Reliability Analysis of Hafnium Oxide Dielectric Based Nanoelectronics

With the physical dimensions ever scaling down, the increasing level of sophistication in nano-electronics requires a comprehensive and multidisciplinary reliability investigation. A kind of nano-devices, HfO2-based high-k dielectric films, are studied in the statistical aspect of reliability as well as electrical and physical aspects of reliability characterization, including charge trapping and degradation mechanisms, breakdown modes and bathtub failure rate estimation. This research characterizes charge trapping and investigates degradation mechanisms in high-k dielectrics. Positive charges trapped in both bulk and interface contribute to the interface state generation and flat band voltage shift when electrons are injected from the gate under a negative gate bias condition.A negligible number of defects are generated until the stress voltage increases to a certain level. As results of hot electrons and positive charges trapped in the interface region, the difference in the breakdown sequence is attributed to the physical thickness of the bulk high-k layer and the structure of the interface layer. Time-to-breakdown data collected in the accelerated life tests are modeled with a bathtub failure rate curve by a 3-step Bayesian approach. Rather than individually considering each stress level in accelerating life tests (ALT), this approach derives the change point and the priors for Bayesian analysis from the time-to-failure data under neighborhood stresses, based on the relationship between the lifetime and stress voltage. This method can provide a fast and reliable estimation of failure rate for burn-in optimization when only a small sample of data is available

Reliability modeling of ultra-thin gate oxide and high-k dielectrics for nano-scale CMOS devices

Ph.DDOCTOR OF PHILOSOPH

Doped And Chemically Transformed Transition Metal Dichalcogenides (tmdcs) For Two-Dimensional (2d) Electronics

Transition metal dichalcogenides (TMDCs) as the semiconductor counterparts of gra-phene have emerged as promising channel materials for flexible electronic and optoelectronic devices. The 2D layer structure of TMDCs enables the ultimate scaling of TMDC-based devices down to atomic thickness. Furthermore, the absence of dangling bonds in these materials helps to form high quality heterostructures with ultra-clean interfaces. The main objective of this work is to develop novel approaches to fabricating TMDC-based 2D electronic devices such as diodes and transistors. In the first part, we have fabricated 2D p-n junction diodes through van der Waals assembly of heavily p-doped MoS2 (WSe2) and lightly n-doped MoS2 to form vertical homo-(hetero-) junctions, which allows to continuously tune the electron concentration on the n-side for a wide range. In sharp contrast to conventional p-n junction diodes, we have observed nearly exponential dependence of the reverse-current on gate-voltage in our 2D p-n junction devices, which can be attributed to band-to-band tunneling through a gate-tunable tunneling barrier. In the second part, we developed a new strategy to engineer high-κ dielectrics by con-verting atomically thin metallic 2D TMDCs into high-κ dielectrics because it remains a signifi-cant challenge to deposit uniform high-κ dielectric thin films on TMDCs with ALD due to the lack of dangling bonds on the surfaces of TMDCs. In our study, we converted mechanically ex-foliated atomically thin layers of a 2D metal, TaS2 (HfSe2) into a high-κ dielectric, Ta2O5 (HfO2) by thermal oxidation. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), and atomic force microscopy (AFM) were used to understand the phase conversion process. Capacitance-voltage (C-V) measure-ments were carried out to determine the dielectric constant of thermally oxidized dielec-trics. We fabricated MoS2 field-effect transistors (FETs) with thermally oxidized ultra-thin and ultra-smooth Ta2O5 as top-gate and bottom-gate high-κ dielectric layers. We observed promis-ing device performance, including a nearly ideal subthreshold swing of ~ 61 mV/dec at room temperature, negligible hysteresis, drain-current saturation in the output characteristics, a high on/off ratio ~ 106, and a room temperature field-effect mobility exceeding 60 cm2/Vs. To fur-ther reduce the leak current and improve the device performance, we have also investigated the chemical transformation of HfSe2 to HfO2 high-κ dielectric, which has significantly larger band gap than Ta2O5

Defect Induced Aging and Breakdown in High-k Dielectrics

abstract: High-k dielectrics have been employed in the metal-oxide semiconductor field effect transistors (MOSFETs) since 45 nm technology node. In this MOSFET industry, Moore’s law projects the feature size of MOSFET scales half within every 18 months. Such scaling down theory has not only led to the physical limit of manufacturing but also raised the reliability issues in MOSFETs. After the incorporation of HfO2 based high-k dielectrics, the stacked oxides based gate insulator is facing rather challenging reliability issues due to the vulnerable HfO2 layer, ultra-thin interfacial SiO2 layer, and even messy interface between SiO2 and HfO2. Bias temperature instabilities (BTI), hot channel electrons injections (HCI), stress-induced leakage current (SILC), and time dependent dielectric breakdown (TDDB) are the four most prominent reliability challenges impacting the lifetime of the chips under use. In order to fully understand the origins that could potentially challenge the reliability of the MOSFETs the defects induced aging and breakdown of the high-k dielectrics have been profoundly investigated here. BTI aging has been investigated to be related to charging effects from the bulk oxide traps and generations of Si-H bonds related interface traps. CVS and RVS induced dielectric breakdown studies have been performed and investigated. The breakdown process is regarded to be related to oxygen vacancies generations triggered by hot hole injections from anode. Post breakdown conduction study in the RRAM devices have shown irreversible characteristics of the dielectrics, although the resistance could be switched into high resistance state.Dissertation/ThesisDoctoral Dissertation Electrical Engineering 201

TiN/HfO2/SiO2/Si gate stacks reliability : Contribution of HfO2 and interfacial SiO2 layer

Hafnium Oxide based gate stacks are considered to be the potential candidates to replace SiO2 in complementary metal-oxide-semiconductor (CMOS), as they reduce the gate leakage by over 100 times while keeping the device performance intact. Even though considerable performance improvement has been achieved, reliability of high-κ devices for the next generation of transistors (45nm and beyond) which has an interfacial layer (IL: typically SiO2) between high-κ and the substrate, needs to be investigated. To understand the breakdown mechanism of high-κ/SiO2 gate stack completely, it is important to study this multi-layer structure extensively. For example, (i) the role of SiO2 interfacial layers and bulk high-κ gate dielectrics without any interfacial layer can be investigated separately while maintaining same growth conditions; (ii) the evolution of breakdown process can be studied through stress induced leakage current (SILC); (iii) relationship of various degradation mechanisms such as negative bias temperature instability (NBTI) with that of the dielectric breakdown; and (iv) a fast evaluation process to estimate statistical breakdown distribution. In this dissertation a comparative study was conducted to investigate individual breakdown characteristics of high-κ/IL (ISSG SiO2)/metal gate stacks, in-situ steam generated (ISSG)-SiO2 MOS structures and HfO2-only metal-insulator-metal (MIM) capacitors. Experimental results indicate that after constant voltage stress (CVS) identical degradation for progressive breakdown and SILC were observed in high-κ/IL and SiO2-only MOS devices, but HfO2-only MIM capacitors showed insignificant SILC and progressive breakdown until it went into hard breakdown. Based on the observed SILC behavior and charge-to-breakdown (QBD), it was inferred that interfacial layer initiates progressive breakdown of metal gate/high-κ gate stacks at room temperature. From normalized SILC (ΔJg/Jg0) at accelerated temperature and activation energy of the timeto- breakdown (TBD), it was observed that IL initiates the gate stack breakdown at higher temperatures as well. A quantitative agreement was observed for key parameters of NBTI and time dependent dielectric breakdown (TDDB) such as the activation energies of threshold voltage change and SILC. The quality and thickness variation of the IL causes similar degradation on both NBTI and TDDB indicating that mechanism of these two reliability issues are related due to creation of identical defect types in the IL. CVS was used to investigate the statistical distribution of TBD, defined as soft or first breakdown where small sample size was considered. As TBD followed Weibull distribution, large sample size was not required. Since the failure process in static random access memory (SRAM) is typically predicted by the realistic TDDB model based on gate leakage current (IFAIL) rather than the conventional first breakdown criterion, the relevant failure distributions at IFAIL are non-Weibull including the progressive breakdown (PBD) phase for high-κ/metal gate dielectrics. A new methodology using hybrid two-stage stresses has been developed to study progressive breakdown phase further for high-κ and SiO2. It is demonstrated that VRS can be used effectively for quantitative reliability studies of progressive breakdown phase and final breakdown of high-κ and other dielectric materials; thus it can replace the time-consuming CVS measurements as an efficient methodology and reduce the resources manufacturing cost

A simple figure of merit to identify the first layer to degrade and fail in dual layer SiOx/HfO2 gate dielectric stacks

Understanding the degradation dynamics and the breakdown sequence of a bilayer high-k (HK) gate dielectric stack is crucial for the improvement of device reliability. We present a new Figure of Merit (FoM), the IL/HK Degradation Index, that depends on fundamental materials properties (the dielectric breakdown strength and the dielectric constant) and can be used to easily and quickly identify the first layer to degrade and fail in a bilayer SiO2/HK dielectric stack. Its dependence on IL and HK material parameters is investigated and its validity is demonstrated by means of accurate physics-based simulations of the degradation process. The proposed FoM can be easily used to understand the degradation dynamics of the gate dielectric stack, providing critical insights for device reliability improvement

Secure HfO2 based charge trap EEPROM with lifetime and data retention time modeling

Trusted computing is currently the most promising security strategy for cyber physical systems. Trusted computing platform relies on securely stored encryption keys in the on-board memory. However, research and actual cases have shown the vulnerability of the on-board memory to physical cryptographic attacks. This work proposed an embedded secure EEPROM architecture employing charge trap transistor to improve the security of storage means in the trusted computing platform. The charge trap transistor is CMOS compatible with high dielectric constant material as gate oxide which can trap carriers. The process compatibility allows the secure information containing memory to be embedded with the CPU. This eliminates the eavesdropping and optical observation. This effort presents the secure EEPROM cell, its high voltage programming control structure and an interface architecture for command and data communication between the EEPROM and CPU. The interface architecture is an ASIC based design that exclusively for the secure EEPROM. The on-board programming capability enables adjustment of programming voltages and accommodates EEPROM threshold variation due to PVT to optimize lifetime. In addition to the functional circuitry, this work presents the first model of lifetime and data retention time tradeoff for this new type of EEPROM. This model builds the bridge between desired data retention time and lifetime while producing the corresponding programming time and voltage

Characterization of high-k layers as the gate dielectric for MOSFETs

As the gate oxide thickness of the Metal-Oxide-Semiconductor Field Effect Transistor (MOSFET) is continuously scaled down with lateral device dimensions, the gate leakage current during operation increases exponentially. This increase in leakage current raises concerns regarding power consumption and device reliability. Alternative dielectrics with higher dielectric constant (high-k) than that of Si02 have been searched. High-k layers allow the use of physically thicker gate dielectrics, so that the gate leakage current is controlled. The intensive world-wide research has identified the Hf-dielectric as the lead candidate for future CMOS technologies. However, the commercial application of Hf-dielectrics as the gate oxide has been held back by a number of issues, including process integration, low carrier mobility, and high instability. This project focuses on characterizing the defect responsible for the instability of Hf-dielectrics. The thesis consists of six chapters. After an introduction in Chapter 1, the characterization techniques used are described in Chapter 2. Two main contributions are: setting up the pulse transfer characteristic technique and developing a newly improved charge pumping technique called Variable T charged is charge Pumping (VT2CP). The research results are presented in Chapters 3,4 and 5. Chapter 3 characterizes a s-grown electron traps in HfO2/SiO2s tacks. The issues addressed include the impact of measurement technique on electron trapping, contribution of different current components to trapping, trap location, and the capture cross section and trapping kinetics. It is shown that the use of pulse transfer characteristic technique is essential for measuring electron trapping, since the traditional quasi-dc transfer characteristic is too IV ABSTRACT slow and the loss of charges is significant. The trap assisted tunneling and the thermally enhanced conduction contributes little to trapping. The trapping does not pile up at the interfaces and the region near to one or both ends of Hf02 has little trapping, when compared with the trapping in the bulk. To evaluate the electron fluency through the gate stack, efforts are made to estimate the trapping-induced transient gate current through simulation. This allows the determination of two capture cross sections: one in the order of 10-14cma2n d the other in the order of 10-16cm2. Chapter 4 concentrates on the characterization of generated electron traps and the time dependent dielectric breakdown (TDDB). Amplitude charge pumping and frequency sweep charge pumping are used to investigate the impact of gate electrodes and channel length on charging and discharging of the bulk defects. As channel length increases,it is found that bulk trapping increases and TDDB time shortens. Efforts are made to show that there is a quantitative correlation between the trapping and TDDB data. The newly improved VTZCP is used to separate trapping in the interfacial Si02 from that in Hf02. The results show that new traps are generated in both layers and the generation follows a power law with similar power factors. Investigation is also carried out to assess the dependence of trap generation on process and deposition conditions. Finally, it is found that Hf-dielectric with metal gate always suffers hard-breakdown. In Chapter 5, attention is turned to positive charging in Hf-dielectric. It is shown that the use of metal gate enhances the positive charging, when stressed under a positive gate bias. This is explained by assuming that there is a large number of hydrogenous species within the metal gate or at its interface with gate dielectric. Two types of threshold voltage instabilities have been identified for pMOSFETs. The first one results in a loop in the transfer characteristics when a pulse is applied to the gate. The second one is caused by the generation of new positive charge. Both are enhanced by V ABSTRACT nitridation. For sub-2nm Hf-dielectric, the threshold voltage instability of pMOSFETs can be more severe than that of nMOSFETs and it can be a limiting factor for the operation voltage. Finally, the project is summarized in Chapter 6 and the future work is discussed

Electrical and chemical characterisation of ultrathin transistor gate dielectric layers

This work examines the suitability of both ultrathin Silicon Oxynitride (SiON) and Hafnium Silicate (HfSiON) layers to be used as high-permittivity gate dielectrics to serve as a replacement to silicon dioxide (Si0 2 )in future Metal-Oxide-Semiconductor (MOS) technologies. The reason Si0 2 needs to be replaced is the extremely high levels of leakage current displayed in ultrathin layers required for sub-90nm CMOS. The main part of the thesis consists of an electrical characterisation section, where the layers are evaluated in terms of their electrical reliability when fabricated into MOS devices, so as to determine their maximum operating voltage and performance during expected device lifetime. Techniques used include constant voltage stress, constant current stress, ramped voltage stress, charge pumping to determine interface state densities and stress induced leakage current measurements. Conventional methods of determining reliability are also evaluated. Results show that these methods cannot be blindly applied in ultrathin regime, and that finding an alternative dielectric material is a major challenge. The second part of the thesis consists of a chemical characterisation section, where blanket layers of the materials are examined using a range of surface analysis techniques. X-ray photoelectron spectroscopy (XPS), synchrotron based photoemission and secondary ion mass spectroscopy (SIMS) are used to determine the chemical composition and chemical depth profile information of the layers and to probe the electronic structure of the valence bands and allow the valence band offsets to be determined