections as a Source of Information on Rate Coefficients

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3D printing of optical materials: an investigation of the microscopic properties

3D printing technologies are currently enabling the fabrication of objects with complex architectures and tailored properties. In such framework, the production of 3D optical structures, which are typically based on optical transparent matrices, optionally doped with active molecular compounds and nanoparticles, is still limited by the poor uniformity of the printed structures. Both bulk inhomogeneities and surface roughness of the printed structures can negatively affect the propagation of light in 3D printed optical components. Here we investigate photopolymerization-based printing processes by laser confocal microscopy. The experimental method we developed allows the printing process to be investigated in-situ, with microscale spatial resolution, and in real-time. The modelling of the photo-polymerization kinetics allows the different polymerization regimes to be investigated and the influence of process variables to be rationalized. In addition, the origin of the factors limiting light propagation in printed materials are rationalized, with the aim of envisaging effective experimental strategies to improve optical properties of printed materials.Comment: 8 pages, 3 figure