Source Apportionment and Forecasting of Aerosol in a Steel City - Case Study of Rourkela

Urban air pollution is one of the biggest problems ascending due to rapid urbanization and industrialization. The improvement of air quality in an urban area in general, constitutes of three phases, monitoring, modeling and control measures. The present research work addresses the requirements of the urban air quality management programme (UAQMP) in Rourkela steel city. A typical UAQMP contains three aspects: monitoring of air pollution, modeling of air pollution and taking control measures. The present study aims to conduct the modeling of particulate air pollution for a steel city. Modeling of particulate matter (PM) pollution is nothing but the application of different mathematical models in source apportionment and forecasting of PM. PM (PM10 and TSP) was collected twice a week for two years (2011-2012) during working hours in Rourkela. The seasonal variations study of PM showed that the aerosol concentration was high during summer and low during monsoon. A detailed chemical characterization of both PM10 and TSP was carried out to find out the concentrations of different metal ions, anions and carbon content. The Spearman rank correlation analysis between different chemical species of PM depicted the presence of both crustal and anthropogenic origins in particulate matter. The enrichment factor analysis highlighted the presence of anthropogenic sources. Three major receptor models were used for the source apportionment of PM, namely chemical mass balance model (CMB), principal component analysis (PCA) and positive matrix factorization (PMF). In selecting source profiles for CMB, an effort has been put to select the profiles which represent the local conditions. Two of the profiles, namely soil dust and road dust, were developed in the present study for better accuracy. All three receptor models have shown that industrial (40-45%) and combustion sources (30-35%) were major contributors to particulate pollution in Rourkela. Artificial neural networks (ANN) were used for the prediction of particulate pollution using meteorological parameters as inputs. The emphasis is to compare the performances of MLP and RBF algorithms in forecasting and provide a rigorous inter-comparison as a first step toward operational PM forecasting models. The training, testing and validation errors of MLP networks are significantly lower than that of RBF networks. The results indicate that both MLP and RBF have shown good prediction capabilities while MLP networks were better than that of RBF networks. There is no profound bias that can be seen in the models which may also suggest that there are very few or zero external factors that may influence the dispersion and distribution of particulate matter in the study area

The Mersey Estuary : sediment geochemistry

This report describes a study of the geochemistry of the Mersey estuary carried out between April 2000 and December 2002. The study was the first in a new programme of surveys of the geochemistry of major British estuaries aimed at enhancing our knowledge and understanding of the distribution of contaminants in estuarine sediments. The report first summarises the physical setting, historical development, geology, hydrography and bathymetry of the Mersey estuary and its catchment. Details of the sampling and analytical programmes are then given followed by a discussion of the sedimentology and geochemistry. The chemistry of the water column and suspended particulate matter have not been studied, the chief concern being with the geochemistry of the surface and near-surface sediments of the Mersey estuary and an examination of their likely sources and present state of contamination

Baseline groundwater chemistry : the Sherwood Sandstone of Devon and Somerset

This report describes the regional geochemistry of groundwater from the Sherwood Sandstone aquifer of Devon and Somerset. In order to assess the likely natural baseline chemistry of the groundwater in the area, information has been gathered from the strategic collection of 21 new groundwater samples, and from collation of existing groundwater, rainfall, mineralogical and geochemical data. The Sherwood Sandstone aquifer results from continental deposition during the early Triassic period. The deposition comprised thick clastic deposits in basins created during the late Permian. There are two distinct units: the Otter Sandstone Formation and the underlying Budleigh Salterton Pebble Beds Formation. These units form the most important aquifer in south-west England. The main chemical properties of the groundwater are determined by rainwater recharge reacting with the aquifer minerals. Of these minerals carbonates are the dominant influence on the water chemistry. While Ca is dominant in groundwaters from both aquifer units, the water types from the two units can be distinguished: the Otter Sandstone Formation aquifer has mainly Ca-HCO3 type waters, with some mixing towards Mg, and the groundwaters in the Budleigh Salterton Pebble Beds Formation aquifer are of Ca-HCO3 type to Na+K-Cl type. There is little variation in the major ion proportion of the groundwaters from the Otter Sandstone Formation, most likely as these represent groundwater in equilibrium with the minerals which give it this character. There is greater variation in the Budleigh Salterton Pebble Beds Formation groundwaters. Besides the difference in groundwater types, the groundwater from the Budleigh Salterton Pebble Beds Formation is more acidic, more oxic, has lower SEC values, and HCO3, Cr, U and Mg concentrations, and higher concentrations of Al, Be, Cd, Cr, Co, Tl and REE than the groundwater from the Otter Sandstone Formation. Human impacts on the water quality are evident. These are mainly visible in the presence of indicator contaminants, such as nitrate. The widespread presence and changes of nitrate concentrations over time indicate the extent to which the unconfined aquifer is influenced by modern farming practices or urban pollution. Concentrations of NO3-N exceeded the current drinking water limit of 11.3 mg L-1 in 25% of the sampled groundwaters, which probably reflects the intensification of agriculture in the study area over the last few decades. Indeed, the dominant land uses of the area are agriculture and grassland. However, recent legislation and the drive towards intelligent farming have meant that in some groundwaters the concentrations of nitrate are decreasing. While many of the groundwaters investigated in this study are of good inorganic quality there are some notable exceptions which contain elevated concentrations of Fe, SO4, Ni, Co and NO3. The distribution of the poor-quality is generally so sporadic that water quality would be difficult to predict prior to drilling a borehole. For many analytes, the 95th percentile of the distributions has been taken as a first approximation of an upper limit of baseline concentrations as this serves to eliminate the most extreme outlier concentrations that likely represent a distinct population

SIGMA GAMMA EPSILON STUDENT RESEARCH POSTER SESSION, GEOLOGICAL SOCIETY OF AMERICA MEETING 2017, SEATTLE, WASHINGTON, USA

The Sigma Gamma Epsilon, an academic honor society for students of the Earth Sciences, is an important tradition at GSA annual meetings. Sigma Gamma Epsilon\u27s goal in sponsoring this session is to provide a student-friendly forum for young researchers to present on undergraduate research; this session has seen increasing interest and participation over the years. The session is open to students (regardless of membership in Sigma Gamma Epsilon) and faculty co-authors working in any area of the geosciences. Those posters authored by student members in good standing of active chapters of Sigma Gamma Epsilon will be judged for two (2) best-poster awards given annually by the Society

Atmospheric Heavy Metal and Nitrogen Deposition Using Mosses as Biomonitors

The Special Issue “Atmospheric Heavy Metal and Nitrogen Deposition Using Mosses as Biomonitors” includes a collection of papers related on aspects of passive moss biomonitoring of air quality in various regions of the world regarding the pollution sources of potentially toxic elements, heavy metal air pollution in the lockdown period due to the COVID-19 pandemic, trends in element atmospheric deposition, and relevance for ecological integrity and human health. Most of the studies were carried out in the framework of the International Cooperative Program on Effects of Air Pollution on Natural Vegetation and Crops (ICP Vegetation) of the United Nations Economic Commission for Europe (UNECE)

Process Modeling in Pyrometallurgical Engineering

The Special Issue presents almost 40 papers on recent research in modeling of pyrometallurgical systems, including physical models, first-principles models, detailed CFD and DEM models as well as statistical models or models based on machine learning. The models cover the whole production chain from raw materials processing through the reduction and conversion unit processes to ladle treatment, casting, and rolling. The papers illustrate how models can be used for shedding light on complex and inaccessible processes characterized by high temperatures and hostile environment, in order to improve process performance, product quality, or yield and to reduce the requirements of virgin raw materials and to suppress harmful emissions

Robotic Automation of Turning Machines in Fenceless Production: A Planning Toolset for Economic-based Selection Optimization between Collaborative and Classical Industrial Robots

Ursprünglich wurden Industrieroboter hauptsächlich hinter Schutzzäunen betrieben, um den Sicherheitsanforderungen gerecht zu werden. Mit der Flexibilisierung der Produktion wurden diese scharfen Trennbereiche zunehmend aufgeweicht und externe Sicherheitstechnik, wie Abstandssensoren, genutzt, um Industrieroboter schutzzaunlos zu betreiben. Ausgehend vom Gedanken dieser Koexistenz bzw. Kooperation wurde die Sicherheitssensorik in den Roboter integriert, um eine wirkliche Kollaboration zu ermöglichen. Diese sogenannten kollaborierenden Roboter, oder Cobots, eröffnen neue Applikationsfelder und füllen somit die bestehenden Automatisierungslücken. Doch welche Automatisierungsvariante ist aus wirtschaftlichen Gesichtspunkten die geeignetste? Bisherige Forschung untersucht zum Großteil isoliert eine der beiden Technologien, ohne dabei einen Systemvergleich hinsichtlich technologischer Spezifika und Wirtschaftlichkeit anzustellen. Daher widmet sich diese Dissertation einer Methodik zum wirtschaftlichen Vergleich von kollaborierenden Robotern und Industrierobotern in schutzzaunlosen Maschinenbeladungssystemen. Besonderer Fokus liegt dabei auf dem Herausarbeiten der technischen Faktoren, die die Wirtschaftlichkeit maßgeblich beeinflussen, um ein Systemverständnis der wirtschaftlichen Struktur beider Robotertechnologievarianten zu erhalten. Zur Untersuchung werden die Inhalte eines solchen Planungsvorhabens beschrieben, kategorisiert, systematisiert und modularisiert. Auf wirtschaftlicher Seite wird ein geeignetes Optimierungsmodell vorgestellt, während auf technischer Seite vor allem die Machbarkeit hinsichtlich Greifbarkeit, Layoutplanung, Robotergeschwindigkeiten und Zykluszeitbestimmung untersucht wird. Mit deduktiven, simulativen, empirischen und statistischen Methoden wird das Systemverhalten für die einzelnen Planungsinhalte analysiert, um die Gesamtwirtschaftlichkeit mit einem Minimum an Investment,- Produktions,- und Zykluszeitinformationen a priori vorhersagen zu können. Es wird gezeigt, dass durch einen Reverse Engineering Ansatz die notwendigen Planungsdaten, im Sinne von Layoutkomposition, Robotergeschwindigkeiten und Taktzeiten, mithilfe von Frontloading zu Planungsbeginn zur Verfügung gestellt werden können. Dabei dient der Kapitalwert als wirtschaftliche Bewertungsgrundlage, dessen Abhängigkeit vom Mensch-Roboter-Interaktionsgrad in einem Vorteilhaftigkeitsdiagramm für die einzelnen Technologiealternativen dargestellt werden kann. Wirtschaftlich fundierte Entscheidungen können somit auf quantitiativer Basis getroffen werden.:1. Introduction 25 1.1 Research Domain 25 1.2 Research Niche 26 1.3 Research Structure 28 2. State of the Art and Research 31 2.1 Turning Machines and Machine Tending 31 2.1.1 Tooling Machine Market Trends and Machine Tending Systems 31 2.1.2 Workpiece System 34 2.1.3 Machine System 36 2.1.4 Logistics System 39 2.1.5 Handling System 41 2.2 Robotics 43 2.2.1 Robot Installation Development and Application Fields 43 2.2.2 Fenceless Industrial and Collaborative Robots 48 2.2.3 Robot Grippers 55 2.3 Planning and Evaluation Methods 56 2.3.1 Planning of General and Manual Workstations 56 2.3.2 Cell Planning for Fully Automated and Hybrid Robot Systems 59 2.3.3 Robot Safety Planning 61 2.3.4 Economic Evaluation Methods 70 2.4 Synthesis - State of the Art and Research 71 3. Solution Approach 77 3.1 Need for Research and General Solution Approach 77 3.2 Use Case Delineation and Planning Focus 80 3.3 Economic Module – Solution Approach 86 3.4 Gripper Feasibility Module – Solution Approach 89 3.5 Rough Layout Discretization Model – Solution Approach 94 3.6 Cycle Time Estimation Module – Solution Approach 97 3.7 Collaborative Speed Estimation Module – Solution Approach 103 3.7.1 General Approach 103 3.7.2 Case 1: Quasi-static Contact with Hand 107 3.7.3 Case 2: Transient Contact with Hand 109 3.7.4 Case 3: Transient Contact with Shoulder 111 3.8 Synthesis – Solution Approach 114 4. Module Development 117 4.1 Economic Module – Module Development 117 4.1.1 General Approach 117 4.1.2 Calculation Scheme for Manual Operation 117 4.1.3 Calculation Scheme for Collaborative Robots 118 4.1.4 Calculation Scheme for Industrial Robots 120 4.2 Gripper Feasibility Module – Module Development 121 4.3 Rough Layout Discretization Module – Module Development 122 4.3.1 General Approach 122 4.3.2 Two-Dimensional Layout Pattern 123 4.3.3 Three-Dimensional Layout Pattern 125 4.4 Cycle Time Estimation Module – Module Development 126 4.4.1 General Approach 126 4.4.2 Reachability Study 127 4.4.3 Simulation Results 128 4.5 Collaborative Speed Estimation Module – Module Development 135 4.5.1 General Approach 135 4.5.2 Case 1: Quasi-static Contact with Hand 135 4.5.3 Case 2: Transient Contact with Hand 143 4.5.4 Case 3: Transient Contact with Shoulder 145 4.6 Synthesis – Module Development 149 5. Practical Verification 155 5.1 Use Case Overview 155 5.2 Gripper Feasibility 155 5.3 Layout Discretization 156 5.4 Collaborative Speed Estimation 157 5.5 Cycle Time Estimation 158 5.6 Economic Evaluation 160 5.7 Synthesis – Practical Verification 161 6. Results and Conclusions 165 6.1 Scientific Findings and Results 165 6.2 Critical Appraisal and Outlook 173Initially, industrial robots were mainly operated behind safety fences to account for the safety requirements. With production flexibilization, these sharp separation areas have been increasingly softened by utilizing external safety devices, such as distance sensors, to operate industrial robots fenceless. Based on this idea of coexistence or cooperation, safety technology has been integrated into the robot to enable true collaboration. These collaborative robots, or cobots, open up new application fields and fill the existing automation gap. But which automation variant is most suitable from an economic perspective? Present research dealt primarily isolated with one technology without comparing these systems regarding technological and economic specifics. Therefore, this doctoral thesis pursues a methodology to economically compare collaborative and industrial robots in fenceless machine tending systems. A particular focus lies on distilling the technical factors that mainly influence the profitability to receive a system understanding of the economic structure of both robot technology variants. For examination, the contents of such a planning scheme are described, categorized, systematized, and modularized. A suitable optimization model is presented on the economic side, while the feasibility regarding gripping, layout planning, robot velocities, and cycle time determination is assessed on the technical side. With deductive, simulative, empirical, and statistical methods, the system behavior of the single planning entities is analyzed to predict the overall profitability a priori with a minimum of investment,- production,- and cycle time information. It is demonstrated that the necessary planning data, in terms of layout composition, robot velocities, and cycle times, can be frontloaded to the project’s beginning with a reverse engineering approach. The net present value serves as the target figure, whose dependency on the human-robot interaction grade can be illustrated in an advantageousness diagram for the individual technical alternatives. Consequently, sound economic decisions can be made on a quantitative basis.:1. Introduction 25 1.1 Research Domain 25 1.2 Research Niche 26 1.3 Research Structure 28 2. State of the Art and Research 31 2.1 Turning Machines and Machine Tending 31 2.1.1 Tooling Machine Market Trends and Machine Tending Systems 31 2.1.2 Workpiece System 34 2.1.3 Machine System 36 2.1.4 Logistics System 39 2.1.5 Handling System 41 2.2 Robotics 43 2.2.1 Robot Installation Development and Application Fields 43 2.2.2 Fenceless Industrial and Collaborative Robots 48 2.2.3 Robot Grippers 55 2.3 Planning and Evaluation Methods 56 2.3.1 Planning of General and Manual Workstations 56 2.3.2 Cell Planning for Fully Automated and Hybrid Robot Systems 59 2.3.3 Robot Safety Planning 61 2.3.4 Economic Evaluation Methods 70 2.4 Synthesis - State of the Art and Research 71 3. Solution Approach 77 3.1 Need for Research and General Solution Approach 77 3.2 Use Case Delineation and Planning Focus 80 3.3 Economic Module – Solution Approach 86 3.4 Gripper Feasibility Module – Solution Approach 89 3.5 Rough Layout Discretization Model – Solution Approach 94 3.6 Cycle Time Estimation Module – Solution Approach 97 3.7 Collaborative Speed Estimation Module – Solution Approach 103 3.7.1 General Approach 103 3.7.2 Case 1: Quasi-static Contact with Hand 107 3.7.3 Case 2: Transient Contact with Hand 109 3.7.4 Case 3: Transient Contact with Shoulder 111 3.8 Synthesis – Solution Approach 114 4. Module Development 117 4.1 Economic Module – Module Development 117 4.1.1 General Approach 117 4.1.2 Calculation Scheme for Manual Operation 117 4.1.3 Calculation Scheme for Collaborative Robots 118 4.1.4 Calculation Scheme for Industrial Robots 120 4.2 Gripper Feasibility Module – Module Development 121 4.3 Rough Layout Discretization Module – Module Development 122 4.3.1 General Approach 122 4.3.2 Two-Dimensional Layout Pattern 123 4.3.3 Three-Dimensional Layout Pattern 125 4.4 Cycle Time Estimation Module – Module Development 126 4.4.1 General Approach 126 4.4.2 Reachability Study 127 4.4.3 Simulation Results 128 4.5 Collaborative Speed Estimation Module – Module Development 135 4.5.1 General Approach 135 4.5.2 Case 1: Quasi-static Contact with Hand 135 4.5.3 Case 2: Transient Contact with Hand 143 4.5.4 Case 3: Transient Contact with Shoulder 145 4.6 Synthesis – Module Development 149 5. Practical Verification 155 5.1 Use Case Overview 155 5.2 Gripper Feasibility 155 5.3 Layout Discretization 156 5.4 Collaborative Speed Estimation 157 5.5 Cycle Time Estimation 158 5.6 Economic Evaluation 160 5.7 Synthesis – Practical Verification 161 6. Results and Conclusions 165 6.1 Scientific Findings and Results 165 6.2 Critical Appraisal and Outlook 17

Integrated Waste Management

This book reports research on policy and legal issues, anaerobic digestion of solid waste under processing aspects, industrial waste, application of GIS and LCA in waste management, and a couple of research papers relating to leachate and odour management

Foresight study - Thematic Report IV: Secondary Raw Materials (Including Mine Wastes)

ABSTRACT: This thematic report has been developed within the Minerals4EU project in the context of the first Foresight Study report (WP6) that comprises a central report and five thematic reports. These contributions were designed according to a well-defined structure to fit the purposes of the central Foresight Study report. The scope and targets of the first Foresight Study significantly determine the nature of the documents and may not be suited for unspecified or differing purposes.N/