Replacing of glass fibres with seed oil palm fibres for tribopolymeric composites

In the current study, the possibility of replacing woven glass fibres (WGFs) with seed oil palm fibres (SOPFs) as reinforcements for tribopolymeric composites is investigated. Mainly, two different polyester composites based on woven glass reinforced polyester (WGRP) and seed oil palm reinforced polyester (SOPRP) are developed. Different volume fractions (25, 35, and 45 vol.- %) of SOPFs were considered. The experiments were performed using a block on disc (BOD) machine and the tests were conducted under dry contact condition against smooth stainless steel counterface at 2?8 m s21 sliding velocity, 20 N applied load for different sliding distances (up to 5 km). The wear mechanism was categorised using a Scanning Electron Microscope (SEM). The results revealed that the steady state was reached after 4 km sliding distance for both WGRP and SOPRP composites. Seed oil palm reinforced polyester composites showed very high friction coefficient compared to WGRP. 35 vol.-% SOPRP composite exhibited a promising wear result, i.e. SOPFs are possible to replace WGFs in polymeric composites reinforcements whereas the wear resistance of the synthetic and natural composite were almost the same. The wear mechanisms for SOPRP composites were predominated by microcracks, deformation and pulled out of fibres while in the WGRP composite, abrasive nature was observed

A bistable morphing composite using viscoelastically generated prestress

Elastically generated prestress within polymeric composites can be used to create bistable morphing structures; i.e. they can ‘snap through’ between one of two states. In this paper, a morphing bistable structure has been produced, utilising viscoelastically generated prestress. Here, polymeric fibres are subjected to a tensile (viscoelastic) creep load which is released before the fibres are moulded into a matrix. Following curing, the previously strained fibres continue to attempt viscoelastic recovery, creating compressive stresses within the matrix that are counterbalanced by residual tension in the fibres. The bistable structure consists of prestressing strips bonded to the sides of a thin, flexible resin-impregnated fibre-glass sheet. Bistability is achieved through pairs of strips orientated to give opposing cylindrical configurations within the sheet. It is envisaged that viscoelastically prestressed morphing structures may overcome the potential limitations of elastic prestressing; i.e. production flexibility and product longevity

Large-surface-area BN nanosheets and their utilization in polymeric composites with improved thermal and dielectric properties

High-throughput few-layered BN nanosheets have been synthesized through a facile chemical blowing route. They possess large lateral dimensions and high surface area, which are beneficial to fabricate effectively reinforced polymeric composites. The demonstrated composites made of polymethyl methacrylate and BN nanosheets revealed excellent thermal stability, 2.5-fold improved dielectric constant, and 17-fold enhanced thermal conductivity. The results indicate multifunctional practical applications of such polymeric composites in many specific fields, such as thermoconductive insulating long-lifetime packaging for electrical circuits

Development of testing and analysis methodology to assess the long term durability of polymeric composites at high temperatures

A workshop was held to help assess the state-of-the-art in evaluating the long term durability of polymeric matrix composites (PMCs) and to recommend future activities. Design and evaluation of PMCs at elevated temperatures were discussed. The workshop presentations, the findings of the workshop sessions are briefly summarized

Matrix cracking in polymeric composites laminates: Modelling and experiments

Composites ability to retain functionality in the presence of damage is a crucial safety and economic issue. Generally the first damage mode in composite laminates is matrix cracking, which affects the mechanical properties of the structure long before its load-bearing capacity is exhausted. In this paper, a detailed analysis of the effect of matrix cracking on the behaviour of cross-ply [0/90]s and unbalanced symmetric [0/45]s glass/epoxy laminates loaded statically in tension is performed. Theoretical predictions of stiffness reduction due to damage are based on the Equivalent Constraint Model (ECM), which takes into account concurrent matrix cracking in all plies of the laminate, although matrix cracking under consideration is developing only within the off-axis ply of the laminates. The longitudinal Young’s modulus predictions are compared to experimentally derived data obtained using laser Raman spectroscopy (LRS). The good agreement between predicted and measured values of the reduced longitudinal Young’s modulus validates the ECM model and proves that its basic assumptions are accurate. Thus, the predictions for all the mechanical properties by the ECM model are within a realistic range, while experimental evidence is required for further validation

In-situ thermally-reduced graphene oxide/epoxy composites: thermal and mechanical properties

Graphene has excellent mechanical, thermal, optical and electrical properties and this has made it a prime target for use as a filler material in the development of multifunctional polymeric composites. However, several challenges need to be overcome in order to take full advantage of the aforementioned properties of graphene. These include achieving good dispersion and interfacial properties between the graphene filler and the polymeric matrix. In the present work we report the thermal and mechanical properties of reduced graphene oxide/epoxy composites prepared via a facile, scalable and commercially-viable method. Electron micrographs of the composites demonstrate that the reduced graphene oxide (rGO) is well-dispersed throughout the composite. Although no improvements in glass transition temperature, tensile strength, and thermal stability in air of the composites were observed, good improvements in thermal conductivity (about 36%), tensile and storage moduli (more than 13%) were recorded with the addition of 2 wt% of rGO

The assessment of metal fiber reinforced polymeric composites

Because of their low cost, excellent electrical conductivity, high specific strength (strength/density), and high specific modulus (modulus/density) short metal fiber reinforced composites have enjoyed a widespread use in many critical applications such as automotive industry, aircraft manufacturing, national defense, and space technology. However, little data has been found in the study of short metal fibrous composites. Optimum fiber concentration in a resin matrix and fiber aspect ratio (length-to-diameter ratio) are often not available to a user. Stress concentration at short fiber ends is the other concern when the composite is applied to a load-bearing application. Fracture in such composites where the damage will be initiated or accumulated is usually difficult to be determined. An experimental investigation is therefore carefully designed and undertaken to systematically evaluate the mechanical properties as well as electrical properties. Inconel 601 (nickel based) metal fiber with a diameter of eight microns is used to reinforce commercially available thermoset polyester resin. Mechanical testing such as tensile, impact, and flexure tests along with electrical conductivity measurements is conducted to study the feasibility of using such composites. The advantages and limitations of applying chopped metal fiber reinforced polymeric composites are also discussed

High temperature structural fibers: Status and needs

The key to high temperature structural composites is the selection and incorporation of continuous fiber reinforcement with optimum mechanical, physical, and chemical properties. Critical fiber property needs are high strength, high stiffness, and retention of these properties during composite fabrication and use. However, unlike polymeric composites where all three requirements are easily achieved with a variety of commercially available carbon-based fibers, structural fibers with sufficient stiffness and strength retention for high temperature metal, intermetallic, and ceramic composites are not available. The objective here is to discuss in a general manner the thermomechanical stability problem for current high performance fibers which are based on silicon and alumina compositions. This is accomplished by presenting relevant fiber property data with a brief discussion of potential underlying mechanisms. From this general overview, some possible materials engineering approaches are suggested which may lead to minimization and/or elimination of this critical stability problem for current high temperature fibers