BIBLE A whole-air sampling as a window on Asian biogeochemistry

Asian trace gas and aerosol emissions into carbon, nitrogen, and other elemental cycles will figure prominently in near term Earth system evolution. Atmospheric hydrocarbon measurements resolve numerous chemical species and can be used to investigate sourcing for key geocarriers. A recent aircraft study of biomass burning and lightning (BIBLE A) explored the East Asian atmosphere and was unique in centering on the Indonesian archipelago. Samples of volatile organics taken over/between the islands of Japan, Saipan, Java, and Borneo are here examined as a guide to whole-air-based studies of future Asian biogeochemistry. The midlatitude onshore/offshore pulse and tropical convection strongly influence concentration distributions. As species of increasing molecular weight are considered, rural, combustion, and industrial source regimes emerge. Methane-rich inputs such as waste treatment and rice cultivation are evidenced in the geostrophic outflow. The Indonesian atmosphere is rich in biomass burning markers and also those of vehicular activity. Complexity of air chemistry in the archipelago is a direct reflection of diverse topography, land use, and local economies in a rapidly developing nation. Conspicuous in its absence is the fingerprint for liquefied petroleum gas leakage, but it can be expected to appear as demand for clean fossil fuels rises along with per capita incomes. Combustion tracers indicate high nitrogen mobilization rates, linking regional terrestrial geocycles with open marine ecosystems. Sea to air fluxes are superimposed on continental and marine backgrounds for the methyl halides. However, ocean hot spots are not coordinated and suggest an intricate subsurface kinetics. Levels of long-lived anthropogenic halocarbons attest to the success of international environmental treaties while reactive chlorine containing species track industrial air masses. The dozens of hydrocarbons resolvable by gas chromatographic methods will enable monitoring of upcoming Asian modernization. Crucial uncertainties are underscored. Signatures for Asian combustion processes and megacities have been obtained only indirectly or at a distance. Detailed fingerprinting must be combined with regular aircraft and ground station measurements to maximize utility of the database

PICES Press, Vol. 14, No. 1, January 2006

The state of PICES science - 2005 (pdf, 0.2 Mb) 2005 Wooster Award (pdf, 0.4 Mb) Korea and U.S. federate metadata collection (pdf, 0.3 Mb) PICES Interns (pdf, 0.3 Mb) Studies on long-term variation of ocean ecosystem / climate interactions based on the Odate collection (pdf, 0.2 Mb) Hokkaido University Fisheries & Oceanographic Database CD-ROM (pdf, 0.2 Mb) Workshop on sardine and anchovy fluctuations (pdf, 0.1 Mb) Photo highlights of PICES XIV (pdf, 0.4 Mb) Workshop on SEEDS-II (pdf, 0.2 Mb) NPAFC-PICES joint symposium "The status of Pacific salmon and their role in North Pacific marine ecosystems" (pdf, 0.2 Mb) PICES Calendar (pdf, 0.2 Mb) New Chairman of the PICES Fishery Science Committee (pdf, 0.1 Mb) The state of the western North Pacific in the first half of 2005 (pdf, 0.4 Mb) Latest and upcoming PICES publications (pdf, 0.4 Mb) Recent trends in waters of the subarctic NE Pacific (pdf, 0.2 Mb) The Bering Sea: Current status and recent events (pdf, 0.1 Mb) PICES and GLOBEC to sponsor workshop on sub-arctic seas (pdf, 0.1 Mb) Professor Mikhail N. Koshlyakov - 75 (pdf, 0.1 Mb) Obituary - Dr. Al Tyler (pdf, 0.1 Mb

The International Intercomparison Exercise of Underway fCO2 Systems During the R/V Meteor Cruise 36/1 in the North Atlantic Ocean

Measurements of the fugacity of carbon dioxide (fCO2) in surface seawater are an important part of studies of the global carbon cycle and its anthropogenic perturbation. An important step toward the thorough interpretation of the vast amount of available fCO2 data is the establishment of a database system that would make sure measurements more widely available for use in understanding the basin- and global-scale distribution of fCO2 and its influence on the oceanic uptake of anthropogenic CO2. Such an effort, however, is based on knowledge of data sets from different laboratories. Currently, however, there is not much known about this subject

Do bacteria thrive when the ocean acidifies? Results from an off-­shore mesocosm study

Marine bacteria are the main consumers of the freshly produced organic matter. In order to meet their carbon demand, bacteria release hydrolytic extracellular enzymes that break down large polymers into small usable subunits. Accordingly, rates of enzymatic hydrolysis have a high potential to affect bacterial organic matter recycling and carbon turnover in the ocean. Many of these enzymatic processes were shown to be pH sensitive in previous studies. Due to the continuous rise in atmospheric CO2 concentration, seawater pH is presently decreasing at a rate unprecedented during the last 300 million years with so-far unknown consequences for microbial physiology, organic matter cycling and marine biogeochemistry. We studied the effects of elevated seawater pCO2 on a natural plankton community during a large-scale mesocosm study in a Norwegian fjord. Nine 25m-long Kiel Off-Shore Mesocosms for Future Ocean Simulations (KOSMOS) were adjusted to different pCO2 levels ranging from ca. 280 to 3000 µatm by stepwise addition of CO2 saturated seawater. After CO2 addition, samples were taken every second day for 34 days. The first phytoplankton bloom developed around day 5. On day 14, inorganic nutrients were added to the enclosed, nutrient-poor waters to stimulate a second phytoplankton bloom, which occurred around day 20. Our results indicate that marine bacteria benefit directly and indirectly from decreasing seawater pH. During both phytoplankton blooms, more transparent exopolymer particles were formed in the high pCO2 mesocosms. The total and cell-specific activities of the protein-degrading enzyme leucine aminopeptidase were elevated under low pH conditions. The combination of enhanced enzymatic hydrolysis of organic matter and increased availability of gel particles as substrate supported higher bacterial abundance in the high pCO2 treatments. We conclude that ocean acidification has the potential to stimulate the bacterial community and facilitate the microbial recycling of freshly produced organic matter, thus strengthening the role of the microbial loop in the surface ocean