291,649 research outputs found
Integration of a failure monitoring within a hybrid dynamic simulation environment
The complexity and the size of the industrial chemical processes induce the monitoring of a growing number of process variables. Their knowledge is generally based on the measurements of system variables and on the physico-chemical models of the process. Nevertheless this information is imprecise because of process and measurement noise. So the research ways aim at developing new and more powerful techniques for the detection of process fault. In this work, we present a method for the fault detection based on the comparison between the real system and the reference model evolution generated by the extended Kalman filter. The reference model is simulated by the dynamic hybrid simulator, PrODHyS. It is a general object-oriented environment which provides common and reusable components designed for the development and the management of dynamic simulation of industrial systems. The use of this method is illustrated through a didactic example relating to the field of Chemical Process System Engineering
Model based fault diagnosis for hybrid systems : application on chemical processes
The complexity and the size of the industrial chemical processes induce the monitoring of a growing number of process variables. Their knowledge is generally based on the measurements of system variables and on the physico-chemical models of the process. Nevertheless, this information is imprecise because of process and measurement noise. So the research ways aim at developing new and more powerful techniques for the detection of process fault. In this work, we present a method for the fault detection based on the comparison between the real system and the reference model evolution generated by the extended Kalman filter. The reference model is simulated by the dynamic hybrid simulator, PrODHyS. It is a general object-oriented environment which provides common and reusable components designed for the development and the management of dynamic simulation of industrial systems. The use of this method is illustrated through a didactic example relating to the field of Chemical Process System Engineering
Life cycle assessment (LCA) applied to the process industry: a review
Purpose : Life cycle assessment (LCA) methodology is a well-established analytical method to quantify environmental impacts, which has been mainly applied to products. However, recent literature would suggest that it has also the potential as an analysis and design tool for processes, and stresses that one of the biggest challenges of this decade in the field of process systems engineering (PSE) is the development of tools for environmental considerations. Method : This article attempts to give an overview of the integration of LCA methodology in the context of industrial ecology, and focuses on the use of this methodology for environmental considerations concerning process design and optimization. Results : The review identifies that LCA is often used as a multi-objective optimization of processes: practitioners use LCA to obtain the inventory and inject the results into the optimization model. It also shows that most of the LCA studies undertaken on process analysis consider the unit processes as black boxes and build the inventory analysis on fixed operating conditions. Conclusions : The article highlights the interest to better assimilate PSE tools with LCA methodology, in order to produce a more detailed analysis. This will allow optimizing the influence of process operating conditions on environmental impacts and including detailed environmental results into process industry
Dynamic hybrid simulation of batch processes driven by a scheduling module
Simulation is now a CAPE tool widely used by practicing engineers for process design and control. In particular, it allows various offline analyses to improve system performance such as productivity, energy efficiency, waste reduction, etc. In this framework, we have developed the dynamic hybrid simulation environment PrODHyS whose particularity is to provide general and reusable object-oriented components dedicated to the modeling of devices and operations found in chemical processes. Unlike continuous processes, the dynamic simulation of batch processes requires the execution of control recipes to achieve a set of production orders. For these reasons, PrODHyS is coupled to a scheduling module (ProSched) based on a MILP mathematical model in order to initialize various operational parameters and to ensure a proper completion of the simulation. This paper focuses on the procedure used to generate the simulation model corresponding to the realization of a scenario described through a particular scheduling
Electrochemical treatment of industrial sulfidic spent caustic streams for sulfide removal and caustic recovery
Alkaline spent caustic streams (SCS) produced in the petrochemical and chemical manufacturing industry, contain high concentrations of reactive sulfide (HS-) and caustic soda (NaOH). Common treatment methods entail high operational costs while not recovering the possible resources that SCS contain. Here we studied the electrochemical treatment of SCS from a chemical manufacturing industry in an electrolysis cell, aiming at anodic HS- removal and cathodic NaOH, devoid of sulfide, recovery. Using a synthetic SCS we first evaluated the HS- oxidation product distribution over time, as well as the HS- removal and the NaOH recovery, as a function of current density. In a second step, we investigated the operational aspects of such treatment for the industrial SCS, under 300 A m(-2) fixed current density. In an electrolysis cell receiving 205 +/- 60 g S L-1 d(-1) HS- over 20 days of continuous operation, HS- was removed with a 38.0 +/- 7.7 % removal and similar to 80 % coulombic efficiency, with a concomitant recovery of a similar to 12 wt.% NaOH solution. The low cell voltage obtained (1.75 +/- 0.12 V), resulted in low energy requirements of 3.7 +/- 0.6 kW h kg(-1) S and 6.3 +/- 0.4 kW h kg(-1) NaOH and suggests techno-economic viability of this process
Open problems in artificial life
This article lists fourteen open problems in artificial life, each of which is a grand challenge requiring a major advance on a fundamental issue for its solution. Each problem is briefly explained, and, where deemed helpful, some promising paths to its solution are indicated
Long-run dynamics of the U.S. patent classification system
Almost by definition, radical innovations create a need to revise existing
classification systems. In this paper, we argue that classification system
changes and patent reclassification are common and reveal interesting
information about technological evolution. To support our argument, we present
three sets of findings regarding classification volatility in the U.S. patent
classification system. First, we study the evolution of the number of distinct
classes. Reconstructed time series based on the current classification scheme
are very different from historical data. This suggests that using the current
classification to analyze the past produces a distorted view of the evolution
of the system. Second, we study the relative sizes of classes. The size
distribution is exponential so classes are of quite different sizes, but the
largest classes are not necessarily the oldest. To explain this pattern with a
simple stochastic growth model, we introduce the assumption that classes have a
regular chance to be split. Third, we study reclassification. The share of
patents that are in a different class now than they were at birth can be quite
high. Reclassification mostly occurs across classes belonging to the same
1-digit NBER category, but not always. We also document that reclassified
patents tend to be more cited than non-reclassified ones, even after
controlling for grant year and class of origin
The Research Space: using the career paths of scholars to predict the evolution of the research output of individuals, institutions, and nations
In recent years scholars have built maps of science by connecting the
academic fields that cite each other, are cited together, or that cite a
similar literature. But since scholars cannot always publish in the fields they
cite, or that cite them, these science maps are only rough proxies for the
potential of a scholar, organization, or country, to enter a new academic
field. Here we use a large dataset of scholarly publications disambiguated at
the individual level to create a map of science-or research space-where links
connect pairs of fields based on the probability that an individual has
published in both of them. We find that the research space is a significantly
more accurate predictor of the fields that individuals and organizations will
enter in the future than citation based science maps. At the country level,
however, the research space and citations based science maps are equally
accurate. These findings show that data on career trajectories-the set of
fields that individuals have previously published in-provide more accurate
predictors of future research output for more focalized units-such as
individuals or organizations-than citation based science maps
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