Textile sensors platform for the selective and simultaneous detection of chloride ion and pH in sweat

open7noAcknowledgements. Te National Operation Program (PON) of the Ministry of Education, University and Research supported this work (Project PON-MIUR 2018 (Italy) ARS01_00996: “TEX-STYLE—Nuovi tessuti intelligenti e sostenibili multi-settoriali per design creativo e stile made-in-Italy”). Te authors wish to thank Dr. Nicola Patelli and Dr. Alberto Piccioni for the SEM images.The development of wearable sensors, in particular fully-textile ones, is one of the most interesting open challenges in bioelectronics. Several and significant steps forward have been taken in the last decade in order to achieve a compact, lightweight, cost-effective, and easy to wear platform for healthcare and sport activities real-time monitoring. We have developed a fully textile, multi-thread biosensing platform that can detect different bioanalytes simultaneously without interference, and, as an example, we propose it for testing chloride ions (Cl−) concentration and pH level. The textile sensors are simple threads, based on natural and synthetic fibers, coated with the conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) and properly functionalized with either a nano-composite material or a chemical sensitive dye to obtain Cl− and pH selective sensing functionality, respectively. The single-thread sensors show excellent sensitivity, reproducibility, selectivity, long term stability and the ability to work with small volumes of solution. The performance of the developed textile devices is demonstrated both in buffer solution and in artificial human perspiration to perform on-demand and point-of-care epidermal fluids analysis. The possibility to easily knit or sew the thread sensors into fabrics opens up a new vision for a textile wearable multi-sensing platform achievable in the near future.openPossanzini L.; Decataldo F.; Mariani F.; Gualandi I.; Tessarolo M.; Scavetta E.; Fraboni B.Possanzini L.; Decataldo F.; Mariani F.; Gualandi I.; Tessarolo M.; Scavetta E.; Fraboni B

Textile chemical sensors based on conductive polymers for the analysis of sweat

Wearable textile chemical sensors are promising devices due to the potential applications in medicine, sports activities and occupational safety and health. Reaching the maturity required for commercialization is a technology challenge that mainly involves material science because these sensors should be adapted to flexible and light-weight substrates to preserve the comfort of the wearer. Conductive polymers (CPs) are a fascinating solution to meet this demand, as they exhibit the mechanical properties of polymers, with an electrical conductivity typical of semiconductors. Moreover, their biocompatibility makes them promising candidates for effectively interfacing the human body. In particular, sweat analysis is very attractive to wearable technologies as perspiration is a naturally occurring process and sweat can be sampled non-invasively and continuously over time. This review discusses the role of CPs in the development of textile electrochemical sensors specifically designed for real-time sweat monitoring and the main challenges related to this topic

Characterizing the Impedance Properties of Dry E-Textile Electrodes Based on Contact Force and Perspiration

Biopotential electrodes play an integral role within smart wearables and clothing in capturing vital signals like electrocardiogram (ECG), electromyogram (EMG), and electroencephalogram (EEG). This study focuses on dry e-textile electrodes (E1–E6) and a laser-cut knit electrode (E7), to assess their impedance characteristics under varying contact forces and moisture conditions. Synthetic perspiration was applied using a moisture management tester and impedance was measured before and after exposure, followed by a 24 h controlled drying period. Concurrently, the signal-to-noise ratio (SNR) of the dry electrode was evaluated during ECG data collection on a healthy participant. Our findings revealed that, prior to moisture exposure, the impedance of electrodes E7, E5, and E2 was below 200 ohm, dropping to below 120 ohm post-exposure. Embroidered electrodes E6 and E4 exhibited an over 25% decrease in mean impedance after moisture exposure, indicating the impact of stitch design and moisture on impedance. Following the controlled drying, certain electrodes (E1, E2, E3, and E4) experienced an over 30% increase in mean impedance. Overall, knit electrode E7, and embroidered electrodes E2 and E6, demonstrated superior performance in terms of impedance, moisture retention, and ECG signal quality, revealing promising avenues for future biopotential electrode designs

Systematic review of textile-based electrodes for long-term and continuous surface electromyography recording

This systematic review concerns the use of smart textiles enabled applications based on myoelectric activity. Electromyography (EMG) is the technique for recording and evaluating electric signals related to muscle activity (myoelectric). EMG is a well-established technique that provides a wealth of information for clinical diagnosis, monitoring, and treatment. Introducing sensor systems that allow for ubiquitous monitoring of health conditions using textile integrated solutions not only opens possibilities for ambulatory, long-term, and continuous health monitoring outside the hospital, but also for autonomous self-administration. Textile-based electrodes have demonstrated potential as a fully operational alternative to \u27standard\u27 Ag/AgCl electrodes for recording surface electromyography (sEMG) signals. As a substitute for Ag/AgCl electrodes fastened to the skin by taping or pre-gluing adhesive, textile-based electrodes have the advantages of being soft, flexible, and air permeable; thus, they have advantages in medicine and health monitoring, especially when self-administration, real-time, and long-term monitoring is required. Such advances have been achieved through various smart textile techniques; for instance, adding functions in textiles, including fibers, yarns, and fabrics, and various methods for incorporating functionality into textiles, such as knitting, weaving, embroidery, and coating. In this work, we reviewed articles from a textile perspective to provide an overview of sEMG applications enabled by smart textile strategies. The overview is based on a literature evaluation of 41 articles published in both peer-reviewed journals and conference proceedings focusing on electrode materials, fabrication methods, construction, and sEMG applications. We introduce four textile integration levels to further describe the various textile electrode sEMG applications reported in the reviewed literature. We conclude with suggestions for future work along with recommendations for the reporting of essential benchmarking information in current and future textile electrode applications

An investigation of textile sensors and their application in wearable electronics

Using a garment as a wearable sensing device has become a reality. New methods and techniques in the field of wearable sensors are being developed and can now be incorporated into the wearer’s everyday attire. This research focuses on two types of textile based sensors – a wearable textile electrode used for ECG continuous monitoring, and a stitch sensor for monitoring body movement. These sensors were designed into a purposely engineered Smart Sports Bra (SSB) which can be regarded as a sensor itself. After a thorough investigation, two optimum textile electrodes were created; a plain electrode using cut and sew method (CSM) and a net type knitted electrode using knitting method (KM). The CSM electrode was made with conductive fabric (MedTexTM P-130) and the KM electrode was made with conductive thread (silver-plated nylon 234/34 four-ply), these materials having the lowest tested contact impedance; 450Ω and 500Ω, respectively. Both electrodes demonstrated a level of noise and baseline drift comparable with standard commercial wet-gel electrodes, which was corrected by optimising their size to 20x40 mm, holding pressure of 4 kPa (30 mmHg) and the electrode position at the 6th intercostal space on the right and left mid-clavicular, with one placed at the scapular line in the rear side (i.e. back horizontal formation) which gives clear and reliable ECG signal. These optimum electrodes were integrated directly into SSBs, in which a novel high shear, net structure, acting as a shock absorber to body movement that shows more stable electrode to skin contact by reducing the body motion artefact. During the investigation of the stitch stretch sensor the single jersey nylon fabric (4.44 tex two-ply) with 25% spandex (7.78 tex) had the highest elastic recovery (93%). Using this fabric, the work went on to show that the stitch type 304 (Zig-zag lock stitch) using the 117/17 two-ply thread demonstrated the best results i.e., maximum working range 50%, gauge factor 1.61, hysteresis 6.25% ΔR, linearity (R2 ) is 0.98, and good repeatability (drift in R2 is -0.00). The stitch stretch sensor was also incorporated into a sports bra SSB and positioned across the chest for respiration monitoring. This thesis contributes to a growing body of research in wearable E -textile solutions to support health and well-being, with fully functional sensors and easy-to-use design, for continues health monitoring

SMART FABRICS-WEARABLE TECHNOLOGY

Smart fabrics, generally regarded as smart Textiles are fabrics that have embedded electronics and interconnections woven into them, resulting in physical flexibility that is not achievable with other known electronic manufacturing techniques. Interconnections and components are intrinsic to the fabric therefore are not visible and less susceptible of getting tangled by surrounding objects. Smart fabrics can also more easily adapt to quick changes in the sensing and computational requirements of any specific application, this feature being useful for power management and context awareness. For electronic systems to be part of our day-to-day outfits such electronic devices need to conform to requirements as regards wear-ability, this is the vision of wearable technology. Wearable systems are characterized by their capability to automatically identify the activity and the behavioral status of their wearer as well as of the situation around them, and to use this information to adjust the systems' configuration and functionality. This write-up focused on recent developments in the field of Smart Fabrics and pays particular attention to the materials and their manufacturing techniques

A fabric-based textile stretch sensor for optimized measurement of strain in clothing

Fabric stretch sensors are available as planar fabrics, but their reliability and reproducibility are low. To find a good working setup for use in an elastic sports garment, the design of such sensors must be optimized. The main purpose of this study was to develop resistive strain sensors from stretchable conductive fabric and investigating the influence of stretchability on conductivity/resistivity. The influence of using the sensor in a sweat rich environment was also determined, in order to evaluate the potential use of the sensor in sporting garments. The sensor resistivity performance was analyzed for its sensitivity, working range, and repeatability and it was determined what makes the sensitivity when elongated or stretched. The resistivity was found to decrease with elongation if no sweat is present, this can be due to molecular rearrangement and a higher degree of orientation that improves the conductivity of a material. The result from this finding also shows that for wearable applications the commercial EeonTexTM conductive stretchable fabric did not show a considerable resistivity increase, nor a good sensitivity. The sensitivity of the sensor was between 0.97 and 1.28 and varies with different elongation %. This may be due to the mechanical deformation characteristics of knitted samples that lead to changes in conductivity. We advise that the testing performed in this paper is done by default on new stretch sensitive textile materials, so practical use of the material can be correctly estimated