Evaluation of an intensified continuous heat-exchanger reactor for inherently safer characteristics

The present paper deals with the establishment of a new methodology in order to evaluate the inherently safer characteristics of a continuous intensified reactor in the case of an exothermic reaction. The transposition of the propionic anhydride esterification by 2-butanol into a new prototype of ‘‘heatexchanger/ reactor’’, called open plate reactor (OPR), designed by Alfa Laval Vicarb has been chosen as a case study. Previous studies have shown that this exothermic reaction is relatively simple to carry out in a homogeneous liquid phase, and a kinetic model is available. A dedicated software model is then used not only to assess the feasibility of the reaction in the ‘‘heat-exchanger/reactor’’ but also to estimate the temperature and concentration profiles during synthesis and to determine optimal operating conditions for safe control. Afterwards the reaction was performed in the reactor. Good agreement between experimental results and the simulation validates the model to describe the behavior of the process during standard runs. A hazard and operability study (HAZOP) was then applied to the intensified process in order to identify the potential hazards and to provide a number of runaway scenarios. Three of them are highlighted as the most dangerous: no utility flow, no reactant flows, both stop at the same time. The behavior of the process is simulated following the stoppage of both the process and utility fluid. The consequence on the evolution of temperature profiles is then estimated for a different hypothesis taking into account the thermal inertia of the OPR. This approach reveals an intrinsically safer behavior of the OPR

Dynamic Behaviour of a Continuous Heat Exchanger/Reactor after Flow Failure

The intensified technologies offer new prospects for the development of hazardous chemical syntheses in safer conditions: the idea is to reduce the reaction volume by increasing the thermal performances and preferring the continuous mode to the batch one. In particular, the Open Plate Reactor (OPR) type “reactor/ exchanger” also including a modular block structure, matches these characteristics perfectly. The aim of this paper is to study the OPR behaviour during a normal operation, that is to say, after a stoppage of the circulation of the cooling fluid. So, an experiment was carried out, taking the oxidation of sodium thiosulfate with hydrogen peroxide as an example. The results obtained, in particular with regard to the evolution of the temperature profiles of the reaction medium as a function of time along the apparatus, are compared with those predicted by a dynamic simulator of the OPR. So, the average heat transfer coefficient regarding the “utility” fluid is evaluated in conductive and natural convection modes, and then integrated in the simulator. The conclusion of this study is that, during a cooling failure, a heat transfer by natural convection would be added to the conduction, which contributes to the intrinsically safer character of the apparatus

Experimental and analytical performance investigation of air to air two phase closed thermosyphon based heat exchangers

In recent years, the use of wickless heat pipes (thermosyphons) in heat exchangers has been on the rise, particularly in gas to gas heat recovery applications due to their reliability and the level of contingency they offer compared to conventional heat exchangers. Recent technological advances in the manufacturing processes and production of gravity assisted heat pipes (thermosyphons) have resulted in significant improvements in both quality and cost of industrial heat pipe heat exchangers. This in turn has broadened the potential for their usage in industrial waste heat recovery applications. In this paper, a tool to predict the performance of an air to air thermosyphon based heat exchanger using the ε-NTU method is explored. This tool allows the predetermination of variables such as the overall heat transfer coefficient, effectiveness, pressure drop and heat exchanger duty according to the flow characteristics and the thermosyphons configuration within the heat exchanger. The new tool's predictions were validated experimentally and a good correlation between the theoretical predictions and the experimental data, was observed. © 2014 Elsevier Ltd. All rights reserved

An integrated methodology to assess the operational and environmental performance of a conceptual regenerative helicopter

This paper aims to present an integrated multidisciplinary simulation framework, deployed for the comprehensive assessment of combined helicopter powerplant systems at mission level. Analytical evaluations of existing and conceptual regenerative engine designs are carried out in terms of operational performance and environmental impact. The proposed methodology comprises a wide-range of individual modeling theories applicable to helicopter flight dynamics, gas turbine engine performance as well as a novel, physics-based, stirred reactor model for the rapid estimation of various helicopter emissions species. The overall methodology has been deployed to conduct a preliminary trade-off study for a reference simple cycle and conceptual regenerative twin-engine light helicopter, modeled after the Airbus Helicopters Bo105 configuration, simulated under the representative mission scenarios. Extensive comparisons are carried out and presented for the aforementioned helicopters at both engine and mission level, along with general flight performance charts including the payload-range diagram. The acquired results from the design trade-off study suggest that the conceptual regenerative helicopter can offer significant improvement in the payload-range capability, while simultaneously maintaining the required airworthiness requirements. Furthermore, it has been quantified through the implementation of a representative case study that, while the regenerative configuration can enhance the mission range and payload capabilities of the helicopter, it may have a detrimental effect on the mission emissions inventory, specifically for NOx (Nitrogen Oxides). This may impose a trade-off between the fuel economy and environmental performance of the helicopter. The proposed methodology can effectively be regarded as an enabling technology for the comprehensive assessment of conventional and conceptual helicopter powerplant systems, in terms of operational performance and environmental impact as well as towards the quantification of their associated trade-offs at mission level. Ali Fakhre, Ioannis Goulos, Vassilios Pachidis School of Engineering, Energy, Power and Propulsion Division, Cranfield University, Cranfield, Bedford, MK43 0AL, UK [email protected] The Aeronautical Journal, 2015, Vol 119, Issue 1211, pp1-24 Published by Cambridge University Press. This is the Author Accepted Manuscript. This article may be used for personal use only. The final published version (version of record) is available online at 10.1017/S0001924000010253. Please refer to any applicable publisher terms of use

Model predictive control based on LPV models with parameter-varying delays

© 2019 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.This paper presents a Model Predictive Control (MPC) strategy based on Linear Parameter Varying (LPV) models with varying delays affecting states and inputs. The proposed control approach allows the controller to accommodate the scheduling parameters and delay change. By computing the prediction of the state variables and delay along a prediction time horizon, the system model can be modified according to the evaluation of the estimated state and delay at each time instant. Moreover, the solution of the optimization problem associated with the MPC design is achieved by solving a series of Quadratic Programming (QP) problem at each time instant. This iterative approach reduces the computational burden compared to the solution of a non-linear optimization problem. A pasteurization plant system is used as a case study to demonstrate the effectiveness of the proposed approach.Peer ReviewedPostprint (author's final draft

Min-Max Predictive Control of a Pilot Plant using a QP Approach

47th IEEE Conference on Decision and Control 9-11 Dec. 2008The practical implementation of min-max MPC (MMMPC) controllers is limited by the computational burden required to compute the control law. This problem can be circumvented by using approximate solutions or upper bounds of the worst possible case of the performance index. In a previous work, the authors presented a computationally efficient MMMPC control strategy in which a close approximation of the solution of the min-max problem is computed using a quadratic programming problem. In this paper, this approach is validated through its application to a pilot plant in which the temperature of a reactor is controlled. The behavior of the system and the controller are illustrated by means of experimental results

Active cooling control of the CLEO detector using a hydrocarbon coolant farm

We describe a novel approach to particle-detector cooling in which a modular farm of active coolant-control platforms provides independent and regulated heat removal from four recently upgraded subsystems of the CLEO detector: the ring-imaging Cherenkov detector, the drift chamber, the silicon vertex detector, and the beryllium beam pipe. We report on several aspects of the system: the suitability of using the aliphatic-hydrocarbon solvent PF(TM)-200IG as a heat-transfer fluid, the sensor elements and the mechanical design of the farm platforms, a control system that is founded upon a commercial programmable logic controller employed in industrial process-control applications, and a diagnostic system based on virtual instrumentation. We summarize the system's performance and point out the potential application of the design to future high-energy physics apparatus.Comment: 21 pages, LaTeX, 5 PostScript figures; version accepted for publication in Nuclear Instruments and Methods in Physics Research

Improving the Accuracy and Scope of Control-Oriented Vapor Compression Cycle System Models

The benefits of applying advanced control techniques to vapor compression cycle systems are well know. The main advantages are improved performance and efficiency, the achievement of which brings both economic and environmental gains. One of the most significant hurdles to the practical application of advanced control techniques is the development of a dynamic system level model that is both accurate and mathematically tractable. Previous efforts in control-oriented modeling have produced a class of heat exchanger models known as moving-boundary models. When combined with mass flow device models, these moving-boundary models provide an excellent framework for both dynamic analysis and control design. This thesis contains the results of research carried out to increase both the accuracy and scope of these system level models. The improvements to the existing vapor compression cycle models are carried out through the application of various modeling techniques, some static and some dynamic, some data-based and some physics-based. Semiempirical static modeling techniques are used to increase the accuracy of both heat exchangers and mass flow devices over a wide range of operating conditions. Dynamic modeling techniques are used both to derive new component models that are essential to the simulation of very common vapor compression cycle systems and to improve the accuracy of the existing compressor model. A new heat exchanger model that accounts for the effects of moisture in the air is presented. All of these model improvements and additions are unified to create a simple but accurate system level model with a wide range of application. Extensive model validation results are presented, providing both qualitative and quantitative evaluation of the new models and model improvements.Air Conditioning and Refrigeration Project 17